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Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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Preface<br />

This volume is the <strong>12</strong> th in the “<strong>Chemical</strong> <strong>Thermodynamics</strong>” series edited and produced<br />

by the <strong>OECD</strong> <strong>Nuclear</strong> Energy Agency (NEA). It is a critical review <strong>of</strong> the<br />

thermodynamic properties <strong>of</strong> tin, its compounds and aqueous complexes, initiated by<br />

the Management Board <strong>of</strong> the NEA Thermochemical Database Project Phase III (NEA<br />

TDB III). The European members <strong>of</strong> the TDB Sn Review Team − Wolfgang Voigt<br />

(Freiberg University <strong>of</strong> Mining and Technology, Germany), Tamás Gajda (University<br />

<strong>of</strong> Szeged, Hungary) and Heinz Gamsjäger as Chairman (Montanuniversität Leoben,<br />

Austria) − first met at the NEA in Issy-les-Moulineaux (France) in September 2004. The<br />

overseas members − Surendra K. Saxena (Florida International University, Miami,<br />

United States) and James Sangster (Sangster Research Laboratories, Montreal, Canada)<br />

participated in this kick<strong>of</strong>f meeting via phone and video link. Four subsequent plenary<br />

meetings took place at the NEA in March 2005, October 2005, March 2006 and October<br />

2006. The latter was held in conjunction with the TDB III Executive Group Meeting on<br />

25 October and the TDB III Management Board Meeting on 26-27 October 2006. In<br />

these meetings the Review Team reported that key values on Sn 4+ formation and the<br />

redox couple Sn 4+ /Sn 2+ were lacking. Moreover, essential formation data on Sn(IV)<br />

chlorido and hydroxido complexes were also lacking. Therefore the Review Team<br />

submitted a proposal to the Management Board requesting to fund an experimental<br />

programme to obtain values for the most important critical data, while the already<br />

completed sections dealing with solids and gases were sent to peer review. The<br />

Management Board agreed and the experimental investigation was carried out under the<br />

leadership <strong>of</strong> Tamás Gajda at the University <strong>of</strong> Szeged Department <strong>of</strong> Inorganic and<br />

Analytical Chemistry. From 7 to 10 August 2008 the solution chemistry group<br />

comprising Wolfgang Voigt, Tamás Gajda and Heinz Gamsjäger met at<br />

Montanuniversität Leoben to include the results <strong>of</strong> the experimental study in the tin<br />

draft. The publication <strong>of</strong> these results, mandatory by NEA standards for including new<br />

data in chemical thermodynamics volumes, appeared in 2009. Heinz Gamsjäger<br />

presented these results at the meeting <strong>of</strong> the TDB IV Executive Group on 19 May 2010<br />

in Karlsruhe.<br />

Hans Wanner participated in meetings <strong>of</strong> the Review Team as the designated<br />

member <strong>of</strong> the Executive Group until he retired from this position in 2007. At the NEA<br />

Data Bank the responsibility for the overall co-ordination <strong>of</strong> the project was placed with<br />

Federico Mompean (from its initiation in 2004 to 2007), with Mireille Defranceschi<br />

(2008 to 2010) and Jane Perrone (2011). Jane Perrone was in charge <strong>of</strong> the preparation<br />

CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © <strong>OECD</strong> 20<strong>12</strong>

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