Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

List of figures
xxi
Figure A-11: SIT analysis of E (Sn 4+ /Sn 2+ ) vs. m −
Cl
, experimental data of
[1934HUE/TAR].............................................................................. 276
Figure A-12: The ternary system SnO-H 2 SO 4 -H 2 O. .............................................. 278
Figure A-13: Variation of E + (k/2)·log 10 K + 2D vs. m − .................................... 279
Cl
Figure A-14: Solubility of SnO(cr) in NaOH solutions. ........................................ 283
Figure A-15: Temperature dependence of log10
β
q
((A.26), q = 1, 2, 3)
recalculated from [1952VAN].......................................................... 290
Figure A-16: Temperature dependence of log10
β
q
((A.27), q = 1, 2, 3)
recalculated from [1952VAN/RHO]. ............................................... 292
Figure A-17: Low temperature heat-capacity function of α-SnS. ......................... 294
Figure A-18: Low temperature heat-capacity function of SnS 2 (cr). ...................... 295
Figure A-19: SIT analysis of the data of [1957WAK/SAL]. ................................. 299
Figure A-20: Enthalpy function of SnS(cr). ........................................................... 301
Figure A-21: Enthalpy function of SnS 2 (cr). ......................................................... 302
Figure A-22:
Figure A-23:
Solubility isotherms in the system SnF 2 -HF-H 2 O in aqueous
solutions at t = 0, 5, 9.9, 15.4, 20.3 and 30 °C. ................................ 308
Part of the diagram in Figure A-22. Solubility range for t = 5 to
30 °C is shown by the shaded area. .................................................. 311
Figure A-24: Activity coefficients of HClO 4 at different temperatures. ................ 314
Figure A-25: Temperature dependence of ε(H + , ClO − 4
). ........................................ 315
Figure A-26: Solubility of SnO(cr) in 1.050 M NaClO 4 solutions at 25 °C. ......... 317
Figure A-27:
Figure A-28:
Third-law analysis of the data of reaction β-Sn(cr) + 2 AgCl(cr)
SnCl 2 (cr) + 2 Ag(cr). ................................................................... 328
Third-law analysis of reaction β-Sn(cr) + PbCl 2 (cr)
SnCl 2 (cr) + Pb(cr). ........................................................................... 329
Figure A-29: Variation of E h as a function of log 10 [Cl – ]. ...................................... 332
Figure A-30: Variation of E h as a function of log 10 [Sn 2+ ]. .................................... 333
Figure A-31: Variation of E h as a function of log 10 [Sn 4+ ]. .................................... 334
Figure A-32: Solubility of SnO 2 in NaOH solutions. ............................................. 337
Figure A-33: SIT analysis of the data of [1973VAS/GLA] at 15 °C. .................... 338
Figure A-34: SIT analysis of the data of [1973VAS/GLA] at 25 °C. .................... 339
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012