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PhD Thesis - Energy Systems Research Unit - University of Strathclyde

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6.3 Transesterification<br />

Transesterification is the production <strong>of</strong> methyl or ethyl esters (biodiesel) from<br />

animal or vegetable oils. The feedstock for this process may be continuously<br />

available (waste vegetable or animal oils), or seasonal (energy crops). Smallscale<br />

production is batch-wise, and larger scale continuous processes are being<br />

developed [7]. An example <strong>of</strong> the transesterification system definition window<br />

is given in Appendix 1, Figure A1.16.<br />

6.3.1 Feedstock Availability<br />

Feedstock availability, for continuous and seasonal supplies, is dealt with in a<br />

similar manner to that described in Section 6.1.1. For seasonal supplies, the oil<br />

availability per day is calculated using Equation 6.3, where the crop yield is in<br />

litres <strong>of</strong> oil per hectare. The electricity and heat required for oil extraction from<br />

energy crops, if necessary, are calculated using Equation 6.1 or 6.2 (substituting<br />

the heat requirement where appropriate), and are applied during the appropriate<br />

times. As it is common to use the same equipment to process oils from different<br />

harvest crops at different times <strong>of</strong> the year, to allow a more continual use, up to<br />

five different seasonal supplies may be defined for use by the same processing<br />

equipment. These are all added into the same store, as they become available, as<br />

the performance <strong>of</strong> the processing equipment and process requirements are not<br />

significantly affected by the use <strong>of</strong> different feedstocks. This process is shown<br />

in Figure 6.5.<br />

Again, the rate <strong>of</strong> use <strong>of</strong> oil from seasonal supplies may be slower than the<br />

production rate to allow fuel production beyond the harvest periods. For<br />

seasonal supplies, if there is excess feedstock left over in the store at the end <strong>of</strong><br />

the simulation period, and this is more than the minimum required for the fuel<br />

production process, the entire simulation period is analysed again, and the<br />

results from this second simulation period are used.<br />

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