PhD Thesis - Energy Systems Research Unit - University of Strathclyde

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Fuel cells are classified by the type of electrolyte they use, and this dictates the type of fuel and operating temperature that are required. The most commonly used fuel cell for small scale and transport applications, due to its low operating temperature, and compact and lightweight form, is the Proton Exchange Membrane fuel cell (PEMFC). Phosphoric Acid and Molten Carbonate fuel cells (PAFC and MCFC) are also available for larger scale applications, and require higher operating temperatures (roughly 200°C and 650°C), which means they must be kept at this temperature if fast start-up is required. All of these fuel cells may be run on pure hydrogen, natural gas or biogas. Certain PAFCs may also use methanol or ethanol as a fuel. If pure hydrogen is used, the only emission from a fuel cell is pure, clean water. If other fuels are used, some emissions are given off, though the amounts are lower due to the better efficiencies achievable with fuel cells, especially at partial load. Figure 2.1 shows the basic components of a fuel cell. Figure 2.1 Basic Components of a Fuel Cell [41] 38
2.3 The Production and Storage of Heat The demand for space and water heating may be met through the use of CHP, or through dedicated heaters using electricity or fuels derived from biomass or waste. This heat may be produced on demand, or produced and stored in electric storage heaters for space heating (using excess electricity when available), or in hot water storage tanks (heated by excess heat from dedicated boilers or CHP systems, or excess electricity). This storage provides a good use for excess electricity in a system, allows dedicated boilers to be run continuously, and/or allows CHP plant to follow the electricity demand or run continuously. Heat stored as hot water may be used later for space heating and the supply of hot water. 2.3.1 Instantaneous Space and Water Heaters Various types of instantaneous heaters are available for different scales and types of application, and using different fuels, including electricity, biogas, and hydrogen [36-39]. These heaters may be used directly in buildings for space and water heating, or for providing or boosting the heat output of district heating schemes. When combined heat and power is being used for district heating, it may be useful to use excess electricity to provide some of the heat requirement when demand for heat is high. This would reduce the loading on the CHP plant, and the amount of wasted electricity. The use of hydrogen fuelled heaters for space and water heating, and cooking is a good use for hydrogen produced by electrolysis from excess electricity, and conversion efficiencies ranging from 80 to 95% are achievable [40,41]. The production of heat from electricity is 100% efficient, though not necessarily the best use for this high grade energy source, and biogas heating systems have electricity to heat conversion efficiencies of 60% to 80%, depending on the type of plant used. Biomass and waste, generally in the form of pellets, can also be used for space heating in domestic-sized and larger boilers, though start-up and response to change in demand times are slower. Figure 2.2 shows the similarity in design between a hydrogen fuelled domestic heater and a wood pellet boiler. 39
Page 1 and 2: Decision Support for New and Renewa
Page 3 and 4: Abstract The global requirement for
Page 5 and 6: CONTENTS 1 ENERGY SYSTEMS FOR SUSTA
Page 7 and 8: 5.5 Steam Turbine Model 149 5.6 Fue
Page 9 and 10: FIGURES Figure 1.1 Final Energy Con
Page 11 and 12: Figure 7.30 Following Electricity a
Page 13 and 14: on the use of fossil fuels, energy
Page 15 and 16: The general increase in energy cons
Page 17 and 18: supply is reduced or eliminated, lo
Page 19 and 20: Figure 1.3 The Electricity Supply G
Page 21 and 22: on different generation mixes depen
Page 23 and 24: Various studies have been carried o
Page 25 and 26: provision for smaller areas, and he
Page 27 and 28: 1.7 References [1] The Internationa
Page 29 and 30: 2 Options for New and Renewable Ene
Page 31 and 32: the amount of usable heat that is g
Page 33 and 34: the conversion of petrol cars; howe
Page 35 and 36: set times, producing a constant ele
Page 37: partial load. Fast response and sta
Page 41 and 42: dedicated boiler, which runs contin
Page 43 and 44: Figure 2.3 A Typical Hydrogen Filli
Page 45 and 46: part of the natural carbon cycle (a
Page 47 and 48: Figure 2.4 Layout of a Gasification
Page 49 and 50: met by process integration and the
Page 51 and 52: Figure 2.5 The Inputs and Outputs o
Page 53 and 54: 1. Scale for measuring out lye and
Page 55 and 56: feedstock being used. Sugary feedst
Page 57 and 58: carbon dioxide via steam reforming.
