PP-<str<strong>on</strong>g>II</str<strong>on</strong>g>-23 Table. Investigated Reacti<strong>on</strong>s, Accelerated by Various Carb<strong>on</strong> Sorbents Reacti<strong>on</strong>s Experimental c<strong>on</strong>diti<strong>on</strong>s Catalysts Acid-base Esterificati<strong>on</strong> of acetic acid with butyl alcohol Liquid- and vapor-phase synthesis, in static and flow-type circulatory reacti<strong>on</strong>; T=393-723 K, reagent ratio 1:20 to 20:1 FOU, DOU, LOU, BAU o , UT-O, KPKO Esterificati<strong>on</strong> of aliphatic acids with glycerol Transesterificati<strong>on</strong> of edible fats and their mixtures Hydrolysis of ethyl acetate Dehydrati<strong>on</strong> of methanol and isobutanol Hydrolysis of vegetable oil Hydrolysis sucrose, maltose Hydrogenati<strong>on</strong> of vegetable oil Static c<strong>on</strong>diti<strong>on</strong>s with agitati<strong>on</strong> under vacuum (1.3.10-3 Pa, 2 h) or in a fluidized bed reactor, T=373-473 The same; beef and pork fat, soya, palm, and sunflower oil Vapor- and liquid-phase hydrolysis at T=423- 673 K in flow-type circulatory reactor and under static c<strong>on</strong>diti<strong>on</strong>s (thermostat, agitati<strong>on</strong>, 24 h) Flow-type reactor, 3 h, T= 493-623 K Static c<strong>on</strong>diti<strong>on</strong>s, thermostat, agitati<strong>on</strong>, T= 309-323 K, 24 h The same DOU, SKNO, BAU o , and their Na <strong>for</strong>ms DOU, SKNO, BAU o , and their Na <strong>for</strong>ms FOU-H, FOU-Me (Me- Na, Ca, Cu, Zn, Fe, Ni, Co, K, Mg) FOU, DOU SKNO, KAU o , their Zn, F, Co, Mn, and Cu <strong>for</strong>ms Ditto, FOU, DOU Static c<strong>on</strong>diti<strong>on</strong>s, agitati<strong>on</strong> with a stream of hydrogen, 1-13 h, T= 433-503 K Ni-c<strong>on</strong>taining FOU and DOU carb<strong>on</strong>s Oxidati<strong>on</strong>-reducti<strong>on</strong> Decompositi<strong>on</strong> of H 2 O 2 Static c<strong>on</strong>diti<strong>on</strong>s, thermostat, T= 293 and 309 K FAU, BAU, CKT, AR-3, KAU, SKN, KPK, LOU, their Fe, Co, Ni, Mn, Cu, Cr <strong>for</strong>ms, C+Me x O y (Me – Mn, Cr, Ni, Fe, Cu) Decompositi<strong>on</strong> of oxygen compounds of chlorine Decompositi<strong>on</strong> of hydroperoxide of dibenzyl ether Oxidati<strong>on</strong> of cumene Static c<strong>on</strong>diti<strong>on</strong>s, agitati<strong>on</strong> in vessels protected from light, T= 295 K Thermostated bubble-type reactor with reflux c<strong>on</strong>denser, 1-6 h, T= 293-323 K Gasometric apparatus, agitati<strong>on</strong>, T= 343 K DOU-Co, DOU-Ni Cati<strong>on</strong>-substituted <strong>for</strong>ms (co, Ni, Mn, Fe, Cu) of DOU, LOU, SKNO SKN, FAU, DOU, UT o , their Cr, Fe, Co, Mn, Cu, Ni-<strong>for</strong>ms Oxidati<strong>on</strong> of H 2 S Stati<strong>on</strong>ary reactor, agitati<strong>on</strong>, T = 294-309 SKN, UT o , DOU, and SO 2 Cr, Fe, Co, Mn, Cu, Ni -<strong>for</strong>ms 272
NANOPOROUS CARBON MATERIALS AS EFFECTIVE PREPARATIONS IN MEDICAL PRACTICE PP-<str<strong>on</strong>g>II</str<strong>on</strong>g>-24 Surovikin V.F., Pjanova L.G., Luzjanina L.S. Institute of Hydrocarb<strong>on</strong>s Processing SB RAS, Omsk, Russia e-mail: val@inkat.okno.ru, uglerod@ihpp.okno.ru Carb<strong>on</strong> hemosorbent VN<str<strong>on</strong>g>II</str<strong>on</strong>g>TU-1 and carb<strong>on</strong> enterosorbent VN<str<strong>on</strong>g>II</str<strong>on</strong>g>TU-2 (nanoporous (mesoporous) carb<strong>on</strong> sorbents <strong>for</strong> medical purpose) have been developed and obtained in the Institute of Hydrocarb<strong>on</strong>s Processing SB RAS. The carb<strong>on</strong> sorbents obtained <strong>on</strong> the base of dispersed carb<strong>on</strong> bel<strong>on</strong>g to mesoporous sorbents group. The dominati<strong>on</strong> volume of mesopores (the c<strong>on</strong>tents mesopores <strong>on</strong> a surface up to 80%) allows to carry out effective sorpti<strong>on</strong> of toxic substances with low and average molecular weight and the molecules size corresp<strong>on</strong>ding to the size of sorbent pores. Sorpti<strong>on</strong> activity of carb<strong>on</strong> hemosorbent VN<str<strong>on</strong>g>II</str<strong>on</strong>g>TU-1 in relati<strong>on</strong> to chemical standard markers has been investigated (tab. 1). Table 1. Sorpti<strong>on</strong> activity of carb<strong>on</strong> hemosorbent VN<str<strong>on</strong>g>II</str<strong>on</strong>g>TU-1 in relati<strong>on</strong> to chemical standard markers. Standard marker Molecular weight Eliminati<strong>on</strong> from physiological soluti<strong>on</strong>, % Methylene blue 319 92-98 Vitamin В 12 1357 88-90 The essentially new technology of medical purpose carb<strong>on</strong> materials producti<strong>on</strong> has been developed and it is completely appropriate to medicine requirements <strong>for</strong> the new generati<strong>on</strong> of sorbents. The given technology has allowed to obtain sorbents with the set physicochemical properties (tab. 2). Table 2. Physical-chemical characteristics of sorbents. Parameter norm Parameter name Carb<strong>on</strong> hemosorbent VN<str<strong>on</strong>g>II</str<strong>on</strong>g>TU-1 Carb<strong>on</strong> enterosorbent VN<str<strong>on</strong>g>II</str<strong>on</strong>g>TU-2 Spherical granule size, mm 0,70-1,00 0,50-1,00 Total pore volume, cm 3 / g 0,30-0,45 0,35-0,55 Adsorpti<strong>on</strong> capacity, g/g ___ Not less than 0,03 Iodine number, g/kg 175-245 200-300 Granule resistance to wear, % per minute, not more than 0,30 0,30 273
