PhD Thesis - Energy Systems Research Unit - University of Strathclyde

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4. Make methanol via catalytic conversion The two-stage process of converting methane to methanol is characterised by the following chemical equation when no carbon dioxide is available [3], 2CH4 + 2H2O 2CH3OH + 2H2 ( 64 kg CH4 + 108 kg H2O 128 kg CH3OH + 8 kg H2O ) and by the following equation if carbon dioxide is available, 6CH4 + 4H2O + 2CO2 8CH3OH ( 192 kg CH4 + 144 kg H2O + 176 kg CO2 512 kg CH3OH ) The methane production rate by weight (in kg/hr) is again determined using Equation 6.19, and the production rate of carbon dioxide is calculated using, CO2 Production = Methane x (100 - %Methane) x CO2Density (6.21) Rate (kg/hr) CH4Density x %Methane Where Methane = Methane production rate (kg/hr) %Methane = Percentage of methane in biogas by volume CO2Density = Density of carbon dioxide (kg/m 3 ) CH4Density = Density of methane (kg/m 3 ) If there is sufficient carbon dioxide to allow the second equation to be used, or if extra carbon dioxide may be used as necessary, the methanol production rate is calculated using Equation 6.22, and any extra carbon dioxide required is calculated in a similar manner. Methanol Production = 512 x Methane x Percent (6.22) Rate (litres/hr) 192 x Density x 100 196
Where Methane = Methane Production Rate (kg/hr) Percent = Reaction Completion Percentage Density = Density of Methanol (kg/litre) If there is not sufficient carbon dioxide present, and extra may not be utilised, the amount of methanol that can be made with the carbon dioxide present is calculated using, Methanol Production = 512 x CO2 x Percent (6.23) Rate (litres/hr) 176 x Density x 100 Where CO2 = CO2 Production Rate (kg/hr), and the remaining, unused methane is calculated using, Remaining = Methane – (196 x CO2 x Percent) (6.24) Methane (kg/hr) (176 x 100) The methanol that can be made using the first chemical reaction is then determined in the same manner, by direct proportion using the first chemical equation, and added to the methanol production rate for that timestep. If desired, the remaining methane production rate may be calculated as described for hydrogen production, as can the process electricity and heat requirements and the electricity required for gas storage. The total amount of methanol produced (litres) throughout the simulation period, and any extra carbon dioxide required, is given along with the final production rate graphs. 197
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Decision Support for New and Renewa
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Abstract The global requirement for
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CONTENTS 1 ENERGY SYSTEMS FOR SUSTA
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5.5 Steam Turbine Model 149 5.6 Fue
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FIGURES Figure 1.1 Final Energy Con
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Figure 7.30 Following Electricity a
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on the use of fossil fuels, energy
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The general increase in energy cons
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supply is reduced or eliminated, lo
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Figure 1.3 The Electricity Supply G
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on different generation mixes depen
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Various studies have been carried o
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provision for smaller areas, and he
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1.7 References [1] The Internationa
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2 Options for New and Renewable Ene
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the amount of usable heat that is g
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the conversion of petrol cars; howe
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set times, producing a constant ele
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partial load. Fast response and sta
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2.3 The Production and Storage of H
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dedicated boiler, which runs contin
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Figure 2.3 A Typical Hydrogen Filli
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part of the natural carbon cycle (a
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Figure 2.4 Layout of a Gasification
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met by process integration and the
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Figure 2.5 The Inputs and Outputs o
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1. Scale for measuring out lye and
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feedstock being used. Sugary feedst
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carbon dioxide via steam reforming.
