Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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354 A Discussion of selected references Table A-33: Stability constants of tin(II) chlorido-complexes, log 10 β q . t /°C I/M (HClO 4 ) SnCl + SnCl 2 SnCl − 3 10 0.0 1.51 ± 0.01 2.20 ± 0.02 1.18 ± 0.04 10 0.2 0.98 1.40 0.38 10 0.5 0.89 1.26 0.24 10 1.0 0.90 1.30 0.58 10 2.0 0.95 1.41 0.99 10 3.0 1.05 1.58 1.46 25 0.0 1.04 ± 0.01 2.43 ± 0.12 1.40 ± 0.01 25 0.5 1.00 1.47 0.44 25 1.0 1.01 1.51 0.78 25 2.0 1.06 1.61 1.18 25 3.0 1.16 1.79 1.66 In the course of recalculation the methods proposed by [1997ALL/BAN] p. 412 and [1967VAS], [1978VAS/YAS] were compared. As Figure A-37 to ο Figure A-40 show the differences in the extrapolated Δ fHm values are small but ο noticeable. For the final calculation of Δ fHm(Sn 2+ , 298.15 K) the results of ο [1973VAS/VAS2] and [1976VAS/KOK] have to be combined with Δ fHm (Cl – , ο 298.15 K) and Δ H (H 2 O, l, 298.15 K) of [1989COX/WAG]. f m The exclusion of dioxygen is not reported, although it can be assumed considering the scientific competence of the authors. The data reported in [1973VAS/VAS] and [1976VAS/KOK] have been used to calculate the standard enthalpies of formation of Sn 2+ and SnCl + ions, as well as the enthalpy of the reaction Sn 2+ + Cl – SnCl + . The graphically presented experimental data in [1973VAS/VAS] for 25 °C were re-evaluated for the purpose of this review. Using the selected log10 β ο q ((A.63), q = 1, 2, 3, 298.15 K) and Δε((A.63), q = 1, 2, 3) values, as well as the assumptions that ε(SnCl 2 ,NaClO 4 ) = ε(SnCl 2 , HClO 4 ) and ε(Na + , SnCl − 3 ) = ε(H + , SnCl − 3 ), the formation 2−q constants of the species SnClq (q = 1, 2, 3) in perchloric acid solutions according to the reaction: Sn 2+ + q Cl − SnCl can be estimated (Table A-34). 2−q q (A.63) CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
A Discussion of selected references 355 Figure A-37: Determination of the enthalpy of dissolution of SnCl 2 (cr) according to the reaction SnCl 2 (cr) Sn 2+ + 2 Cl – in HClO 4 medium at 25 °C. Extrapolation to infinite dilution according to [1967VAS]. (: experimental data of [1976VAS/KOK]; solid line: linear fit; dotted lines: 95% confidence limits). -1.0 -1.5 SnCl 2 (cr) Sn 2+ + 2 Cl – (Δ r H - F (I) Vas )/kcal·mol –1 -2.0 -2.5 -3.0 -3.5 ΔH° m (SnCl 2 , 298.15 K) = – (3.30 ± 0.24) kcal·mol –1 = – (13.81 ± 1.00) kJ·mol –1 0.0 0.5 1.0 1.5 2.0 2.5 3.0 I / mol·kg –1 Figure A-38: Determination of the enthalpy of dissolution of SnCl 2 (cr) according to the reaction SnCl 2 (cr) Sn 2+ + 2 Cl – in HClO 4 medium at 25 °C. Extrapolation to infinite dilution according to [1997ALL/BAN] (Eq. IX.72, r = 0). (: experimental data of [1976VAS/KOK]; solid line: linear fit; dotted lines: 95% confidence limits). -6 SnCl 2 (cr) Sn 2+ + 2 Cl – -8 (Δ r H - F (I) SIT )/kJ·mol –1 -10 -12 -14 -16 ΔH° m (SnCl 2 , 298.15 K) = – (15.05 ± 0.93) kJ·mol –1 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 I / mol·kg –1 CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
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CHEMICAL THERMODYNAMICS OF TIN Hein
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CHEMICAL THERMODYNAMICS Vol. 1. Che
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vi Preface of the successive drafts
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viii Acknowledgements for peer revi
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x How to contact the NEA TDB Projec
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xii Contents III Selected tin data
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xiv Contents VIII.3 Aqueous halide
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xvi Contents B.1.3.2 Estimations ba
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xviii List of figures Figure VII-12
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xx List of figures Figure IX-3: Hea
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xxii List of figures Figure A-35: S
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List of tables Table II-1: Abbrevia
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List of tables xxvii Table VIII-1:
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List of tables xxix Table IX-4: Tab
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List of tables xxxi Table A-21: Sta
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List of tables xxxiii Table A-64: T
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Part 1 Introductory material
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4 I Introduction and Ti. In 1976, t
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6 I Introduction The present review
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8 I Introduction subjective choice
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10 II Standards, conventions and co
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30 II.3 II Standards, conventions a
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Part 2 Tables of selected data
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44 III Selected tin data Table III-
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50 III Selected tin data Species Re
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Chapter IV Selected auxiliary data
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IV Selected auxiliary data 57 Table
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IV Selected auxiliary data 75 Speci
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IV Selected auxiliary data 77 Speci
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Part 3 Discussion of data selection
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82 V Elemental tin transition, call
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84 V Elemental tin ο Table V-3: Co
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86 V Elemental tin Table V-6: Param
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Chapter VI VI Simple tin aqua ionsE
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VI.2 Sn 2+ 91 at 24.5 °C in aqueou
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VI.2 Sn 2+ 93 Reference Table VI-1:
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VI.2 Sn 2+ 95 As only three data pa
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VI.2 Sn 2+ 97 Figures A-37 to A-40.
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VI.3 Sn 4+ 99 Sn 4+ + H 2 (g) Sn 2
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VI.3 Sn 4+ 101 (NH 4 ) 2 SnCl 6 see
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VI.3 Sn 4+ 103 Sn 4+ + H 2 (g) Sn
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VI.3 Sn 4+ 105 Figure VI-3: Modifie
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108 VII Tin oxygen and hydrogen com
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138 VIII Group 17 (halogen) compoun
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Chapter IX IX Group 16 compounds an
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IX.1 Sulfur compounds and complexes
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232 X Group 15 compounds and comple
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Chapter XI XI Group 14 compounds an
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XI-1 Aqueous tin thiocyanato comple
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Appendix A Discussion of selected r
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A Discussion of selected references
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Page 339 and 340: A Discussion of selected references
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B Appendix B Ionic strength correct
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B.1 2BThe specific ion interaction
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B.3 4BTables of ion interaction coe
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484 C Assigned uncertainties The mi
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486 C Assigned uncertainties discus
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488 C Assigned uncertainties In cas
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490 C Assigned uncertainties The un
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492 C Assigned uncertainties In thi
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494 C Assigned uncertainties bit fu
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496 C Assigned uncertainties that t
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498 C Assigned uncertainties Eq. (C
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Bibliography [1813BER] [1831NEU] [1
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Bibliography 503 [1906GOL/ECK] [190
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Bibliography 505 [1924LAN] [1925BRI
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Bibliography 513 [1954BRU] [1954DEL
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Bibliography 525 [1968KEB/MUL] Keba
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Bibliography 531 [1973HUL/DES] Hult
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Bibliography 557 [1990KOK/RAK] Koku
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Bibliography 563 [1997ALL/BAN] [199
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Bibliography 571 [2010TAN/SEK] [201
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