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II International Symposium on Carbon for Catalysis ABSTRACTS

II International Symposium on Carbon for Catalysis ABSTRACTS

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PP-I-44<br />

Figure 1. From left to right, TEM and SEM of MWNTs, and TEM of the heat-treated MWNTs<br />

The treatment at 2600°C decreases the specific surface area, removes the oxygenate groups <strong>on</strong><br />

the carb<strong>on</strong> surfaces and increases the purity <strong>on</strong> the MWNTs. The heat treated MWNTs used<br />

as catalysts <strong>for</strong> the 9,10-dihydroanthracene oxidati<strong>on</strong> in anthracene, shows a better catalytic<br />

activity compared to MWNTs without post-treatment and to expensed carb<strong>on</strong>. The carb<strong>on</strong><br />

graphitizati<strong>on</strong> level and the lower oxygen c<strong>on</strong>centrati<strong>on</strong> <strong>on</strong> the heat-treated carb<strong>on</strong> nanotubes,<br />

which favorises the reactants adsorpti<strong>on</strong> <strong>on</strong> the nanotubes surface, increase the<br />

di-hydroanthracene c<strong>on</strong>versi<strong>on</strong> into anthracene. Similar results have already been obtained.<br />

The authors have observed a c<strong>on</strong>versi<strong>on</strong> reaching 93 % over activated charcoal in the same<br />

reacti<strong>on</strong> c<strong>on</strong>diti<strong>on</strong>s [8].<br />

References<br />

[1] Iijima S., Nature, 1991, 354, 56-58<br />

[2] Ajayan P.M., Chem. Rev., 1999, 99, 1787-1800<br />

[3] Ebbesen T.W. (Ed.), Carb<strong>on</strong> Nanotubes. Preparati<strong>on</strong> and Properties, CRC Press,<br />

New-York, 1997<br />

[4] B<strong>on</strong>ard J.M. and al., Eur. Chem. Chr<strong>on</strong>icle 3, 1998, 9-16, 1-9<br />

[5] Pham-Huu C. and al., Chem. Commun., 2000, 19, 1871-1872<br />

[6] Ledoux M. J., Pham-Huu C., Catal. Today, 2005, 102-103, 2-14<br />

[7] Louis B. and al., Catal. Today, 2005, 102-103, 23-28<br />

[8] Nakamichi and al. J. Org. Chem., 2003, 68, 8272-8273<br />

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