II International Symposium on Carbon for Catalysis ABSTRACTS

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PP-I-2 6OH − + C − 4 e = CO + 3H2O (8) 2− 3 and the reaction which involves oxide ions formed by the reaction (3). In the Na 2 CO 3 -K 2 CO 3 melt carbonate ions discharge in stages: 3O 2− 2− + C − 4 e = CO 3 , (9) CO + C − 2 e = CO ads + CO 2 , (10) 2− 3 CO + COads − 2 e = 2CO 2 . (11) 2− 3 The reactions (10) and (11) represent reactions of electrochemical adsorption and desorption respectively. The study revealed that the processes taking place on glassy-carbon anodes in ionic melts are irreversible. The anodes fail as a result of electrochemical oxidation. This study was supported by RFBR-Ural (Project No. 04-03-96113) and RFBR (Project No. 04-03-08113 ofi). References 1 Nekrasov V.N., Barbin N.M., Ivanovsky L.E. Study of the anodic process on a glassycarbon electrode in the NaCl-KCl-Li 2 O melt using voltammetry with a linear potential scan. Rasplavy. 1989. No. 6. pp. 55-64. 2 Nekrasov V.N., Barbin N.M., Pekar A.P. Polarization measurements on carbon and noble-metal electrodes in the NaCl-KCl-Na 2 CO 3 melt. Elektrokhimiya. 1997. No. 3. pp. 273-279. 3 Nekrasov V.N., Barbin N.M., Pekar A.P. Mechanism of anodic processes on carbon and noble-metal electrodes in the NaCl-KCl-Na 2 CO 3 melt. Elektrokhimiya. 1997. No. 3. pp. 280-283. 4 Filyaev A.T., Barbin N.M. Study of oxidation-reduction processes on a glassy-carbon electrode in an alkaline melt. Rasplavy. 2002. No. 3. pp. 64-75. 122
TEMPLATED SYNTHESIS OF NOBLE METAL CONTAINING CARBONS PP-I-3 Böhme K., Klepel O. Universität Leipzig, Institut für Technische Chemie, Linnéstr. 3, D-04103 Leipzig, Germany e-mail: klepel@chemie.uni-leipzig.de Introduction Activated carbons are widely used as noble metal supports for reactions such as liquid phase hydrogenation, dehydrogenation or oxidation. Since they have been originally prepared by carbonisation of natural precursors like wood or coal, their chemical and textural properties are often not well defined. Therefore, many efforts have been taken to develop carbon materials with improved properties. In the last seven years novel synthesis methods by using solid templates have been described [1]. The synthesis includes filling of an inorganic porous material (i.e. the template) with carbon precursor followed by carbonization and calcination steps. After removal of the inorganic material a carbon replica can be obtained. The aim of the present study was to advance this method by introduction of a metal compound. The use of a carbon precursor solution containing the metal compound results in a carbon material which possesses (partly) embedded metal particles in the pore walls. In such a way, the dispersity and the stability of the metal particles should be improved. Experimental All carbon materials were prepared by templated synthesis whereas two different ways of metal incorporation were applied. First, the carbon was synthesized following a procedure described elsewhere [2] and then loaded with the noble metal (5 wt. %) by impregnation. The alternative route combines the carbon synthesis and the modification with the metal compound in one step (in-situ): The template was impregnated using a solution of sucrose, hexachloroplatinic acid and water. After carbonization and calcination the obtained Pt/C/Si composite was reduced for 3 h at 400°C in hydrogen and then treated with HF solution. The prepared samples were characterized by N 2 -adsorption, XRD-measurements, CO chemisorption, thermo analysis, elemental analysis, and catalytic test reaction (glucose oxidation). 123
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Boreskov Institute of Catalysis of
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ORGANIZING COMMITTEE Chairman: Vlad
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CATALYSTS ON CARBON MATERIALS BASIS
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PREPARATION OF CARBON FILMS ON CERA
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PL-2 polymer gas separation membran
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CHARACTERIZATION OF POROUS STRUCTUR
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ROLE OF CARBON POROSITY AND FUNCTIO
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KEYNOTE LECTURES
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KL-1 governed by the equation of th
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KL-2 NITROGEN DOPED CARBON NANOFIBE
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KL-3 CARBON BASED STRUCTURED CATALY
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KL-4 The strong mesoporous carbons
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KL-5 NANOSTRUCTURED CARBONS FOR THE
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KL-6 THEORY OF MECHANICAL BEHAVIOR
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KL-7 MOLECULAR STRUCTURE EFFECT OF
