Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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List of figures
Figure A-35: SIT analysis of the data of [1973VAS/GLA] at 35 °C. .................... 339
Figure A-36:
Figure A-37:
Figure A-38:
Figure A-39:
Figure A-40:
ο
Determination of Δ H (Sn 2+ , 298.15 K). ....................................... 340
f
m
Determination of the enthalpy of dissolution of SnCl 2 (cr)
according to the reaction SnCl 2 (cr) Sn 2+ + 2 Cl – in HClO 4
medium at 25 °C. .............................................................................. 355
Determination of the enthalpy of dissolution of SnCl 2 (cr)
according to the reaction SnCl 2 (cr) Sn 2+ + 2 Cl – in HClO 4
medium at 25 °C. Extrapolation to infinite dilution according to
[1997ALL/BAN]. ............................................................................. 355
Determination of the enthalpy of dissolution of SnCl 2·2H 2 O(cr)
according to the reaction SnCl 2·2H 2 O(cr) Sn 2+ + 2 Cl – +
2 H 2 O(l) in HClO 4 medium at 25 °C. Extrapolation to infinite
dilution according to [1967VAS]. .................................................... 356
Determination of the enthalpy of dissolution of SnCl 2·2H 2 O(cr)
according to the reaction SnCl 2·2H 2 O(cr) Sn 2+ + 2 Cl – +
2 H 2 O(l) in HClO 4 medium at 25 °C. Extrapolation to infinite
dilution according to [1997ALL/BAN]. ........................................... 356
Figure A-41: SIT analysis of data from [1979VAS/GLA]. ................................... 368
Figure A-42: Experimental cell-potential values reported in
[1980AND/SAM] as a function of the nitrate concentration. ........... 370
Figure A-43: Heat-capacity function of Sn 2 S 3 (cr). ................................................ 377
Figure A-44: Entropy function of Sn 2 S 3 (cr). .......................................................... 378
Figure A-45: Heat capacity data for β-SnBr 4 . ........................................................ 386
Figure A-46: Speciation curves in the tin(II)-pyrophosphate system
([Sn 2+ ] T = 10 –4 3
M, [ PO − 4
] T = 10 –3 M, T = 298 K). a) curves
calculated using the data reported in [1991DUF/WIL] for I =
0.15 M NaCl, b) speciation suggested by Tur'yan et al.
[1986TUR/KRA], [1986TUR/KRA2], [1987TUR/KRA] for I =
1.0 M NaClO 4 ................................................................................... 397
Figure A-47: Sn(OH) 2 solubility in 3.0 M NaCl. ................................................... 407
Figure A-48: Stoichiometric solubility constant for Sn 3 (OH) 2 OSO 4 . .................... 409
Figure A-49: High-temperature heat capacity of SnO 2 (tetr.). ............................... 423
Figure A-50:
4−x
Extrapolation to I = 0 of the formation constants of SnClx
complexes using SIT (x = 1(A), 6(E)). ............................................. 429
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012