II International Symposium on Carbon for Catalysis ABSTRACTS

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PP-I-16 METALS SUPPORTED ON CARBON-BASED HONEYCOMB MONOLITHS: INFLUENCE OF THE PREPARATION METHOD ON THE TEXTURAL AND STRUCTURAL PROPERTIES Harti S., Cifredo G. 1 , Gatica J.M. 1 , Chafik T, Vidal H. 1 Laboratoire des Procédés et Matériaux de Dépollutions. Faculté des Sciences et Techniques de Tanger, Université Abdelmalek Essaadi, BP 416 Tanger, Morocco 1 Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, 11510 Puerto Real, Spain e-mail: hilario.vidal@uca.es In this work different catalysts constituted by copper and manganese supported on carbonbased honeycomb monoliths obtained at lab scale have been prepared with a further intention of using them for Selective Catalytic Reduction of nitrogen oxides. The main scope at this stage was to study the influence of the metal phase incorporation procedure on the final textural and structural properties of the catalysts. For this purpose the following preparative variables were investigated: 1) the way of introducing the metal, either by impregnation of the monoliths with a precursor solution or through its integration in the paste before the extrusion or even by homogeneous deposition-precipitation from urea decomposition; 2) the concentration of the precursor solution in those catalysts prepared via impregnation technique (1M or 2M); 3) the time of contact between the monoliths and such solution (ranging from 30 to 90 minutes); 4) the use or not of a support pre-treatment with HNO 3 and/or NaOH, and 5) the drying method (conventional or using microwaves) (see Figure 1). X-Ray Fluorescence, Inductively Coupled Plasma Spectroscopy (ICP-AES) and Scanning Electron Microscopy with Energy Dispersive Spectroscopy (EDS) have been used as complementary techniques to analyze the metal loading of the catalysts. In addition, isotherms of N 2 adsorption at 77 K have shown significant differences both in the specific surface area and the porosity of the samples. Finally, X-Ray diffraction has allowed to identify the metal phases present in each catalyst and to obtain data of the metal dispersion. 150
PP-I-16 A B Figure 1. SEM images corresponding to two supported Cu catalysts prepared following the same technique (impregnation), from equal precursors (1M nitrate solution), after same contact time with the monolith (30 min), both without support pre-treatment, and just differing in the final drying method: A) in air at 80 ºC overnight; B) using microwaves (1 min). After being dried, both catalysts were treated in Ar at 250ºC. 151
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Boreskov Institute of Catalysis of
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ORGANIZING COMMITTEE Chairman: Vlad
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CATALYSTS ON CARBON MATERIALS BASIS
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PREPARATION OF CARBON FILMS ON CERA
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PL-2 polymer gas separation membran
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CHARACTERIZATION OF POROUS STRUCTUR
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ROLE OF CARBON POROSITY AND FUNCTIO
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KEYNOTE LECTURES
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KL-1 governed by the equation of th
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KL-2 NITROGEN DOPED CARBON NANOFIBE
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KL-3 CARBON BASED STRUCTURED CATALY
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KL-4 The strong mesoporous carbons
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KL-5 NANOSTRUCTURED CARBONS FOR THE
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KL-6 THEORY OF MECHANICAL BEHAVIOR
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KL-7 MOLECULAR STRUCTURE EFFECT OF
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Presentation of FGUP “ENPO Neorga
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OP-I-1 COBALT ON CARBON NANOFIBER C
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OP-I-1 from 41 to 23 %, while the C
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OP-I-2 loading. It is also interest
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OP-I-3 5 nm 50 nm Figure 1: PtRu/MW
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OP-I-4 As it can be seen, potassium
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OP-I-5 [A] ⇔ A+[ ] (5) Kinetic an
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Results and discussion OP-I-6 The T
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OP-I-7 product selectivity). The an
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OP-I-8 After introduction of the me
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OP-I-9 Hydrogenations were carried
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OP-I-10 activated with CO 2 . In al
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OP-I-11 from Jaroszów deposit, Low
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OP-I-12 The carbon matrix avoids th
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OP-I-13 • thermal destruction of
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OP-I-14 hexanol (AA) was anchored t
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OP-I-15 removing the physically ads
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OP-I-16 surface concentration of HE
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Our analysis of the chemical activi
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OP-I-18 running. The TEM reveals th
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OP-I-19 explore the role of CNF sur
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pH 10 8 6 4 2 0 2 4 6 8 10 ml HCl a
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OP-I-21 resorcinol to catalyst mola
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OP-I-22 AS in the catalysts examine
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OP-I-23 polyfunctional surface cove
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OP-I-24 as sibunite and nanofibrous
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OP-I-25 is a consequence of the mac
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OP-I-27 THE CARBON FILMS ON Pt(111)
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OP-I-28 LASER RAMAN MICRO-SPECTROSC
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OP-I-29 ELECTROCATALYTIC PROPERTIES
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OP-II-1 SYNTHESIS
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OP-II-2 SYNTHESIS,
Page 99 and 100: TOWARDS LARGE SCALE PRODUCTION OF C
Page 101 and 102: CO-CARBONIZATION OF POLYMERS - NEW
Page 103 and 104: OP-II-5 3. Results
Page 105 and 106: OP-II-6 pore size
Page 107 and 108: OP-II-7 their adva
Page 109 and 110: OP-II-8 effect, el
