II International Symposium on Carbon for Catalysis ABSTRACTS

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PP-I-27 (a) (b) (c) (d) 10 nm Figure: Micrographs of the product: (a) SEM-FEG of a catalyst grain after C-CVD of methane; (b) higher magnification of the surface; (c) bundles of SWNT on the surface of Fe x Mo y /Al 2 O 3 catalyst; (d) HTEM of SWNT bundles. References 1 K.P. De Jong, J.W. Geus, Catal. Rev.-Sci. Eng. 42 (2000) 481. 2 P. Serp, M. Corrias, P. Kalck, Appl. Catal. A: Gen. 253 (2003) 337. 3 P. Serp, P. Kalck, R. Feurer, Chem. Rev. 102(9) (2002) 3085. 4 C. Xu and J. Zhu, Nanotechnology 15(11) (2004) 1671. 5 P. Serp, P. Kalck, R. Feurer, C. Vahlas, WO03/002456A2. 172
CONTROLLING DIAMETER AND PRESENCE OF DEFECTS OF MULTI PP-I-28 WALLED CARBON NANOTUBES BY CVD OVER Fe/Co SBA-15 CATALYSTS Lanzafame P. 1,3 , Perathoner S. 1,3 , Centi G. 1,3 , Su D. 2,3 , Schlögl R. 2,3 1 Department of Industrial Chemistry and Eng. of Materials, University of Messina and UdR-Messina of INSTM Messina, Italy 2 Department of Inorganic Chemistry, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin, Germany 3 ELCASS, European Laboratory of Catalysis and Surface Science e-mail: planzafame@ingegneria.unime.it The use of carbon nanotubes (CNT) opens new perspectives in electronics, sensors, nanoelectromechanical systems, and in the field of catalysis. The diameter and chirality of CNT determine their physical and chemical properties, but still there are limited data on how to control these properties. Limiting to the synthesis of CNT by catalytic hydrocarbon decomposition over metal particles (usually Fe, Co, Ni), because this is one of the preferable methods for larger-scale and low-cost production, it was reported by different authors that the CNT diameter depends on the metal particles size. However, it is unclear whether or not the characteristics and modality of growing of the CNT could also depend on this parameter. Due to the quite different range of reaction conditions, catalyst composition and type of feed used by the different authors in literature, it is also not possible to derive clear information from these results. In order to contribute to clarify this question, we have prepared FeCo catalytic nanoparticles stabilized inside an ordered mesoporous matrix (SBA-15) or located on the external surface of this mesoporous matrix. The former FeCo particles have uniform size of around 6 nm, the same size of the channels of the SBA-15 we used in this work, while the particles located on the external crystals have a size slightly larger, of around 30 nm, as shown by TEM characterization. Both types of particles have the same composition. The synthesis of CNT was made by CVD of propane. Under exactly the same reaction conditions, these two type of FeCo nanoparticles give rise to multiwalled carbon nanotubes (MWCNT) with a diameter close to that of the catalyst nanoparticles, but having a different way by which the graphene sheets are rolled up. The amount and purity of the carbon nanotubes produced by C 3 H 8 -CVD over Fe/Co SBA-15 catalyst was monitored by temperature programmed oxidation (TPO) in a 173
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Boreskov Institute of Catalysis of
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ORGANIZING COMMITTEE Chairman: Vlad
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CATALYSTS ON CARBON MATERIALS BASIS
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PREPARATION OF CARBON FILMS ON CERA
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PL-2 polymer gas separation membran
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CHARACTERIZATION OF POROUS STRUCTUR
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ROLE OF CARBON POROSITY AND FUNCTIO
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KEYNOTE LECTURES
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KL-1 governed by the equation of th
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KL-2 NITROGEN DOPED CARBON NANOFIBE
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KL-3 CARBON BASED STRUCTURED CATALY
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KL-4 The strong mesoporous carbons
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KL-5 NANOSTRUCTURED CARBONS FOR THE
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KL-6 THEORY OF MECHANICAL BEHAVIOR
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KL-7 MOLECULAR STRUCTURE EFFECT OF
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Presentation of FGUP “ENPO Neorga
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OP-I-1 COBALT ON CARBON NANOFIBER C
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OP-I-1 from 41 to 23 %, while the C
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OP-I-2 loading. It is also interest