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Boreskov Institute of Catalysis of
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ORGANIZING COMMITTEE Chairman: Vlad
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CATALYSTS ON CARBON MATERIALS BASIS
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PREPARATION OF CARBON FILMS ON CERA
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PL-2 polymer gas separation membran
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CHARACTERIZATION OF POROUS STRUCTUR
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ROLE OF CARBON POROSITY AND FUNCTIO
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KEYNOTE LECTURES
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KL-1 governed by the equation of th
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KL-2 NITROGEN DOPED CARBON NANOFIBE
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KL-3 CARBON BASED STRUCTURED CATALY
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KL-4 The strong mesoporous carbons
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KL-5 NANOSTRUCTURED CARBONS FOR THE
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KL-6 THEORY OF MECHANICAL BEHAVIOR
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KL-7 MOLECULAR STRUCTURE EFFECT OF
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Presentation of FGUP “ENPO Neorga
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OP-I-1 COBALT ON CARBON NANOFIBER C
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OP-I-1 from 41 to 23 %, while the C
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OP-I-2 loading. It is also interest
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OP-I-3 5 nm 50 nm Figure 1: PtRu/MW
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OP-I-4 As it can be seen, potassium
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OP-I-5 [A] ⇔ A+[ ] (5) Kinetic an
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Results and discussion OP-I-6 The T
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OP-I-7 product selectivity). The an
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OP-I-8 After introduction of the me
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OP-I-9 Hydrogenations were carried
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OP-I-10 activated with CO 2 . In al
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OP-I-11 from Jaroszów deposit, Low
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OP-I-12 The carbon matrix avoids th
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OP-I-13 • thermal destruction of
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OP-I-14 hexanol (AA) was anchored t
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OP-I-15 removing the physically ads
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OP-I-16 surface concentration of HE
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Our analysis of the chemical activi
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OP-I-18 running. The TEM reveals th
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OP-I-19 explore the role of CNF sur
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pH 10 8 6 4 2 0 2 4 6 8 10 ml HCl a
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OP-I-21 resorcinol to catalyst mola
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OP-I-22 AS in the catalysts examine
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OP-I-23 polyfunctional surface cove
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OP-I-24 as sibunite and nanofibrous
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OP-I-25 is a consequence of the mac
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OP-I-27 THE CARBON FILMS ON Pt(111)
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OP-I-28 LASER RAMAN MICRO-SPECTROSC
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OP-I-29 ELECTROCATALYTIC PROPERTIES
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OP-II-1 SYNTHESIS
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OP-II-2 SYNTHESIS,
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TOWARDS LARGE SCALE PRODUCTION OF C
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CO-CARBONIZATION OF POLYMERS - NEW
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OP-II-5 3. Results
