Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

A Discussion of selected references
425
Table A-75 (continued)
T/K
o
C T 1 /
( )
o
p, m
–1
J·K
–1·mol
C ( ) p, m
T 2 o
/
–1
J·K
–1·mol
S ( T)
1 o
m
/
–1
J·K
–1·mol
S ( m
/ H°(T) – H°(0 K) 1 / H°(T) – H°(0 K) 2 /
J·K –1·mol –1 kJ·mol –1 kJ·mol –1
1020.00 81.96 81.12 138.83 138.85 61.75 61.73
1040.00 82.22 81.35 140.43 140.43 63.39 63.35
1060.00 82.46 81.59 141.99 141.98 65.04 64.98
1080.00 82.70 81.82 143.54 143.51 66.69 66.62
1100.00 82.94 82.05 145.06 145.01 68.34 68.26
1120.00 83.17 82.28 146.55 146.49 70.01 69.90
1140.00 83.39 82.51 148.03 147.95 71.67 71.55
1160.00 83.61 82.73 149.48 149.39 73.34 73.20
1180.00 83.82 82.96 150.91 150.80 75.02 74.86
1200.00 84.03 83.18 152.32 152.20 76.69 76.52
1220.00 84.24 83.40 153.71 153.58 78.38 78.18
1240.00 84.44 83.61 155.08 154.93 80.06 79.85
1260.00 84.64 83.82 156.44 156.27 81.75 81.53
1280.00 84.83 84.03 157.77 157.60 83.45 83.21
1300.00 85.03 84.24 159.09 158.90 85.15 84.89
1320.00 85.22 84.44 160.39 160.19 86.85 86.58
1340.00 85.40 84.63 161.67 161.46 88.56 88.27
1360.00 85.59 84.83 162.94 162.71 90.27 89.96
1380.00 85.77 85.01 164.19 163.95 91.98 91.66
1400.00 85.95 85.20 165.42 165.18 93.70 93.36
1420.00 86.12 85.37 166.64 166.39 95.42 95.07
1440.00 86.30 85.54 167.85 167.58 97.14 96.78
1460.00 86.47 85.71 169.04 168.76 98.87 98.49
1480.00 86.64 85.86 170.22 169.93 100.60 100.20
1500.00 86.81 86.01 171.38 171.09 102.34 101.92
[2004GUR/GAV3]
In this paper, the same experimental data have been reported as in [2004GUR/GAV2],
and the heat capacity values of SnO 2 (cass) between 13.4 and 336.88 K were analysed by
the same methods. In this paper however, the comparison of low- and high-temperature
data is lacking.
[2005GIE/POR]
The kinetics of the disproportionation reaction of tin(II) oxide (SnO) to tin(IV) oxide
(SnO 2 ) and tin metal (Sn) was studied ex-situ and in-situ by X-ray powder diffraction
with synchrotron radiation. Depending on sample preparation and decomposition
temperature an intermediate oxide Sn 2 O 3 was observed. From thermal
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012