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From linear regression <strong>the</strong> const<strong>an</strong>ts could be determined. The resulting expression with a<br />

variable temperature gradient is:<br />

Accounting for <strong>the</strong>rmal diffusivity did prove more complex because variable diffusivity does<br />

not relate linearly to H. Instead <strong>the</strong> logarithm of <strong>the</strong> ratio between <strong>the</strong> adjusted <strong>the</strong>rmal diffusivity<br />

to <strong>the</strong> diffusivity of ice(Diff/Diff ice ) did prove invariable with H. Fig 2 shows this relation for<br />

T ice = –10 °C.<br />

For T(ice)=-10 °C<br />

0,0007<br />

0,00065<br />

0,0006<br />

0,00055<br />

0,0005<br />

0,00045<br />

0,0004<br />

0,00035<br />

0,0003<br />

-1,5 -1 -0,5 0<br />

Figure 2. The ch<strong>an</strong>ge in SI formation <strong>as</strong> a function of <strong>the</strong> property Diff/Diffice The resulting expression with<br />

variable diffusivity becomes.<br />

When combining <strong>the</strong> contribution from temperature gradient <strong>an</strong>d <strong>the</strong>rmal diffusivity,<br />

respectively, <strong>the</strong> final equation becomes:<br />

CONCLUSIONS<br />

⎛ dT ⎞<br />

H ( t)<br />

= ⎜k<br />

2 − Tsk1⎟<br />

⎝ dx ⎠<br />

⎛ ⎛ ⎜ ⎛ ⎛<br />

f<br />

⎞<br />

H t = ⎜Ts⎜<br />

⎜ ⎜κ<br />

⎟<br />

( ) k1−<br />

k<br />

⎜ ⎜<br />

⎜ 3ln⎜<br />

⎟<br />

⎜ ⎜ ⎜ κi<br />

⎟<br />

⎝ ⎝ ⎝ ⎝ ⎠<br />

t<br />

⎞<br />

⎞<br />

⎟<br />

⎟<br />

⎟<br />

⎟<br />

⎟<br />

⎟<br />

⎠ ⎠<br />

⎞<br />

⎟<br />

⎠<br />

⎛ ⎛ dT ⎜ ⎛ ⎛<br />

f<br />

H t = ⎜k<br />

Ts<br />

⎜<br />

− ⎜<br />

⎜ ⎜κ<br />

( ) 2<br />

k1−<br />

k ⎜<br />

⎜ 3ln⎜<br />

i<br />

⎝ dx ⎜ ⎜ ⎜ κ<br />

⎝ ⎝ ⎝<br />

A parameterization <strong>as</strong> addition to <strong>the</strong> Neum<strong>an</strong> solution h<strong>as</strong> been derived valid for temperature<br />

gradients r<strong>an</strong>ging from –1 to 0.5 K/m. It is believed that gradients exceeding this r<strong>an</strong>ge do not<br />

occur over longer time in nature. The const<strong>an</strong>ts were found to be robust over a temperature r<strong>an</strong>ge<br />

of at le<strong>as</strong>t 10 K.<br />

As a second addition to <strong>the</strong> Neum<strong>an</strong>n solution <strong>the</strong> effect of variable <strong>the</strong>rmal diffusivity is<br />

examined <strong>an</strong>d parameterized. Here a logarithmic term did prove to be <strong>the</strong> best solution. The<br />

motivation for deriving <strong>the</strong> diffusivity term is because <strong>the</strong> parameterization <strong>the</strong>n also becomes<br />

t<br />

249<br />

⎞<br />

⎞ ⎞⎟<br />

⎟ ⎟<br />

⎟<br />

⎟<br />

⎟<br />

⎟ ⎟<br />

⎟<br />

⎠<br />

⎟<br />

⎠⎠<br />

⎞<br />

⎟<br />

⎠<br />

t

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