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OP-II-6 pore size
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OP-II-7 their adva
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OP-II-8 effect, el
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OP-II-9 Therefore,
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OP-II-10 The dehyd
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OP-II-11 a result
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INVESTIGATION OF THE ELECTROCHEMICA
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SURFACE ELECTROCHEMISTRY OF CARBON
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TEMPLATED SYNTHESIS OF NOBLE METAL
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PROPERTIES AND STRUCTURE OF SORBENT
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CATALYSIS DURING SULPHUR COALS PROC
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ORDERED MESOPOROUS CARBONS SYNTHESI
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PP-I-7 INFLUENCE OF FUNCTIONALIZATI
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PP-I-8 AROMATIZATION OF 5-PHENYL-PI
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N 2 O CONVERSION USING BINARY MIXTU
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PP-I-9 [8] F. Gonçalves, G.E. Marn
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PP-I-10 The Table 1 demonstrates th
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PP-I-11 We suppose that the active
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PP-I-12 Activation with steam promo
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PP-I-13 separation of bundles forme
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PP-I-14 temperature at which the ma
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PP-I-15 Titania was prepared by hyd
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PP-I-16 A B Figure 1. SEM images co
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PP-I-17 the carbon matrix has been
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PP-I-18 0.9 0.8 0.7 0.6 lg (ΔV/ΔR
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PP-I-19 Electron-microscopic studie
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PP-I-20 time on stream increased fr
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CARBON-SUPPORTED 12-MOLYBDOPHOSPHOR
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PP-I-23 CARBON SUPPORTS FOR IMMOBIL
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PP-I-24 example, in the polymer ele
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PP-I-25 of microporous structure wa
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PP-I-26 contain at first. Non-oxida
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PP-I-27 this reaction and that the
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CONTROLLING DIAMETER AND PRESENCE O
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INFLUENCE OF GAS OXIDATIVE TREATMEN
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PP-I-30 EXPERIMENTAL VALUES OF THE
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PP-I-30 Acknowledgements The author
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PP-I-31 suspensions of UFD had low
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PP-I-32 It was detected, that precu
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PP-I-33 consistence of the process,
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PP-I-34 practically identical [2],
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PP-I-35 • surface porosity (P 245
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PP-I-36 (COOH+OH), mg-eq/g 1,8 1,2
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PP-I-37 As one can see in the table
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PP-I-38 hydrogenation (61 o and 65
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PP-I-39 Ensembles №№ 31, 45, 55
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PP-I-40 The pore structure of origi
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PP-I-41 Sr 2+ and Ba 2+ ions are in
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PP-I-42 volume are formed from init
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PP-I-43 30 wt% Pt-15 wt% Ru/NCM cat
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PP-I-44 Figure 1. From left to righ
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PP-I-45 Table 1: Characteristics of
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PP-I-45 The search for alternative
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PP-I-46 zeroth moment expression, w
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PP-I-47 It was revealed, that the i
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PP-I-48 Table 1 Characteristics of
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PP-I-49 4-Carboxybenzaldehyde (4-CB
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