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Message - 7th IAL Symposium

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The 7 th International Association for Lichenology <strong>Symposium</strong> 2012<br />

(4I-P16) Submission ID: <strong>IAL</strong>0243-00003<br />

DETERMINATION OF IRON (Fe) AND ZINC (Zn) CONTENTS IN SOME LICHENS<br />

IN NONGSOUNG DISTRICT, MUKDAHAN PROVINCE, THAILAND<br />

Keoinpaeng S. 1 , Chantiratikul P. 1 , Papong K. 2<br />

1 Faculty of Science, Department of Chemistry, Mahasarakham University, Thailand<br />

2 Faculty of Science, Department of Biology, Mahasarakham University, Thailand<br />

This research was to study the concentration of Fe and Zn contents in thallus of Dirinaria picta, Laurera<br />

benguelensis, Parmotrema tinctorum and Pyxine coccifera from Nongsoung District, Mukdahan Province. Atomic<br />

Absorption Spectrometry (AAS) technique was used to determine amounts of metals in corticolous lichens. The<br />

high concentration of Fe were found in Pyxine coccifera and Dirinaria picta; 0.959 mg g -1 and 0.853 mg g -1 ,<br />

respectively. In other hand, Zn concentration was low such as Parmotrema tinctorum 0.293 mg g -1 , Laurera<br />

benguelensis 0.213 mg g -1 . The trace element absorption in lichens thallus can be used for bio-monitoring of air<br />

pollution.<br />

(4I-P17) Submission ID: <strong>IAL</strong>0244-00001<br />

MEASURING NITRATE AND SULFATE DEPOSITION IN LICHENS AFTER TRANSPLANTATION<br />

TO POLLUTED SITES IN BANGKOK, THAILAND<br />

Sriviboon C. 1 , Boonpragob K. 2 , Sriviboon T. 1 , Jhumpasri T. 1 , Boonpeng C. 2<br />

1 Chemistry, Ramkhamhaeng University, Bangkok, Thailand<br />

2 Biology, Ramkhamhaeng University, Bangkok, Thailand<br />

The ion chromatography was performed to measure nitrate and sulfate deposition in lichens transplanted<br />

to public parks around Bangkok city. The inorganic anions in lichens were separated and quantify by using column<br />

IonPac AS12A and suppressed conductometric detection with ASRS-300 (4 mm). The eluent was a mixture of<br />

2.7 mM Na 2 CO 3 and 0.3 mM NaHCO 3 by isocratic elution. The chromatographic conditions were validated in<br />

terms of detection limit, precision and linearity. It was found that the detection limit of nitrate and sulfate were<br />

0.014 mg/L and 0.019 mg/L respectively, and precision in seven repetitions (%RSD) of two ions were more than<br />

2.5% at concentration lower than 1 ppm and less than 0.6 % at concentration higher than 1 ppm. The linearity<br />

was obtained by correlation coefficient (R 2 ) better than 0.998. The results found that the amounts of nitrates and<br />

sulfates in transplanted lichens from eleven public parks had increasing tendency with exposure time in Bangkok<br />

during 19/9/2010 to 5/2/2011. However, the amount of both ions in the last sampling period 20/4/2011, declined<br />

in all public parks because of rain before samples were collected. Nevertheless these amounts were still higher<br />

than those at Khao Yai National Park and the control site. No correlations, R 2 below 0.3, were found between<br />

nitrate and sulfate from CS, KY, BS and SP, whereas the other sites had R 2 higher than 0.5.<br />

147<br />

4I-P

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