Chemical Thermodynamics of Tin - Volume 12 - OECD Nuclear ...

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478 B Ionic strength corrections Table B-5: (continued) K + — + 4− + 4− 2 3 2 3 3 j k ε(j,k) Comments 4 UO 2(ox) 3 Li + — Na + − 0.01 ± 0.11 Estimated in [2005HUM/AND], Section VI.10.2.4.1 by assuming ε(Na ,UO (ox) ) ≈ ε(Na ,UO (CO ) ) . 4 (UO 2) 3(OH) 4(SO 4) 3 Li + — Na + 0.6 ± 0.6 Estimated in Section 9.5.1.1.2 of [2003GUI/FAN]. K + — 5 NpO 2(CO 3) − 3 Li + — Na + − 0.53 ± 0.19 Calculated in [2001LEM/FUG] (Section 12.1.2.1.3). K + − 0.22 ± 0.03 Evaluated in [2003GUI/FAN] (discussion of [1998ALM/NOV] in Appendix A) from Δε for the reactions 2 KNpO 2CO 3(s) + 2CO − 5 − + 3 NpO 2(CO 3) 3 + K (in K 2 CO 3 −KCl solution) and K 3 NpO 2 (CO 3 ) 2 (s) 2 + CO − 5 3 NpO 2(CO 3) 3 + 3K + (in K 2 CO 3 solution) (based + 2− on ε (K ,CO 3 ) = (0.02 ± 0.01) kg·mol −1 ). 5 UO 2(CO 3) 3 Li + — Na + − 0.62 ± 0.15 These values differ from those reported in [1992GRE/FUG]. 2 See the discussion in [1995GRE/PUI]. Values for CO − 3 and HCO − 3 are based on [1980CIA]. K + — 5 Th(OH)(CO 3 ) − 4 Li + — Na + – 0.22 ± 0.13 Evaluated in Section XI.1.3.2.1 of [2008RAN/FUG]. K + — 6 Np(CO 3) 5 Li + — Na + — K + − 0.73 ± 0.68 Calculated in [2001LEM/FUG] (Section 12.1.2.1.4). 6 (NpO 2) 3(CO 3) 6 Li + — Na + − 0.46 ± 0.73 Calculated in [2001LEM/FUG] (Section 12.1.2.1.2). K + — 6 U(CO 3) 5 Li + — Na + − 0.30 ± 0.15 These values differ from those reported in [1992GRE/FUG]. 2 See the discussion in [1995GRE/PUI]. Values for CO − 3 and HCO − 3 are based on [1980CIA]. K + − 0.70 ± 0.31 Calculated in [2001LEM/FUG] from Pitzer coefficients [1998RAI/FEL]. Continued on next page) CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
B.3 4BTables of ion interaction coefficients 479 Table B-5: (continued) j k ε(j,k) Comments 6 (UO 2) 3(CO 3) 6 Li + — Na + 0.37 ± 0.11 These values differ from those reported in [1992GRE/FUG]. K + — See the discussion in [1995GRE/PUI]. Values for HCO − are based on [1980CIA]. 3 6 (UO 2) 2NpO 2(CO 3) 6 Li + — Na + 0.09 ± 0.71 Estimated by analogy in [2001LEM/FUG] (Section K + — 12.1.2.2.1). 6 (UO 2) 5(OH) 8 (SO 4) 4 Li + — Na + 1.10 ± 0.5 Estimated in Section 9.5.1.1.2 of [2003GUI/FAN]. K + — 6 Th(CO 3) − 5 Li + — Na + – 0.30 ± 0.15 Estimated in Section XI.1.3.2.1 of [2008RAN/FUG]. K + — 7 (UO 2) 4(OH) 7(SO 4) 4 Li + — Na + 2.80 ± 0.7 Estimated in Section 9.5.1.1.2 of [2003GUI/FAN]. K + — 2 CO − and 3 CHEMICAL THERMODYNAMICS OF TIN, ISBN 978-92-64-99206-1, © OECD 2012
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CHEMICAL THERMODYNAMICS OF TIN Hein
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CHEMICAL THERMODYNAMICS Vol. 1. Che
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vi Preface of the successive drafts
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viii Acknowledgements for peer revi
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x How to contact the NEA TDB Projec
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xii Contents III Selected tin data
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xiv Contents VIII.3 Aqueous halide
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xvi Contents B.1.3.2 Estimations ba
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xviii List of figures Figure VII-12
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xx List of figures Figure IX-3: Hea
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xxii List of figures Figure A-35: S
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List of tables Table II-1: Abbrevia
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List of tables xxvii Table VIII-1:
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List of tables xxix Table IX-4: Tab
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List of tables xxxi Table A-21: Sta
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List of tables xxxiii Table A-64: T
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Part 1 Introductory material
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4 I Introduction and Ti. In 1976, t
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6 I Introduction The present review
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8 I Introduction subjective choice
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10 II Standards, conventions and co
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30 II.3 II Standards, conventions a
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Part 2 Tables of selected data
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44 III Selected tin data Table III-
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50 III Selected tin data Species Re
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Chapter IV Selected auxiliary data
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IV Selected auxiliary data 57 Table
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IV Selected auxiliary data 75 Speci
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IV Selected auxiliary data 77 Speci
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Part 3 Discussion of data selection
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82 V Elemental tin transition, call
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84 V Elemental tin ο Table V-3: Co
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86 V Elemental tin Table V-6: Param
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Chapter VI VI Simple tin aqua ionsE
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VI.2 Sn 2+ 91 at 24.5 °C in aqueou
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VI.2 Sn 2+ 93 Reference Table VI-1:
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VI.2 Sn 2+ 95 As only three data pa
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VI.2 Sn 2+ 97 Figures A-37 to A-40.
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VI.3 Sn 4+ 99 Sn 4+ + H 2 (g) Sn 2
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VI.3 Sn 4+ 101 (NH 4 ) 2 SnCl 6 see
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VI.3 Sn 4+ 103 Sn 4+ + H 2 (g) Sn
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VI.3 Sn 4+ 105 Figure VI-3: Modifie
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108 VII Tin oxygen and hydrogen com
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138 VIII Group 17 (halogen) compoun
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Chapter IX IX Group 16 compounds an
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IX.1 Sulfur compounds and complexes
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232 X Group 15 compounds and comple
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Chapter XI XI Group 14 compounds an
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XI-1 Aqueous tin thiocyanato comple
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Appendix A Discussion of selected r
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A Discussion of selected references
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Page 463 and 464: A Discussion of selected references
Page 471 and 472: B Appendix B Ionic strength correct
Page 473 and 474: B.1 2BThe specific ion interaction
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Page 537 and 538: Bibliography [1813BER] [1831NEU] [1
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