PhD Thesis - Energy Systems Research Unit - University of Strathclyde

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2.5.3 Transesterification The use of vegetable oils (straight or blended) in a diesel engine gives higher particulate emissions, reduced efficiency, and greater maintenance requirements compared to the use of conventional diesel. However, if these oils are transesterified to make methyl or ethyl esters (biodiesel), increased relative efficiency, and lower particulate emissions can be achieved, with little or no engine modifications necessary [68]. The transesterification process can use waste vegetable or animal oils, or specially grown energy crops with high oil yields (including soybeans, oilseed rape, olives, or sunflowers) as a feedstock. Where energy crops are used, energy in the forms of heat and/or electricity is required for oil extraction from the crop. The residue left after oil extraction can be used as cattle feed, put into an anaerobic digester or gasifier, or burned directly to produce heat and/or electricity, depending on the residue type, and energy requirements [69]. Small-scale production of biodiesel is batch-wise, where batches of up to 2000 litres can be processed, each batch taking around 10 hours to complete. Figure 2.6 shows the stages of a typical batch process for producing ‘backyard biodiesel’. If necessary, the oil is first filtered to remove particles, and boiled for between 30 to 60 minutes to remove any water, which is often required when waste oil is being used. Ethanol or methanol (between 10 to 15% of the amount of oil by volume) and a catalyst (sodium hydroxide or potassium hydroxide, around 1% by weight) are mixed together and added to the oil. This is mixed mechanically for around one hour, and then allowed to settle for about eight hours, to allow separation of the biodiesel and glycerine. The glycerine is drained off, and any soap in the mixture is removed, if necessary, by adding water and mixing, or bubbling air through the biodiesel. This, again, is allowed to settle, and the biodiesel is drained off, leaving the soapy water. This process yields around the same volume of biodiesel as oil that was input, and around the same volume of glycerine as alcohol that was input [24,70,71]. Glycerine is a valuable by-product that can be sold to the pharmaceuticals or explosives industry or used to make soap or cosmetics. 52
1. Scale for measuring out lye and chemical supplies used for a titration. 2. Sample of used oil about to be titrated. 3. Colour of titrated liquid sample when at the correct pH. 4. Weighing correct amount of lye. 5. Lighting burner under transesterifyer vessel. 6. View of sodium methoxide mixer (left) and transesterifyer vessel (right). 7. View of sodium methoxide mixer being drained into transesterifyer vessel (note thermometer). 8. Valve on bottom of transesterifyer vessel user to decant out more dense glycerine from less dense esters. 9. Fuel pump and filters -- these are used last, after soapy residues and lye have had time to settle out of biodiesel. 10. Overview of trailer-mounted processor: propane tank is for heating grease, PVC containers on either side are soap settling tanks for biodiesel prior to pumping through filters. Pick-up line for filter pump is inserted into tank only deep enough to siphon esters and not soaps on bottom. 11. The finished product. 12. Mike's original 5-gallon biodiesel mill. Figure 2.6 Biodiesel Production Process [71] 53
Page 1 and 2: Decision Support for New and Renewa
Page 3 and 4: Abstract The global requirement for
Page 5 and 6: CONTENTS 1 ENERGY SYSTEMS FOR SUSTA
Page 7 and 8: 5.5 Steam Turbine Model 149 5.6 Fue
Page 9 and 10: FIGURES Figure 1.1 Final Energy Con
Page 11 and 12: Figure 7.30 Following Electricity a
Page 13 and 14: on the use of fossil fuels, energy
Page 15 and 16: The general increase in energy cons
Page 17 and 18: supply is reduced or eliminated, lo
Page 19 and 20: Figure 1.3 The Electricity Supply G
Page 21 and 22: on different generation mixes depen
Page 23 and 24: Various studies have been carried o
Page 25 and 26: provision for smaller areas, and he
Page 27 and 28: 1.7 References [1] The Internationa
Page 29 and 30: 2 Options for New and Renewable Ene
Page 31 and 32: the amount of usable heat that is g
Page 33 and 34: the conversion of petrol cars; howe
Page 35 and 36: set times, producing a constant ele
Page 37 and 38: partial load. Fast response and sta
Page 39 and 40: 2.3 The Production and Storage of H
Page 41 and 42: dedicated boiler, which runs contin
Page 43 and 44: Figure 2.3 A Typical Hydrogen Filli
Page 45 and 46: part of the natural carbon cycle (a
Page 47 and 48: Figure 2.4 Layout of a Gasification
Page 49 and 50: met by process integration and the
Page 51: Figure 2.5 The Inputs and Outputs o
Page 55 and 56: feedstock being used. Sugary feedst
Page 57 and 58: carbon dioxide via steam reforming.