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• Where CHP is used, the balance
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[22] Vehicle Certification Agency (
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[55] M. A. Paisley, J. M. Irving, R
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3 Approaches to Renewable Energy Sy
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Because of the intermittent nature
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A renewable energy supply evaluatio
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the system are kept. The output of
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There are various models available
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When the use of climate dependant i
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3.5 References [1] M. Muselli, G. N
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4 A Procedure for Demand and Supply
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pumped storage and flywheels), a ba
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for the agricultural vehicle use re
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Figure 4.4 Combining Demands to Tak
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ates for vehicles, engines and othe
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Figure 4.5 Derived Fuel Production
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together if desired, and taken forw
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profiles are output from this part
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dividing the production rate at eac
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As it would be too confusing to sho
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Figure 4.12 Output of the Matching
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However, when more than one transpo
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considered, this amount is added to
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users are alerted if there is not e
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at the matching stage, along with t
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vehicles if they are increased by 1
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If biogas is being considered, the
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The number of timesteps per hour wi
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After the algorithm has been follow
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• Float Charge - once the battery
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Discharge No tank = tank fuel used
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equired (kW) = maxkWh x bulk% (5.16
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An example of the output graph prod
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5.2.1 Required Power Specifically d
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5.2.3 Engine Performance in the Con
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used for gas powered ICEs, but the
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and five times, depending on the nu
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Is PL < Min ? No Is PL = 0 ? No Is
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where Max = maximum energy availabl
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where Ratiopart = heat to electrici
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(including following heat demand wh
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where SFC = specific fuel consumpti
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engines running respectively). If t
Page 145 and 146: (continued) Is Fuel Available > (4
Page 147 and 148: of the definition window for a Stir
Page 149 and 150: and continuous operation. Again, mu
Page 151 and 152: The performance of a fuel cell is n
Page 153 and 154: percentage loading, rather than usi
Page 155 and 156: Is Min = 0 ? No Is Min = PC1 ? No I
Page 157 and 158: 5.6.4 If Fuel Availability is Less
Page 159 and 160: 5.7 Electrolyser Model An electroly
Page 161 and 162: original calculation of the amount
Page 163 and 164: 5.8 Regenerative Fuel Cell Model A
Page 165 and 166: following the heat demand. To follo
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Page 169 and 170: As 1 kWh = 3610.3 kJ, and using lit
Page 171 and 172: Add Heat to Water Storage Tank Usin
Page 173 and 174: Use Stored Hot Water to Supply Heat
Page 175 and 176: information is given about the over
Page 177 and 178: [23] K. Foger, B. Godfrey, “Syste
Page 179 and 180: the gasification and pyrolysis defi
Page 181 and 182: eing used each day for a continuous
Page 183 and 184: Where Biogas = Biogas production ra
Page 185 and 186: 6.1.3 Use of Biogas Various options
Page 187 and 188: The amount of hydrogen that can be
Page 189 and 190: direct proportion, and the weight o
Page 191 and 192: produce in total (Nm 3 per tonne fe
Page 193 and 194: Electricity (kW) = Elec x Feed (6.1
Page 195: 3. Make hydrogen via steam reformin
Page 199 and 200: (continued) Keep as medium heating
Page 201 and 202: Yes Feed1 = Yield1 x Land1 / No. of
Page 203 and 204: production and energy use profiles
Page 205 and 206: If it is the last timestep of the p
Page 207 and 208: For each process, the process chara
Page 209 and 210: At the end of the simulation, graph
Page 211 and 212: As the time required for one batch
Page 213 and 214: Ethanol = Factor1 x Eth x Timesteps
Page 215 and 216: 6.5 Electrolysis As it is sometimes
Page 217 and 218: 6.7 Landfill Gas Processing As the
Page 219 and 220: Demand Profile Design & Profile Dat
Page 221 and 222: Figure 7.2 Degree-Days Versus Month
Page 223 and 224: Stage 1 - Sustainable Fuel Supply S
Page 225 and 226: The different profile of use graphs
Page 227 and 228: Figure 7.3 Fermentation System Inpu
Page 229 and 230: Figure 7.7 Fermentation System Info
Page 231 and 232: Figure 7.10 Fermentation System Out
Page 233 and 234: The output obtained when a second h
Page 235 and 236: Figure 7.16 Anaerobic Digestion Par
Page 237 and 238: Figure 7.19 Fermentation System Inp
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Page 241 and 242: Figure 7.25 Heat Demand Profile Fig
Page 243 and 244: Figure 7.28 Effect of Minimum Load
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Figure 7.35 Second Engine: Followin
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This chapter described how the over
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heat and electricity during the tou
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Figure 8.2: Overall Yearly Heat Dem
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to allow for efficient operation du
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would be incurred, and the scale of
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Figure 8.5: Electricity Supply and
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heat demand or both, or run at cons
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ut with 30% less land being require
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9 Conclusions and Recommendations T
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through these, technically viable p
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considered. The introduction of coo
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When considering larger geographica
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Appendix 1: Program Windows Figure
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Figure A1.5 CreateClimate.exe Figur
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Figure A1.9: Demand Profile Designe
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Figure A1.13: Derived Fuel Supply W
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Figure A1.17: Fermentation System D
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Figure A1.21: PV Electrolysis Syste
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Figure A1.25: Fuel Supply Profile D
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Figure A1.29: Auxilliary Supply Def
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Figure A1.33: Stirling Engine Syste
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Figure A1.37: Fuel Cell System Defi
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Figure A1.41: Electric Vehicle Syst
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Figure A1.45: Vehicle Conversion Fa
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Figure A1.49: Heating System Defini
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Figure A1.53: Pumped Hydro System D
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Figure A1.57: Auto Search Evaluatio
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PhD Thesis - Energy Systems Research Unit - University of Strathclyde

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