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PhD Thesis - Energy Systems Research Unit - University of Strathclyde

PhD Thesis - Energy Systems Research Unit - University of Strathclyde

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the conversion <strong>of</strong> petrol cars; however, specially designed vehicles take these<br />

issues into account.<br />

The use <strong>of</strong> alcohol-fuelled vehicles is well tested, and has achieved great success<br />

in countries such as Brazil [16]. A variety <strong>of</strong> flexible fuelled vehicles (FFVs)<br />

are available which can run on 100% alcohol (ethanol or methanol), 100%<br />

petrol, or a combination <strong>of</strong> the two [8-13,17-19]. This type <strong>of</strong> vehicle uses an<br />

internal combustion engine (ICE), which is able to sense the percentage <strong>of</strong><br />

alcohol in the mixture, and adjust its parameters accordingly. The use <strong>of</strong> alcohol<br />

as a fuel does still produce various emissions, though these are substantially<br />

lower than if using petrol or diesel. However, as the carbon dioxide produced<br />

by these vehicles is reused when growing the crops used to make the alcohol,<br />

this process is classed as carbon neutral [7]. Fuel cell vehicles are also being<br />

developed with on-board fuel reformers that convert the alcohol to hydrogen,<br />

and it is estimated that these will achieve 2.1 to 2.6 times greater fuel efficiency<br />

than using the alcohol in an ICE [20]. The efficiency <strong>of</strong> an FFV is comparable<br />

to a petrol engine.<br />

Fuel cell powered vehicles can run on pure hydrogen, producing clean water as<br />

the only emission. They are also being designed to run on alcohol, biogas or<br />

even petrol, with onboard reformers converting these fuels into hydrogen.<br />

These latter vehicles, therefore, still produce some emissions, though fuel<br />

efficiencies are greater than equivalent use in ICEs. The use <strong>of</strong> fuel cell vehicles<br />

is less established than the other types <strong>of</strong> vehicle being considered here, and,<br />

although a number <strong>of</strong> buses are in operation, commercially available cars are<br />

still three to five years away from the market, so little performance data is<br />

available from manufacturers [13,19,21].<br />

Biodiesel can be used directly in a diesel engine with little or no modifications,<br />

and burns much more cleanly and thoroughly than diesel, giving a substantial<br />

reduction in unburned hydrocarbons, carbon monoxide and particulate matter.<br />

This does still produce carbon dioxide, but this is balanced by the continued<br />

growing <strong>of</strong> the crops used to produce the biodiesel [7]. It is a well-tested fuel,<br />

and experience shows that the fuel consumption <strong>of</strong> a diesel vehicle in litres<br />

33

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