Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

Contents
xiii
VIII Group 17 (halogen) compounds and complexes 137
VIII.1 Halide compounds ........................................................................................ 137
VIII.1.1 Solid fluorides ........................................................................................... 137
VIII.1.1.1 SnF 2 (cr) ............................................................................................ 137
VIII.1.1.2 Ternary fluorides .............................................................................. 138
VIII.1.1.2.1 PbSnF 4 (cr)............................................................................... 138
VIII.1.1.2.2 BaSnF 4 (cr)............................................................................... 139
VIII.1.1.2.3 SrSnF 4 (cr)................................................................................ 140
VIII.1.2 Solid chlorides .......................................................................................... 140
VIII.1.2.1 SnCl 2 (cr)........................................................................................... 140
VIII.1.2.2 SnCl 2·2H 2 O(cr) ................................................................................. 145
VIII.1.2.3 Basic tin(II) chloride ........................................................................ 148
VIII.1.2.3.1 Composition of basic tin(II) chloride ...................................... 148
VIII.1.2.3.2 Solubility of Sn 21 Cl 16 (OH) 14 O 6 (cr).......................................... 149
VIII.1.3 Solid bromides .......................................................................................... 152
VIII.1.3.1 SnBr 2 (cr) .......................................................................................... 152
VIII.1.3.2 SnBr 4 (cr) .......................................................................................... 154
VIII.1.4 Solid iodides ............................................................................................. 156
VIII.1.4.1 Introduction ...................................................................................... 156
VIII.1.4.2 SnI 2 (cr) ............................................................................................. 156
VIII.1.4.3 SnI 4 (cr) ............................................................................................. 157
VIII.2 Solubility of tin halides in aqueous systems ............................................... 158
VIII.2.1 Solubility of tin fluorides .......................................................................... 158
VIII.2.1.1 SnF 2 (cr) ............................................................................................ 158
VIII.2.1.2 SnF 4 (s).............................................................................................. 161
VIII.2.1.3 SnO(OH)F(s) .................................................................................... 161
VIII.2.2 Solubility of tin chlorides ......................................................................... 161
VIII.2.2.1 SnCl 2 (s) ............................................................................................ 161
VIII.2.2.2 SnCl 2 - SnF 2 ..................................................................................... 162
VIII.2.2.3 SnCl 4 ................................................................................................ 162
VIII.2.2.4 Sn(OH)Cl 3·3H 2 O(s) .......................................................................... 162
VIII.2.2.5 Sn(OH) 2 Cl 2 (s) .................................................................................. 163
VIII.2.2.6 Sn(OH) 3 Cl·H 2 O(s) ............................................................................ 163
VIII.2.3 Solubility of tin bromides ......................................................................... 163
VIII.2.3.1 SnBr 2 (s)............................................................................................ 163
VIII.2.3.2 SnBrF(s) and Sn 3 BrF 5 (s) .................................................................. 163
VIII.2.3.3 SnBr 4 (s)............................................................................................ 163
VIII.2.3.4 Hydrates of SnBr 4 ............................................................................ 163
VIII.2.3.5 Sn(OH)Br 3·3H 2 O(s) .......................................................................... 163
VIII.2.4 Solubility of tin iodides ............................................................................ 164
VIII.2.4.1 SnI 2 (s)............................................................................................... 164
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012