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Mathematical Methods for Physics and Engineering - Matematica.NET

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EIGENFUNCTION METHODS FOR DIFFERENTIAL EQUATIONSwhich is a statement of the orthogonality of y i <strong>and</strong> y j .If one (or more) of the eigenvalues is degenerate, however, we have differenteigenfunctions corresponding to the same eigenvalue, <strong>and</strong> the proof of orthogonalityis not so straight<strong>for</strong>ward. Nevertheless, an orthogonal set of eigenfunctionsmay be constructed using the Gram–Schmidt orthogonalisation method mentionedearlier in this chapter <strong>and</strong> used in chapter 8 to construct a set of orthogonaleigenvectors of an Hermitian matrix. We repeat the analysis here <strong>for</strong> completeness.Suppose, <strong>for</strong> the sake of our proof, that λ 0 is k-fold degenerate, i.e.Ly i = λ 0 ρy i <strong>for</strong> i =0, 1,...,k− 1, (17.25)but that λ 0 is different from any of λ k , λ k+1 , etc. Then any linear combination ofthese y i is also an eigenfunction with eigenvalue λ 0 since∑k−1∑k−1∑k−1Lz ≡ L c i y i = c i Ly i = c i λ 0 ρy i = λ 0 ρz. (17.26)i=0i=0If the y i defined in (17.25) are not already mutually orthogonal then considerthe new eigenfunctions z i constructed by the following procedure, in which eachof the new functions z i is to be normalised, to give ẑ i , be<strong>for</strong>e proceeding to theconstruction of the next one (the normalisation can be carried out by dividingthe eigenfunction z i by ( ∫ ba z∗ i z iρdx) 1/2 ):z 0 = y 0 ,∫ b)z 1 = y 1 −(ẑ 0 ẑ0y ∗ 1 ρdx ,a∫ b) ∫ b)z 2 = y 2 −(ẑ 1 ẑ1y ∗ 2 ρdx −(ẑ 0 ẑ0y ∗ 2 ρdx ,aa.∫ b)∫ b)z k−1 = y k−1 −(ẑ k−2 ẑk−2y ∗ k−1 ρdx − ···−(ẑ 0 ẑ0y ∗ k−1 ρdx .aaEach of the integrals is just a number <strong>and</strong> thus each new function z i is, as can beshown from (17.26), an eigenvector of L with eigenvalue λ 0 . It is straight<strong>for</strong>wardto check that each z i is orthogonal to all its predecessors. Thus, by this explicitconstruction we have shown that an orthogonal set of eigenfunctions of anHermitian operator L can be obtained. Clearly the orthogonal set obtained, z i ,isnot unique.In general, since L is linear, the normalisation of its eigenfunctions y i (x) isarbitrary. It is often convenient, however, to work in terms of the normalisedeigenfunctions ŷ i (x), so that ∫ ba ŷ∗ i ŷiρdx= 1. These there<strong>for</strong>e <strong>for</strong>m an orthonormal562i=0

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