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OP-I-3 5 nm 50 nm Figure 1: PtRu/MW
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OP-I-4 As it can be seen, potassium
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OP-I-5 [A] ⇔ A+[ ] (5) Kinetic an
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Results and discussion OP-I-6 The T
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OP-I-7 product selectivity). The an
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OP-I-8 After introduction of the me
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OP-I-9 Hydrogenations were carried
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OP-I-10 activated with CO 2 . In al
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OP-I-11 from Jaroszów deposit, Low
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OP-I-12 The carbon matrix avoids th
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OP-I-13 • thermal destruction of
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OP-I-14 hexanol (AA) was anchored t
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OP-I-15 removing the physically ads
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OP-I-16 surface concentration of HE
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Our analysis of the chemical activi
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OP-I-18 running. The TEM reveals th
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OP-I-19 explore the role of CNF sur
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pH 10 8 6 4 2 0 2 4 6 8 10 ml HCl a
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OP-I-21 resorcinol to catalyst mola
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OP-I-22 AS in the catalysts examine
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OP-I-23 polyfunctional surface cove
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OP-I-24 as sibunite and nanofibrous
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OP-I-25 is a consequence of the mac
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OP-I-27 THE CARBON FILMS ON Pt(111)
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OP-I-28 LASER RAMAN MICRO-SPECTROSC
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OP-I-29 ELECTROCATALYTIC PROPERTIES
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OP-II-1 SYNTHESIS
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OP-II-2 SYNTHESIS,
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TOWARDS LARGE SCALE PRODUCTION OF C
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CO-CARBONIZATION OF POLYMERS - NEW
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OP-II-5 3. Results
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OP-II-6 pore size
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OP-II-7 their adva
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OP-II-8 effect, el
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OP-II-9 Therefore,
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OP-II-10 The dehyd
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OP-II-11 a result
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INVESTIGATION OF THE ELECTROCHEMICA
Page 121 and 122: SURFACE ELECTROCHEMISTRY OF CARBON
Page 123 and 124: TEMPLATED SYNTHESIS OF NOBLE METAL
Page 125 and 126: PROPERTIES AND STRUCTURE OF SORBENT
Page 127 and 128: CATALYSIS DURING SULPHUR COALS PROC
Page 129 and 130: ORDERED MESOPOROUS CARBONS SYNTHESI
Page 131 and 132: PP-I-7 INFLUENCE OF FUNCTIONALIZATI
Page 133 and 134: PP-I-8 AROMATIZATION OF 5-PHENYL-PI
Page 135 and 136: N 2 O CONVERSION USING BINARY MIXTU
Page 137 and 138: PP-I-9 [8] F. Gonçalves, G.E. Marn
Page 139 and 140: PP-I-10 The Table 1 demonstrates th
Page 141 and 142: PP-I-11 We suppose that the active
Page 143 and 144: PP-I-12 Activation with steam promo
Page 145 and 146: PP-I-13 separation of bundles forme
Page 147 and 148: PP-I-14 temperature at which the ma
Page 149 and 150: PP-I-15 Titania was prepared by hyd
Page 151 and 152: PP-I-16 A B Figure 1. SEM images co
Page 153 and 154: PP-I-17 the carbon matrix has been
Page 155 and 156: PP-I-18 0.9 0.8 0.7 0.6 lg (ΔV/ΔR
Page 157 and 158: PP-I-19 Electron-microscopic studie
Page 159 and 160: PP-I-20 time on stream increased fr
Page 161 and 162: CARBON-SUPPORTED 12-MOLYBDOPHOSPHOR
Page 163 and 164: PP-I-23 CARBON SUPPORTS FOR IMMOBIL
Page 165 and 166: PP-I-24 example, in the polymer ele
Page 167 and 168: PP-I-25 of microporous structure wa
Page 169 and 170: PP-I-26 contain at first. Non-oxida
Page 171: PP-I-27 this reaction and that the
Page 175 and 176: INFLUENCE OF GAS OXIDATIVE TREATMEN
Page 177 and 178: PP-I-30 EXPERIMENTAL VALUES OF THE
Page 179 and 180: PP-I-30 Acknowledgements The author
Page 181 and 182: PP-I-31 suspensions of UFD had low
