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ORNL-5388 - the Molten Salt Energy Technologies Web Site

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resulting ratios of 41K/39K abundance as measured by <strong>the</strong> mass spectrometer were,<br />

respectively, 0.07 (<strong>the</strong> natural abundance), 0.02 and 4. The abundance ratio of 4<br />

A-18<br />

corresponds to a more than tenfold enrichment of '+lK.<br />

In addition to potassium ions, work has been done on neon, argon, xenon and<br />

uranium toward resolving <strong>the</strong> ion cyclotron resonances for individual positive ions.<br />

The work with uranium is proceeding toward estimates of realistic operating parameters<br />

(ion densities, magnetic field strength, isotopic excitation energies, device length,<br />

ion temperatures, and collector types).<br />

A second process involves <strong>the</strong> achievement of a UF6 plasma by chemi-ionization.<br />

UF6 molecules are accelerated by expansion with an inert carrier gas through a<br />

supersonic jet. A cross beam of alkali metal molecules results in <strong>the</strong> formation of<br />

NA' or Cs' and UF6'. A radio-frequency quadrupole mass filter deflects <strong>the</strong> 238UF6<br />

out of <strong>the</strong> plasma beam, permitting <strong>the</strong> separation of <strong>the</strong> two isotopes by collection<br />

of <strong>the</strong> two beams on separate baffles cooled by liquid nitrogen. This process seems<br />

to have less potential than <strong>the</strong> first.<br />

Comparison of Advanced Separation Processes<br />

The estimated costs of <strong>the</strong> processes mentioned are compared in Table A-3<br />

with that of gaseous diffusion. With two exceptions, <strong>the</strong> table is based on process<br />

evaluations made by <strong>the</strong> Nuclear Division of <strong>the</strong> Union Carbide Corporation17 for<br />

ERDA. For <strong>the</strong> exceptions, which are <strong>the</strong> FRG's separation nozzle and South Africa's<br />

stationary-walled centrifuge, <strong>the</strong> comparison is based on published statements by <strong>the</strong><br />

developers of <strong>the</strong> process. Of all <strong>the</strong> processes listed, only <strong>the</strong> costs for <strong>the</strong><br />

centrifuge, and possibly for <strong>the</strong> separation nozzle, are known with any degree<br />

of certainty .<br />

I<br />

r;<br />

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