Page 59 and 60: • Where CHP is used, the balance
Page 61 and 62: [22] Vehicle Certification Agency (
Page 63 and 64: [55] M. A. Paisley, J. M. Irving, R
Page 65 and 66: 3 Approaches to Renewable Energy Sy
Page 67 and 68: Because of the intermittent nature
Page 69 and 70: A renewable energy supply evaluatio
Page 71 and 72: the system are kept. The output of
Page 73 and 74: There are various models available
Page 75 and 76: When the use of climate dependant i
Page 77 and 78: 3.5 References [1] M. Muselli, G. N
Page 79 and 80: 4 A Procedure for Demand and Supply
Page 81 and 82: pumped storage and flywheels), a ba
Page 83 and 84: for the agricultural vehicle use re
Page 85 and 86: Figure 4.4 Combining Demands to Tak
Page 87 and 88: ates for vehicles, engines and othe
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Figure 4.5 Derived Fuel Production
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together if desired, and taken forw
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profiles are output from this part
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dividing the production rate at eac
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As it would be too confusing to sho
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Figure 4.12 Output of the Matching
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However, when more than one transpo
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considered, this amount is added to
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users are alerted if there is not e
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at the matching stage, along with t
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vehicles if they are increased by 1
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If biogas is being considered, the
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The number of timesteps per hour wi
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After the algorithm has been follow
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• Float Charge - once the battery
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Discharge No tank = tank fuel used
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equired (kW) = maxkWh x bulk% (5.16
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An example of the output graph prod
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5.2.1 Required Power Specifically d
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5.2.3 Engine Performance in the Con
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used for gas powered ICEs, but the
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and five times, depending on the nu
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Is PL < Min ? No Is PL = 0 ? No Is
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where Max = maximum energy availabl
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where Ratiopart = heat to electrici
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(including following heat demand wh
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where SFC = specific fuel consumpti
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engines running respectively). If t
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(continued) Is Fuel Available > (4
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of the definition window for a Stir
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and continuous operation. Again, mu
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The performance of a fuel cell is n
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percentage loading, rather than usi
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Is Min = 0 ? No Is Min = PC1 ? No I
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5.6.4 If Fuel Availability is Less
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5.7 Electrolyser Model An electroly
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original calculation of the amount
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5.8 Regenerative Fuel Cell Model A
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following the heat demand. To follo
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C:\ My Documents\ Nic\ Thesis\ Old\
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As 1 kWh = 3610.3 kJ, and using lit
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Add Heat to Water Storage Tank Usin
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Use Stored Hot Water to Supply Heat
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information is given about the over
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[23] K. Foger, B. Godfrey, “Syste
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the gasification and pyrolysis defi
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eing used each day for a continuous
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Where Biogas = Biogas production ra
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6.1.3 Use of Biogas Various options
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The amount of hydrogen that can be
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direct proportion, and the weight o
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produce in total (Nm 3 per tonne fe
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Electricity (kW) = Elec x Feed (6.1
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3. Make hydrogen via steam reformin
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Where Methane = Methane Production
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(continued) Keep as medium heating
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Yes Feed1 = Yield1 x Land1 / No. of
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production and energy use profiles
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If it is the last timestep of the p
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For each process, the process chara
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At the end of the simulation, graph
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As the time required for one batch
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Ethanol = Factor1 x Eth x Timesteps
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6.5 Electrolysis As it is sometimes
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6.7 Landfill Gas Processing As the
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Demand Profile Design & Profile Dat
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Figure 7.2 Degree-Days Versus Month
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Stage 1 - Sustainable Fuel Supply S
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The different profile of use graphs
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Figure 7.3 Fermentation System Inpu
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Figure 7.7 Fermentation System Info
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Figure 7.10 Fermentation System Out
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The output obtained when a second h
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Figure 7.16 Anaerobic Digestion Par
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Figure 7.19 Fermentation System Inp
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clarity. A constant supply rate of
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Figure 7.25 Heat Demand Profile Fig
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Figure 7.28 Effect of Minimum Load
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esidual heat demand as this would r
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Figure 7.35 Second Engine: Followin
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This chapter described how the over
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heat and electricity during the tou
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Figure 8.2: Overall Yearly Heat Dem
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to allow for efficient operation du
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would be incurred, and the scale of
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Figure 8.5: Electricity Supply and
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heat demand or both, or run at cons
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ut with 30% less land being require
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9 Conclusions and Recommendations T
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through these, technically viable p
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considered. The introduction of coo
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When considering larger geographica
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Appendix 1: Program Windows Figure
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Figure A1.5 CreateClimate.exe Figur
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Figure A1.9: Demand Profile Designe
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Figure A1.13: Derived Fuel Supply W
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Figure A1.17: Fermentation System D
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Figure A1.21: PV Electrolysis Syste
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Figure A1.25: Fuel Supply Profile D
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Figure A1.29: Auxilliary Supply Def
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Figure A1.33: Stirling Engine Syste
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Figure A1.37: Fuel Cell System Defi
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Figure A1.41: Electric Vehicle Syst
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Figure A1.45: Vehicle Conversion Fa
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Figure A1.49: Heating System Defini
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Figure A1.53: Pumped Hydro System D
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Figure A1.57: Auto Search Evaluatio
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PhD Thesis - Energy Systems Research Unit - University of Strathclyde

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