Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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246 X Group 15 compounds and complexes T/K ο p,m Table X-8 (continued) C /J·K –1·mol –1 HT ( ) − H(0K) / J·mol –1 ο S m /J·K –1·mol –1 −[( GT ( ) − G(0 K)) T −1 ] / –1 J·K –1·mol 110 148.4 (148.203) 9530 (9532.847) 161 (160.310) 74.364 (73.648) 120 152.8 (152.462) 11000 (11036.867) 174 (173.394) 82.333 (81.420) 130 156.2 (155.984) 12600 (12579.630) 187 (185.740) 90.077 (88.974) 140 159.1 (158.937) 14200 (14154.650) 198 (197.411) 96.571 (96.306) 150 161.4 (161.448) 15800 (15756.902) 209 (208.464) 103.667 (103.418) 160 163.4 (163.614) 17400 (17382.468) 220 (218.955) 111.250 (110.315) 170 165.5 (165.508) 19000 (19028.276) 230 (228.932) 118.235 (117.001) 180 167.2 (167.186) 20700 (20691.904) 239 (238.440) 124.000 (123.485) 190 168.9 (168.696) 22400 (22371.440) 248 (247.521) 130.105 (129.777) 200 170.2 (170.070) 24100 (24065.367) 257 (256.209) 136.500 (135.882) 220 172.3 (172.521) 27500 (27491.839) 273 (272.536) 148.000 (147.573) 240 174.5 (174.702) 31000 (30964.415) 289 (287.643) 159.833 (158.626) 260 176.6 (176.719) 34500 (34478.833) 303 (301.707) 170.308 (169.096) 273.15 178.0 (177.991) 36800 (36811.088) 311 (310.457) 174.008 (175.692) 290 179.8 (179.584) 39800 (39823.704) 322 (321.159) 184.759 (183.836) 298.15 180.5 (180.346) 41300 (41290.423) 327 (326.147) 188.479 (187.658) 310 181.6 (181.450) 43400 (43434.068) 334 (333.197) 194.000 (193.087) ο 40K p,m 5K [ C ] ο 315K p,m 40K [ C ] The data can be fitted by the following equations: (Sn 4 As 3 , cr, T)/J·K –1·mol –1 = (167.9 ± 3.9)exp[− (35.55 ± 0.70)/(T/K)] (Sn 4 As 3 , cr, T )/J·K –1·mol –1 = − (30.22 ± 11.26) + (0.1828 ± 0.0099) T/K − (33393 ± 1232)/(T/K) + (333880 ± 13018)/(T/K) 2 + (4554 ± 213)/(T/K) 0.5 . The selected data for Sn 4 As 3 (cr) are: ο –1 C p,m (Sn 4 As 3 , cr, 298.15 K) = (179.8 ± 0.6) J·K –1·mol ο S m (Sn 4 As 3 , cr, 298.15 K) = (323.8 ± 3.8) J·K –1·mol –1 . CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
X.3 Arsenic compounds and complexes 247 Figure X-5: Two sets of measured heat capacity data for Sn 4 As 3 with w(Sn) = 0.58 and ο 0.59 [1980KOS/PAS]. The difference between the two C p,m data sets is about 1.2% through the whole range. 200 exp. data [1980KOS/PAS], [1980KOS/DEM] 100 w(Sn) = 58 100 w(Sn) = 59 150 –1·mol –1 C° p,m /J·K 100 50 C° p,m /J·K –1·mol –1 = (167.9 ± 3.9) exp[–(35.55 ± 0.70)/(T/K)] C° p,m /J·K –1·mol –1 = – (30.22 ± 11.27) + (0.1828 ± 0.0099)(T/K) – (33390 ± 1232)(K/T) + (333900 ± 13020)(K/T) 2 + (4554 ± 213)(K/T) 0.5 0 0 100 200 300 T / K CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
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CHEMICAL THERMODYNAMICS OF TIN Hein
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CHEMICAL THERMODYNAMICS Vol. 1. Che
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vi Preface of the successive drafts
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viii Acknowledgements for peer revi
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x How to contact the NEA TDB Projec
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xii Contents III Selected tin data
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xiv Contents VIII.3 Aqueous halide
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xvi Contents B.1.3.2 Estimations ba
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xviii List of figures Figure VII-12
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xx List of figures Figure IX-3: Hea
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xxii List of figures Figure A-35: S
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List of tables Table II-1: Abbrevia
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List of tables xxvii Table VIII-1:
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List of tables xxix Table IX-4: Tab
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List of tables xxxi Table A-21: Sta
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List of tables xxxiii Table A-64: T
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Part 1 Introductory material
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4 I Introduction and Ti. In 1976, t
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6 I Introduction The present review
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8 I Introduction subjective choice
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10 II Standards, conventions and co
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30 II.3 II Standards, conventions a
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Part 2 Tables of selected data
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44 III Selected tin data Table III-
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50 III Selected tin data Species Re
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Chapter IV Selected auxiliary data
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IV Selected auxiliary data 57 Table
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IV Selected auxiliary data 75 Speci
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IV Selected auxiliary data 77 Speci
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Part 3 Discussion of data selection
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82 V Elemental tin transition, call
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84 V Elemental tin ο Table V-3: Co
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86 V Elemental tin Table V-6: Param
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Chapter VI VI Simple tin aqua ionsE
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VI.2 Sn 2+ 91 at 24.5 °C in aqueou
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VI.2 Sn 2+ 93 Reference Table VI-1:
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VI.2 Sn 2+ 95 As only three data pa
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VI.2 Sn 2+ 97 Figures A-37 to A-40.
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VI.3 Sn 4+ 99 Sn 4+ + H 2 (g) Sn 2
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VI.3 Sn 4+ 101 (NH 4 ) 2 SnCl 6 see
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VI.3 Sn 4+ 103 Sn 4+ + H 2 (g) Sn
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VI.3 Sn 4+ 105 Figure VI-3: Modifie
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108 VII Tin oxygen and hydrogen com
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138 VIII Group 17 (halogen) compoun
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A Discussion of selected references
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B Appendix B Ionic strength correct
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B.1 2BThe specific ion interaction
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B.3 4BTables of ion interaction coe
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484 C Assigned uncertainties The mi
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486 C Assigned uncertainties discus
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488 C Assigned uncertainties In cas
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490 C Assigned uncertainties The un
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492 C Assigned uncertainties In thi
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494 C Assigned uncertainties bit fu
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496 C Assigned uncertainties that t
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498 C Assigned uncertainties Eq. (C
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