05.08.2013 Views

ORNL-5388 - the Molten Salt Energy Technologies Web Site

ORNL-5388 - the Molten Salt Energy Technologies Web Site

ORNL-5388 - the Molten Salt Energy Technologies Web Site

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

u A-1<br />

Aerodynamic Methods<br />

7<br />

Both <strong>the</strong> separation nozzle and <strong>the</strong> stationary-walled centrifuge can be<br />

classed as aerodynamic processes. These are considered to be competitive processes<br />

by <strong>the</strong>ir proponents and plans for <strong>the</strong>ir implementation are well advanced. Research<br />

efforts have been directed at several o<strong>the</strong>r aerodynamic methods such as <strong>the</strong> vortex<br />

tube, <strong>the</strong> separation probe, crossed beams, velocity slip and <strong>the</strong> jet membrane. None<br />

of <strong>the</strong>se appear at <strong>the</strong> present time to offer <strong>the</strong> promise of <strong>the</strong> two aforementioned<br />

aerodynamic processes, although an expanded effort is proceeding on <strong>the</strong> jet membrane<br />

process.<br />

Commonly known as <strong>the</strong> Muntz-Hamel process, it involves <strong>the</strong> penetration of<br />

a stream of UF6 gas into an expanding jet of easily condensible carrier gas. The<br />

lighter 235UF6 molecules penetrate <strong>the</strong> jet more easily than <strong>the</strong> heavier 238UF6<br />

molecules. A tube placed on <strong>the</strong> axis of <strong>the</strong> jet collects <strong>the</strong> enriched UF6.<br />

depleted UF6 flows out of <strong>the</strong> o<strong>the</strong>r end of <strong>the</strong> scattering chamber, after <strong>the</strong> carrier<br />

gas is separated from it by condensation.<br />

Plasma-Based Processes<br />

Since a plasma can be made to rotate at speeds greater than that of an ultra-<br />

centrifuge, it occurred to various investigators that such high speed gas rotation<br />

without <strong>the</strong> use of revolving equipment might possibly be developed into a more<br />

efficient isotope separation process than that based on a mechanical centrifuge.<br />

Five papers on this topic were presented at <strong>the</strong> International Conference on Uranium<br />

Isotope Separation in London in March 1975. The authors’ assessment of <strong>the</strong> prospects<br />

for such a process ran <strong>the</strong> gamut from highly optimistic--technology is simple and well<br />

known so that minimal development will be required--to pessimistic--a rotating plasma<br />

process cannot possibly be economically competitive.<br />

separated uranium isotopes by means of <strong>the</strong> plasma centrifuge.<br />

The<br />

To our knowledge, no one has<br />

Since that time, several o<strong>the</strong>r plasma-based processes have been proposed.<br />

all <strong>the</strong>se processes, <strong>the</strong> currently most feasible seems to be <strong>the</strong> Plasma Ion Enrichment<br />

process (<strong>the</strong> Dawson separation process). In this process a plasma of uF6 (or of<br />

uranium atoms) within a strong uniform magnetic field is exposed to a low energy<br />

radio-frequency wave resonant with <strong>the</strong> cyclotron frequency of <strong>the</strong> 235UF6 ions. The<br />

rotation <strong>the</strong>reby imparted preferentially to <strong>the</strong> 235UF6 ions enables <strong>the</strong> 235U to be<br />

separated from <strong>the</strong> 238U by properly placed collection plates.<br />

tassium.<br />

This method has been used successfully to enrich macroscopic samples of po-<br />

The collector was a cooled tungsten ribbon having a voltage bias to<br />

collect selectively <strong>the</strong> excited ions. The potassium vapor was contact ionized at<br />

<strong>the</strong> entrance to <strong>the</strong> mass spectrometer. To eliminate spurious effects, samples were<br />

collected under three conditions of rf excitation: (1) no rf; (2) excitation at <strong>the</strong><br />

39K cyclotron frequency; and (3) excitation at <strong>the</strong> 41K cyclotron frequency. The<br />

Of

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!