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Presentation of FGUP “ENPO Neorga
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OP-I-1 COBALT ON CARBON NANOFIBER C
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OP-I-1 from 41 to 23 %, while the C
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OP-I-2 loading. It is also interest
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OP-I-3 5 nm 50 nm Figure 1: PtRu/MW
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OP-I-4 As it can be seen, potassium
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OP-I-5 [A] ⇔ A+[ ] (5) Kinetic an
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Results and discussion OP-I-6 The T
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OP-I-7 product selectivity). The an
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OP-I-8 After introduction of the me
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OP-I-9 Hydrogenations were carried
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OP-I-10 activated with CO 2 . In al
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OP-I-11 from Jaroszów deposit, Low
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OP-I-12 The carbon matrix avoids th
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OP-I-13 • thermal destruction of
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OP-I-14 hexanol (AA) was anchored t
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OP-I-15 removing the physically ads
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OP-I-16 surface concentration of HE
Page 71 and 72: Our analysis of the chemical activi
Page 73 and 74: OP-I-18 running. The TEM reveals th
Page 75 and 76: OP-I-19 explore the role of CNF sur
Page 77 and 78: pH 10 8 6 4 2 0 2 4 6 8 10 ml HCl a
Page 79 and 80: OP-I-21 resorcinol to catalyst mola
Page 81 and 82: OP-I-22 AS in the catalysts examine
Page 83 and 84: OP-I-23 polyfunctional surface cove
Page 85 and 86: OP-I-24 as sibunite and nanofibrous
Page 87 and 88: OP-I-25 is a consequence of the mac
Page 89 and 90: OP-I-27 THE CARBON FILMS ON Pt(111)
Page 91 and 92: OP-I-28 LASER RAMAN MICRO-SPECTROSC
Page 93 and 94: OP-I-29 ELECTROCATALYTIC PROPERTIES
Page 95 and 96: OP-II-1 SYNTHESIS
Page 97 and 98: OP-II-2 SYNTHESIS,
Page 99 and 100: TOWARDS LARGE SCALE PRODUCTION OF C
Page 101 and 102: CO-CARBONIZATION OF POLYMERS - NEW
Page 103 and 104: OP-II-5 3. Results
Page 105 and 106: OP-II-6 pore size
Page 107 and 108: OP-II-7 their adva
Page 109 and 110: OP-II-8 effect, el
Page 111 and 112: OP-II-9 Therefore,
Page 113 and 114: OP-II-10 The dehyd
Page 115: OP-II-11 a result
Page 119 and 120: INVESTIGATION OF THE ELECTROCHEMICA
Page 121: SURFACE ELECTROCHEMISTRY OF CARBON
Page 125 and 126: PROPERTIES AND STRUCTURE OF SORBENT
Page 127 and 128: CATALYSIS DURING SULPHUR COALS PROC
Page 129 and 130: ORDERED MESOPOROUS CARBONS SYNTHESI
Page 131 and 132: PP-I-7 INFLUENCE OF FUNCTIONALIZATI
Page 133 and 134: PP-I-8 AROMATIZATION OF 5-PHENYL-PI
Page 135 and 136: N 2 O CONVERSION USING BINARY MIXTU
Page 137 and 138: PP-I-9 [8] F. Gonçalves, G.E. Marn
Page 139 and 140: PP-I-10 The Table 1 demonstrates th
Page 141 and 142: PP-I-11 We suppose that the active
Page 143 and 144: PP-I-12 Activation with steam promo
Page 145 and 146: PP-I-13 separation of bundles forme
Page 147 and 148: PP-I-14 temperature at which the ma
Page 149 and 150: PP-I-15 Titania was prepared by hyd
Page 151 and 152: PP-I-16 A B Figure 1. SEM images co
Page 153 and 154: PP-I-17 the carbon matrix has been
Page 155 and 156: PP-I-18 0.9 0.8 0.7 0.6 lg (ΔV/ΔR
Page 157 and 158: PP-I-19 Electron-microscopic studie
Page 159 and 160: PP-I-20 time on stream increased fr
Page 161 and 162: CARBON-SUPPORTED 12-MOLYBDOPHOSPHOR
Page 163 and 164: PP-I-23 CARBON SUPPORTS FOR IMMOBIL
Page 165 and 166: PP-I-24 example, in the polymer ele
Page 167 and 168: PP-I-25 of microporous structure wa
Page 169 and 170: PP-I-26 contain at first. Non-oxida
Page 171 and 172: PP-I-27 this reaction and that the
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CONTROLLING DIAMETER AND PRESENCE O
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INFLUENCE OF GAS OXIDATIVE TREATMEN
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PP-I-30 EXPERIMENTAL VALUES OF THE
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PP-I-30 Acknowledgements The author
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PP-I-31 suspensions of UFD had low
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PP-I-32 It was detected, that precu
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PP-I-33 consistence of the process,
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PP-I-34 practically identical [2],
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PP-I-35 • surface porosity (P 245
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PP-I-36 (COOH+OH), mg-eq/g 1,8 1,2
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PP-I-37 As one can see in the table