Page 111 and 112: OP-II-9 Therefore,
Page 113 and 114: OP-II-10 The dehyd
Page 115: OP-II-11 a result
Page 119 and 120: INVESTIGATION OF THE ELECTROCHEMICA
Page 121 and 122: SURFACE ELECTROCHEMISTRY OF CARBON
Page 123 and 124: TEMPLATED SYNTHESIS OF NOBLE METAL
Page 125 and 126: PROPERTIES AND STRUCTURE OF SORBENT
Page 127 and 128: CATALYSIS DURING SULPHUR COALS PROC
Page 129 and 130: ORDERED MESOPOROUS CARBONS SYNTHESI
Page 131 and 132: PP-I-7 INFLUENCE OF FUNCTIONALIZATI
Page 133 and 134: PP-I-8 AROMATIZATION OF 5-PHENYL-PI
Page 135 and 136: N 2 O CONVERSION USING BINARY MIXTU
Page 137 and 138: PP-I-9 [8] F. Gonçalves, G.E. Marn
Page 139 and 140: PP-I-10 The Table 1 demonstrates th
Page 141 and 142: PP-I-11 We suppose that the active
Page 143 and 144: PP-I-12 Activation with steam promo
Page 145 and 146: PP-I-13 separation of bundles forme
Page 147 and 148: PP-I-14 temperature at which the ma
Page 149: PP-I-15 Titania was prepared by hyd
Page 153 and 154: PP-I-17 the carbon matrix has been
Page 155 and 156: PP-I-18 0.9 0.8 0.7 0.6 lg (ΔV/ΔR
Page 157 and 158: PP-I-19 Electron-microscopic studie
Page 159 and 160: PP-I-20 time on stream increased fr
Page 161 and 162: CARBON-SUPPORTED 12-MOLYBDOPHOSPHOR
Page 163 and 164: PP-I-23 CARBON SUPPORTS FOR IMMOBIL
Page 165 and 166: PP-I-24 example, in the polymer ele
Page 167 and 168: PP-I-25 of microporous structure wa
Page 169 and 170: PP-I-26 contain at first. Non-oxida
Page 171 and 172: PP-I-27 this reaction and that the
Page 173 and 174: CONTROLLING DIAMETER AND PRESENCE O
Page 175 and 176: INFLUENCE OF GAS OXIDATIVE TREATMEN
Page 177 and 178: PP-I-30 EXPERIMENTAL VALUES OF THE
Page 179 and 180: PP-I-30 Acknowledgements The author
Page 181 and 182: PP-I-31 suspensions of UFD had low
Page 183 and 184: PP-I-32 It was detected, that precu
Page 185 and 186: PP-I-33 consistence of the process,
Page 187 and 188: PP-I-34 practically identical [2],
Page 189 and 190: PP-I-35 • surface porosity (P 245
Page 191 and 192: PP-I-36 (COOH+OH), mg-eq/g 1,8 1,2
Page 193 and 194: PP-I-37 As one can see in the table
Page 195 and 196: PP-I-38 hydrogenation (61 o and 65
Page 197 and 198: PP-I-39 Ensembles №№ 31, 45, 55
Page 199 and 200: PP-I-40 The pore structure of origi
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PP-I-41 Sr 2+ and Ba 2+ ions are in
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PP-I-42 volume are formed from init
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PP-I-43 30 wt% Pt-15 wt% Ru/NCM cat
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PP-I-44 Figure 1. From left to righ
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PP-I-45 Table 1: Characteristics of
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PP-I-45 The search for alternative
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PP-I-46 zeroth moment expression, w
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PP-I-47 It was revealed, that the i
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PP-I-48 Table 1 Characteristics of
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PP-I-49 4-Carboxybenzaldehyde (4-CB
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PP-I-50 Computational details First
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PP-I-51 The result showed that surf
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PP-II-1 COOH COO(C
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PP-II-2 The result
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PP-II-3 prepared,
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PP-II-4 CNF from b
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PP-II-5 support; t
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PP-II-6 The main p
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PP-II-7 porous net
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PP-II-8 It is note
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PP-II-9 selective
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STABILITY OF A CARBON CATALYST FLUI
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PP-II-11 CARBON FI
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PP-II-12 CATALYTIC
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THE SORBENTS FOR AIR CLEANING PREPA
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MACRO-SHAPING OF CARBON NANOFIBERS
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PP-II-15 MESOPOROU
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PP-II-16 EVALUATIO
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PP-II-16 As it wou
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PP-II-17 with exis
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PP-II-18 Thus, the
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PP-II-19 (NaOH, Cs
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PP-II-20 MEDICAL C
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PP-II-21 Pt /AC an
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PP-II-22 Prelimina
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FACTORS DETERMINING THE CATALYTIC P
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NANOPOROUS CARBON MATERIALS AS EFFE
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CARBON NANOSTRUCTURAL MATERIALS PRO
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GROWTH OF CARBON NANOFIBERS ON META
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ACTIVE CARBON AS SUPPORT FOR IMMOBI
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PP-II-28 USING OF
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AKSOYLU Ahmet Erhan Department of C
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DIDENKO Olga Pisarzhevskii Institut
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KOGAN Victor M. Zelinsky Institute
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NOUGMANOV Evgeniy Lomonosov Moscow
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SERP Philippe INPToulouse 118 Route
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ZAITSEV Yurij P. Institute for Sorp
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steel, Hastelloy C22, Titanium, Tan
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Условия эксплуатац
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DONAU LAB MOSCOW ПРОГРАММА
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CONTENT PLENARY LECTURES...........
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OP-I-12 Maldonado-Hódar F.J., Carr
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OP-II-8 Isse A.A.,
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PP-I-21 Karaseva M.S., Perederiy M.
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PP-I-47 Zaitsev Yu., Zhuravsky S.,
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PP-II-21 Özkara S
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II International Symposium on Carbon for Catalysis ABSTRACTS

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