Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

458
B Ionic strength corrections
j k ε(j,k) Comments
2
PuF +
2
Cl −
Table B-4: (continued)
ClO − 4
0.36 ± 0.17 Estimated in [2001LEM/FUG] by analogy with Δε of the corresponding
U(IV) reaction.
NO − —
3
2
PuCl + Cl − —
ClO − 4
0.39 ± 0.16 Estimated in [2001LEM/FUG] by analogy with Δε of the corresponding
Am(III) reaction.
NO − —
3
2
PuI + Cl − —
ClO − 0.39 ± 0.04 Estimated in [2001LEM/FUG] by assuming ε (PuI ,ClO
4
4
) ≈
2+ −
+ −
+ −
ε (AmSCN ,ClO
4
) and ε (NH
4
,I ) ≈ ε (Na ,SCN ) .
NO − 3
—
2
PuSCN + Cl − —
ClO − 2+ −
0.39 ± 0.04 Estimated in [2001LEM/FUG] by assuming ε (PuSCN ,ClO
4
4
)
2+
≈ ε (AmSCN ,ClO 4
) .
NO − 3
—
2
NpO + 2
Cl − —
ClO − 2+ −
0.46 ± 0.05 By analogy with ε (UO
4
2
,ClO
4)
as derived from isopiestic
measurements noted in [1992GRE/FUG]. The uncertainty is
increased because the value is estimated by analogy.
NO − 3
—
2
(NpO ) (OH) + 2 2 2
Cl − —
ClO − 4
0.57 ± 0.10 See Section 8.1.2 in [2001LEM/FUG].
NO − 3
—
2
NpF + 2
Cl − —
ClO − 4
0.38 ± 0.17 Estimated in [2001LEM/FUG] by analogy with Δε of the corresponding
U(IV) reaction.
NO − 3
—
2
NpSO + 4
Cl − —
ClO − 4
0.48 ± 0.11 Estimated on Section 10.1.2.1 of [2001LEM/FUG].
NO − 3
—
2
Np(SCN) + 2
Cl − —
ClO − 4
0.38 ± 0.20 Estimated in [2001LEM/FUG] by analogy with Δε of the corresponding
U(IV) reaction.
NO − 3
—
2+
(Continued on next page)
−
CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012