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PP-I-38 hydrogenation (61 o and 65
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PP-I-39 Ensembles №№ 31, 45, 55
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PP-I-40 The pore structure of origi
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PP-I-41 Sr 2+ and Ba 2+ ions are in
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PP-I-42 volume are formed from init
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PP-I-43 30 wt% Pt-15 wt% Ru/NCM cat
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PP-I-44 Figure 1. From left to righ
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PP-I-45 Table 1: Characteristics of
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PP-I-45 The search for alternative
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PP-I-46 zeroth moment expression, w
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PP-I-47 It was revealed, that the i
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PP-I-48 Table 1 Characteristics of
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PP-I-49 4-Carboxybenzaldehyde (4-CB
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PP-I-50 Computational details First
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PP-I-51 The result showed that surf
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PP-II-1 COOH COO(C
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PP-II-2 The result
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PP-II-3 prepared,
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PP-II-4 CNF from b
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PP-II-5 support; t
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PP-II-6 The main p
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PP-II-7 porous net
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PP-II-8 It is note
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PP-II-9 selective
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STABILITY OF A CARBON CATALYST FLUI
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PP-II-11 CARBON FI
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PP-II-12 CATALYTIC
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THE SORBENTS FOR AIR CLEANING PREPA
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MACRO-SHAPING OF CARBON NANOFIBERS
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PP-II-15 MESOPOROU
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PP-II-16 EVALUATIO
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PP-II-16 As it wou
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PP-II-17 with exis
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PP-II-18 Thus, the
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PP-II-19 (NaOH, Cs
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PP-II-20 MEDICAL C
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PP-II-21 Pt /AC an
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PP-II-22 Prelimina
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FACTORS DETERMINING THE CATALYTIC P
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NANOPOROUS CARBON MATERIALS AS EFFE
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CARBON NANOSTRUCTURAL MATERIALS PRO
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GROWTH OF CARBON NANOFIBERS ON META
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ACTIVE CARBON AS SUPPORT FOR IMMOBI
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PP-II-28 USING OF
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AKSOYLU Ahmet Erhan Department of C
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DIDENKO Olga Pisarzhevskii Institut
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KOGAN Victor M. Zelinsky Institute
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NOUGMANOV Evgeniy Lomonosov Moscow
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SERP Philippe INPToulouse 118 Route
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ZAITSEV Yurij P. Institute for Sorp
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steel, Hastelloy C22, Titanium, Tan
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Условия эксплуатац
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DONAU LAB MOSCOW ПРОГРАММА
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CONTENT PLENARY LECTURES...........
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OP-I-12 Maldonado-Hódar F.J., Carr
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OP-II-8 Isse A.A.,
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PP-I-21 Karaseva M.S., Perederiy M.
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PP-I-47 Zaitsev Yu., Zhuravsky S.,
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PP-II-21 Özkara S
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II International Symposium on Carbon for Catalysis ABSTRACTS

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