Page 59 and 60: • Where CHP is used, the balance
Page 61 and 62: [22] Vehicle Certification Agency (
Page 63 and 64: [55] M. A. Paisley, J. M. Irving, R
Page 65 and 66: 3 Approaches to Renewable Energy Sy
Page 67 and 68: Because of the intermittent nature
Page 69 and 70: A renewable energy supply evaluatio
Page 71 and 72: the system are kept. The output of
Page 73 and 74: There are various models available
Page 75 and 76: When the use of climate dependant i
Page 77 and 78: 3.5 References [1] M. Muselli, G. N
Page 79 and 80: 4 A Procedure for Demand and Supply
Page 81 and 82: pumped storage and flywheels), a ba
Page 83 and 84: for the agricultural vehicle use re
Page 85 and 86: Figure 4.4 Combining Demands to Tak
Page 87 and 88: ates for vehicles, engines and othe
Page 89 and 90: Figure 4.5 Derived Fuel Production
Page 91 and 92: together if desired, and taken forw
Page 93 and 94: profiles are output from this part
Page 95 and 96: dividing the production rate at eac
Page 97 and 98: As it would be too confusing to sho
Page 99 and 100: Figure 4.12 Output of the Matching
Page 101 and 102: However, when more than one transpo
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considered, this amount is added to
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users are alerted if there is not e
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at the matching stage, along with t
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vehicles if they are increased by 1
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If biogas is being considered, the
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The number of timesteps per hour wi
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After the algorithm has been follow
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• Float Charge - once the battery
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Discharge No tank = tank fuel used
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equired (kW) = maxkWh x bulk% (5.16
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An example of the output graph prod
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5.2.1 Required Power Specifically d
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5.2.3 Engine Performance in the Con
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used for gas powered ICEs, but the
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and five times, depending on the nu
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Is PL < Min ? No Is PL = 0 ? No Is
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where Max = maximum energy availabl
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where Ratiopart = heat to electrici
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(including following heat demand wh
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where SFC = specific fuel consumpti
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engines running respectively). If t
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(continued) Is Fuel Available > (4
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of the definition window for a Stir
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and continuous operation. Again, mu
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The performance of a fuel cell is n
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percentage loading, rather than usi
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Is Min = 0 ? No Is Min = PC1 ? No I
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5.6.4 If Fuel Availability is Less
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5.7 Electrolyser Model An electroly
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original calculation of the amount
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5.8 Regenerative Fuel Cell Model A
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following the heat demand. To follo
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C:\ My Documents\ Nic\ Thesis\ Old\
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As 1 kWh = 3610.3 kJ, and using lit
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Add Heat to Water Storage Tank Usin
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Use Stored Hot Water to Supply Heat
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information is given about the over
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[23] K. Foger, B. Godfrey, “Syste
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the gasification and pyrolysis defi
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eing used each day for a continuous
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Where Biogas = Biogas production ra
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6.1.3 Use of Biogas Various options
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The amount of hydrogen that can be
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direct proportion, and the weight o
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produce in total (Nm 3 per tonne fe
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Electricity (kW) = Elec x Feed (6.1
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3. Make hydrogen via steam reformin
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Where Methane = Methane Production
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(continued) Keep as medium heating
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Yes Feed1 = Yield1 x Land1 / No. of
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production and energy use profiles
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If it is the last timestep of the p
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For each process, the process chara
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At the end of the simulation, graph
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As the time required for one batch
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Ethanol = Factor1 x Eth x Timesteps
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6.5 Electrolysis As it is sometimes
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6.7 Landfill Gas Processing As the
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Demand Profile Design & Profile Dat
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Figure 7.2 Degree-Days Versus Month
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Stage 1 - Sustainable Fuel Supply S
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The different profile of use graphs
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Figure 7.3 Fermentation System Inpu
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Figure 7.7 Fermentation System Info
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Figure 7.10 Fermentation System Out
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The output obtained when a second h
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Figure 7.16 Anaerobic Digestion Par
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Figure 7.19 Fermentation System Inp
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clarity. A constant supply rate of
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Figure 7.25 Heat Demand Profile Fig
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Figure 7.28 Effect of Minimum Load
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esidual heat demand as this would r
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Figure 7.35 Second Engine: Followin
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This chapter described how the over
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heat and electricity during the tou
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Figure 8.2: Overall Yearly Heat Dem
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to allow for efficient operation du
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would be incurred, and the scale of
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Figure 8.5: Electricity Supply and
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heat demand or both, or run at cons
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ut with 30% less land being require
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9 Conclusions and Recommendations T
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through these, technically viable p
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considered. The introduction of coo
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When considering larger geographica
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Appendix 1: Program Windows Figure
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Figure A1.5 CreateClimate.exe Figur
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Figure A1.9: Demand Profile Designe
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Figure A1.13: Derived Fuel Supply W
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Figure A1.17: Fermentation System D
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Figure A1.21: PV Electrolysis Syste
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Figure A1.25: Fuel Supply Profile D
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Figure A1.29: Auxilliary Supply Def
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Figure A1.33: Stirling Engine Syste
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Figure A1.37: Fuel Cell System Defi
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Figure A1.41: Electric Vehicle Syst
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Figure A1.45: Vehicle Conversion Fa
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Figure A1.49: Heating System Defini
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Figure A1.53: Pumped Hydro System D
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Figure A1.57: Auto Search Evaluatio
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PhD Thesis - Energy Systems Research Unit - University of Strathclyde

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