II International Symposium on Carbon for Catalysis ABSTRACTS

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PL-1 In the case of “palladium on carbon” system physical-chemical investigations data have permitted to optimize methods of preparation of metallic palladium particles precursors for concrete hydrogenation process. During these catalysts synthesis it is necessary to achieve optimal for this process dispersity and width of metal particles size distribution which can be regulated by nature of their location places on carbon carrier surface which in their turn are determined by the supported precursors nature and by the condition of carrier treatment. The influence of these factors on activity is demonstrated by examples connected with the development of catalysts for the processes of nitroaromatic compounds hydrogenation, rosin disproportionation and monomers hydropurification. 8
PREPARATION OF CARBON FILMS ON CERAMIC SUPPORTS PL-2 Tennison S. MAST Carbon Technology Ltd., Henley Park, England e-mail: Steve.tennison@mastcarbon.co.uk Introduction Polymer derived nanoporous carbons offer many advantages over carbons based on naturally occurring carbon as catalyst supports. These include precisely controlled pore structure 1,2 , greatly enhanced reproducibility, high purity and the ability to precisely control the surface chemistry 3 . In some cases the possibility also exists to produce the materials in a wide range of physical forms to suit different applications. MAST has spent several years, through a variety of collaborative projects 4,5 and in house research, developing a family of phenolic resin derived that can be produced in physical forms from extrudates and beads, through complex monolithic structures to asymmetric membranes. In the latter case these membranes can either be pure carbon systems or carbon coated ceramics. One of the major benefits of the phenolic system is that all of these physical forms exhibit a common pore and surface structure and therefore similar characteristics when used as catalyst supports. This presentation will therefore first review the pore, surface chemistry and catalyst characteristics of the phenolic resin derived carbons and subsequently the production, structure and performance the carbon-ceramic composite membrane devices based on phenolic resin. Phenolic Resin Derived Carbons The pore structure of the phenolic based carbons derives directly from the underlying polymer structure and is similar for all phenolic precursors. The production of the crosslinked resin from the novolak or resol precursors gives rise to a phase separation process within the polymer matrix during crosslinking that leads to the formation of microdomains of highly crosslinked resin a matrix of less cured resin. Pyrolysis then leads to the loss of the less crosslinked material leaving a matrix of interlinked, high density nanobeads of 5-10nm diameter where the resulting pore structure comprises the voids between these beads. It is this process that give the phenolic derived carbons their unique structure. This phase separation process also underpins the production of the mesoporous carbons via a secondary phase separation process. 9
Page 1 and 2: Boreskov Institute of Catalysis of
Page 3: ORGANIZING COMMITTEE Chairman: Vlad
Page 7: CATALYSTS ON CARBON MATERIALS BASIS
Page 11 and 12: PL-2 polymer gas separation membran
Page 13 and 14: CHARACTERIZATION OF POROUS STRUCTUR
Page 15 and 16: ROLE OF CARBON POROSITY AND FUNCTIO
Page 17: KEYNOTE LECTURES
Page 20 and 21: KL-1 governed by the equation of th
Page 22 and 23: KL-2 NITROGEN DOPED CARBON NANOFIBE
Page 24 and 25: KL-3 CARBON BASED STRUCTURED CATALY
Page 26 and 27: KL-4 The strong mesoporous carbons
Page 28 and 29: KL-5 NANOSTRUCTURED CARBONS FOR THE
Page 30 and 31: KL-6 THEORY OF MECHANICAL BEHAVIOR
Page 32 and 33: KL-7 MOLECULAR STRUCTURE EFFECT OF
Page 34 and 35: Presentation of FGUP “ENPO Neorga
Page 37 and 38: OP-I-1 COBALT ON CARBON NANOFIBER C
Page 39 and 40: OP-I-1 from 41 to 23 %, while the C
Page 41 and 42: OP-I-2 loading. It is also interest
Page 43 and 44: OP-I-3 5 nm 50 nm Figure 1: PtRu/MW
Page 45 and 46: OP-I-4 As it can be seen, potassium
Page 47 and 48: OP-I-5 [A] ⇔ A+[ ] (5) Kinetic an
Page 49 and 50: Results and discussion OP-I-6 The T
Page 51 and 52: OP-I-7 product selectivity). The an
Page 53 and 54: OP-I-8 After introduction of the me
Page 55 and 56: OP-I-9 Hydrogenations were carried
Page 57 and 58: OP-I-10 activated with CO 2 . In al
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OP-I-11 from Jaroszów deposit, Low
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OP-I-12 The carbon matrix avoids th
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OP-I-13 • thermal destruction of
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OP-I-14 hexanol (AA) was anchored t
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OP-I-15 removing the physically ads
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OP-I-16 surface concentration of HE
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Our analysis of the chemical activi
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OP-I-18 running. The TEM reveals th
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OP-I-19 explore the role of CNF sur
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pH 10 8 6 4 2 0 2 4 6 8 10 ml HCl a
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OP-I-21 resorcinol to catalyst mola
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OP-I-22 AS in the catalysts examine
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OP-I-23 polyfunctional surface cove
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OP-I-24 as sibunite and nanofibrous
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OP-I-25 is a consequence of the mac
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OP-I-27 THE CARBON FILMS ON Pt(111)
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OP-I-28 LASER RAMAN MICRO-SPECTROSC
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OP-I-29 ELECTROCATALYTIC PROPERTIES
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OP-II-1 SYNTHESIS
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OP-II-2 SYNTHESIS,
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TOWARDS LARGE SCALE PRODUCTION OF C
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CO-CARBONIZATION OF POLYMERS - NEW
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OP-II-5 3. Results
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OP-II-6 pore size
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OP-II-7 their adva
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OP-II-8 effect, el
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OP-II-9 Therefore,
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OP-II-10 The dehyd
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OP-II-11 a result
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INVESTIGATION OF THE ELECTROCHEMICA
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SURFACE ELECTROCHEMISTRY OF CARBON
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TEMPLATED SYNTHESIS OF NOBLE METAL
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PROPERTIES AND STRUCTURE OF SORBENT
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CATALYSIS DURING SULPHUR COALS PROC
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ORDERED MESOPOROUS CARBONS SYNTHESI
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PP-I-7 INFLUENCE OF FUNCTIONALIZATI
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PP-I-8 AROMATIZATION OF 5-PHENYL-PI