Page 183 and 184: PP-I-32 It was detected, that precu
Page 185 and 186: PP-I-33 consistence of the process,
Page 187 and 188: PP-I-34 practically identical [2],
Page 189 and 190: PP-I-35 • surface porosity (P 245
Page 191 and 192: PP-I-36 (COOH+OH), mg-eq/g 1,8 1,2
Page 193 and 194: PP-I-37 As one can see in the table
Page 195 and 196: PP-I-38 hydrogenation (61 o and 65
Page 197 and 198: PP-I-39 Ensembles №№ 31, 45, 55
Page 199 and 200: PP-I-40 The pore structure of origi
Page 201 and 202: PP-I-41 Sr 2+ and Ba 2+ ions are in
Page 203 and 204: PP-I-42 volume are formed from init
Page 205 and 206: PP-I-43 30 wt% Pt-15 wt% Ru/NCM cat
Page 207 and 208: PP-I-44 Figure 1. From left to righ
Page 209 and 210: PP-I-45 Table 1: Characteristics of
Page 211 and 212: PP-I-45 The search for alternative
Page 213 and 214: PP-I-46 zeroth moment expression, w
Page 215 and 216: PP-I-47 It was revealed, that the i
Page 217 and 218: PP-I-48 Table 1 Characteristics of
Page 219 and 220: PP-I-49 4-Carboxybenzaldehyde (4-CB
Page 221 and 222: PP-I-50 Computational details First
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PP-I-51 The result showed that surf
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PP-II-1 COOH COO(C
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PP-II-2 The result
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PP-II-3 prepared,
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PP-II-4 CNF from b
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PP-II-5 support; t
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PP-II-6 The main p
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PP-II-7 porous net
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PP-II-8 It is note
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PP-II-9 selective
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STABILITY OF A CARBON CATALYST FLUI
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PP-II-11 CARBON FI
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PP-II-12 CATALYTIC
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THE SORBENTS FOR AIR CLEANING PREPA
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MACRO-SHAPING OF CARBON NANOFIBERS
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PP-II-15 MESOPOROU
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PP-II-16 EVALUATIO
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PP-II-16 As it wou
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PP-II-17 with exis
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PP-II-18 Thus, the
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PP-II-19 (NaOH, Cs
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PP-II-20 MEDICAL C
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PP-II-21 Pt /AC an
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PP-II-22 Prelimina
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FACTORS DETERMINING THE CATALYTIC P
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NANOPOROUS CARBON MATERIALS AS EFFE
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CARBON NANOSTRUCTURAL MATERIALS PRO
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GROWTH OF CARBON NANOFIBERS ON META
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ACTIVE CARBON AS SUPPORT FOR IMMOBI
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PP-II-28 USING OF
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AKSOYLU Ahmet Erhan Department of C
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DIDENKO Olga Pisarzhevskii Institut
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KOGAN Victor M. Zelinsky Institute
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NOUGMANOV Evgeniy Lomonosov Moscow
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SERP Philippe INPToulouse 118 Route
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ZAITSEV Yurij P. Institute for Sorp
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steel, Hastelloy C22, Titanium, Tan
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Условия эксплуатац
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DONAU LAB MOSCOW ПРОГРАММА
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CONTENT PLENARY LECTURES...........
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OP-I-12 Maldonado-Hódar F.J., Carr
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OP-II-8 Isse A.A.,
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PP-I-21 Karaseva M.S., Perederiy M.
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PP-I-47 Zaitsev Yu., Zhuravsky S.,
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PP-II-21 Özkara S
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II International Symposium on Carbon for Catalysis ABSTRACTS

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