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PhD Thesis - Energy Systems Research Unit - University of Strathclyde

PhD Thesis - Energy Systems Research Unit - University of Strathclyde

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Larger scale biodiesel production can take place through a continuous process<br />

that goes through the same stages as the batch process and is, therefore, not<br />

easily stopped and started [72]. The energy required for either process is around<br />

2% <strong>of</strong> the electricity and 3% <strong>of</strong> the heat that would be obtained from a typical<br />

suitable CHP plant using the fuel produced [73].<br />

A substantial amount <strong>of</strong> alcohol is required for this process, and methanol is the<br />

easier alcohol to use, though it is more difficult to make in a sustainable manner.<br />

Suitable processes are beginning to be developed using ethanol, which can be<br />

made by fermentation, as described in the next section. The batch<br />

transesterification process can be time consuming, and safety precautions must<br />

be taken at all stages due to the chemicals being used and the reactions taking<br />

place.<br />

2.5.4 Fermentation<br />

Fermentation is the biological conversion <strong>of</strong> sugar, starch or cellulose, to ethanol<br />

and carbon dioxide, through anaerobic respiration by yeast or other organisms.<br />

Roughly half <strong>of</strong> the weight <strong>of</strong> sugars is converted to ethanol, and half to carbon<br />

dioxide, and the ethanol produced has roughly 90% <strong>of</strong> the energy content <strong>of</strong> the<br />

sugars used, or roughly 96% <strong>of</strong> the heat <strong>of</strong> combustion <strong>of</strong> the cellulose used.<br />

The carbon dioxide produced is pure, and can be sold to industry [17].<br />

Possible feedstocks for fermentation include sugar cane, sugar beet, fruit waste,<br />

wheat, cereals, potatoes, wood, newspapers, and municipal waste. Of these<br />

feedstocks, grains can be stored without degradation, but tubers, fruits and beet<br />

crops rot rapidly once harvested, and should be used as soon as possible. Any<br />

crop residues remaining after the harvest <strong>of</strong> energy crops, can be burned directly<br />

to produce heat and/or electricity, or put into an anaerobic digester or gasifier,<br />

depending on the residue type, and energy needs [74].<br />

Pre-treatment <strong>of</strong> the feedstock is required to produce simple, fermentable sugars<br />

(glucose and fructose), and the type <strong>of</strong> pre-treatment required depends on the<br />

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