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N 2 O CONVERSION USING BINARY MIXTU
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PP-I-9 [8] F. Gonçalves, G.E. Marn
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PP-I-10 The Table 1 demonstrates th
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PP-I-11 We suppose that the active
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PP-I-12 Activation with steam promo
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PP-I-13 separation of bundles forme
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PP-I-14 temperature at which the ma
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PP-I-15 Titania was prepared by hyd
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PP-I-16 A B Figure 1. SEM images co
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PP-I-17 the carbon matrix has been
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PP-I-18 0.9 0.8 0.7 0.6 lg (ΔV/ΔR
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PP-I-19 Electron-microscopic studie
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PP-I-20 time on stream increased fr
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CARBON-SUPPORTED 12-MOLYBDOPHOSPHOR
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PP-I-23 CARBON SUPPORTS FOR IMMOBIL
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PP-I-24 example, in the polymer ele
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PP-I-25 of microporous structure wa
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PP-I-26 contain at first. Non-oxida
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PP-I-27 this reaction and that the
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CONTROLLING DIAMETER AND PRESENCE O
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INFLUENCE OF GAS OXIDATIVE TREATMEN
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PP-I-30 EXPERIMENTAL VALUES OF THE
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PP-I-30 Acknowledgements The author
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PP-I-31 suspensions of UFD had low
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PP-I-32 It was detected, that precu
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PP-I-33 consistence of the process,
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PP-I-34 practically identical [2],
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PP-I-35 • surface porosity (P 245
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PP-I-36 (COOH+OH), mg-eq/g 1,8 1,2
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PP-I-37 As one can see in the table
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PP-I-38 hydrogenation (61 o and 65
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PP-I-39 Ensembles №№ 31, 45, 55
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PP-I-40 The pore structure of origi
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PP-I-41 Sr 2+ and Ba 2+ ions are in
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PP-I-42 volume are formed from init
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PP-I-43 30 wt% Pt-15 wt% Ru/NCM cat
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PP-I-44 Figure 1. From left to righ
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PP-I-45 Table 1: Characteristics of
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PP-I-45 The search for alternative
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PP-I-46 zeroth moment expression, w
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PP-I-47 It was revealed, that the i
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PP-I-48 Table 1 Characteristics of
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PP-I-49 4-Carboxybenzaldehyde (4-CB
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PP-I-50 Computational details First
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PP-I-51 The result showed that surf
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PP-II-1 COOH COO(C
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PP-II-2 The result
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PP-II-3 prepared,
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PP-II-4 CNF from b
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PP-II-5 support; t
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PP-II-6 The main p
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PP-II-7 porous net
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PP-II-8 It is note
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PP-II-9 selective
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STABILITY OF A CARBON CATALYST FLUI
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PP-II-11 CARBON FI
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PP-II-12 CATALYTIC
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THE SORBENTS FOR AIR CLEANING PREPA
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MACRO-SHAPING OF CARBON NANOFIBERS
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PP-II-15 MESOPOROU
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PP-II-16 EVALUATIO
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PP-II-16 As it wou
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PP-II-17 with exis
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PP-II-18 Thus, the
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PP-II-19 (NaOH, Cs
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PP-II-20 MEDICAL C
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PP-II-21 Pt /AC an
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PP-II-22 Prelimina
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FACTORS DETERMINING THE CATALYTIC P
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NANOPOROUS CARBON MATERIALS AS EFFE
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CARBON NANOSTRUCTURAL MATERIALS PRO
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GROWTH OF CARBON NANOFIBERS ON META
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ACTIVE CARBON AS SUPPORT FOR IMMOBI
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PP-II-28 USING OF
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AKSOYLU Ahmet Erhan Department of C
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DIDENKO Olga Pisarzhevskii Institut
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KOGAN Victor M. Zelinsky Institute
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NOUGMANOV Evgeniy Lomonosov Moscow
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SERP Philippe INPToulouse 118 Route
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ZAITSEV Yurij P. Institute for Sorp
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steel, Hastelloy C22, Titanium, Tan
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Условия эксплуатац
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DONAU LAB MOSCOW ПРОГРАММА
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CONTENT PLENARY LECTURES...........
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OP-I-12 Maldonado-Hódar F.J., Carr
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OP-II-8 Isse A.A.,
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PP-I-21 Karaseva M.S., Perederiy M.
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PP-I-47 Zaitsev Yu., Zhuravsky S.,
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PP-II-21 Özkara S
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II International Symposium on Carbon for Catalysis ABSTRACTS

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