II International Symposium on Carbon for Catalysis ABSTRACTS

PP-<strong>II</strong>-23
Table. Investigated Reactions, Accelerated by Various Carbon Sorbents
Reactions Experimental conditions Catalysts
Acid-base
Esterification of
acetic acid with
butyl alcohol
Liquid- and vapor-phase synthesis, in static and
flow-type circulatory reaction; T=393-723 K,
reagent ratio 1:20 to 20:1
FOU, DOU, LOU,
BAU o , UT-O,
KPKO
Esterification of
aliphatic acids with
glycerol
Transesterification
of edible fats and
their mixtures
Hydrolysis of ethyl
acetate
Dehydration of
methanol and
isobutanol
Hydrolysis of
vegetable oil
Hydrolysis
sucrose, maltose
Hydrogenation of
vegetable oil
Static conditions with agitation under vacuum
(1.3.10-3 Pa, 2 h) or in a fluidized bed reactor,
T=373-473
The same; beef and pork fat, soya, palm, and
sunflower oil
Vapor- and liquid-phase hydrolysis at T=423-
673 K in flow-type circulatory reactor and under
static conditions (thermostat, agitation, 24 h)
Flow-type reactor, 3 h, T= 493-623 K
Static conditions, thermostat, agitation,
T= 309-323 K, 24 h
The same
DOU, SKNO,
BAU o , and their Na
forms
DOU, SKNO,
BAU o , and their Na
forms
FOU-H, FOU-Me
(Me- Na, Ca, Cu, Zn,
Fe, Ni, Co, K, Mg)
FOU, DOU
SKNO, KAU o , their
Zn, F, Co, Mn, and
Cu forms
Ditto, FOU, DOU
Static conditions, agitation with a stream of
hydrogen, 1-13 h, T= 433-503 K
Ni-containing FOU
and DOU carbons
Oxidation-reduction
Decomposition of
H 2 O 2
Static conditions, thermostat, T= 293 and 309 K FAU, BAU, CKT,
AR-3, KAU, SKN,
KPK, LOU, their Fe,
Co, Ni, Mn, Cu, Cr
forms, C+Me x O y (Me
– Mn, Cr, Ni, Fe, Cu)
Decomposition of
oxygen
compounds of
chlorine
Decomposition of
hydroperoxide of
dibenzyl ether
Oxidation of
cumene
Static conditions, agitation in vessels protected
from light, T= 295 K
Thermostated bubble-type reactor with reflux
condenser, 1-6 h, T= 293-323 K
Gasometric apparatus, agitation, T= 343 K
DOU-Co, DOU-Ni
Cation-substituted
forms (co, Ni, Mn,
Fe, Cu) of DOU,
LOU, SKNO
SKN, FAU, DOU,
UT o , their Cr, Fe, Co,
Mn, Cu, Ni-forms
Oxidation of H 2 S Stationary reactor, agitation, T = 294-309 SKN, UT o , DOU,
and SO 2 Cr, Fe, Co, Mn, Cu,
Ni -forms
272