II International Symposium on Carbon for Catalysis ABSTRACTS

PP-I-39
SELF ORGANIZED CARBON POLYCYCLES
Smirnova N.L.
Moscow Lomonosov State University, Moscow, Russia
e-mail:snl194@mail.ru
The 21-century will be the century of systemic sciences. It means that universal systemic
laws will be used to design objects out of elements and their ensembles. It was supposed by us
that elements and ensembles arise as latent faults in objects of previous level.
The structure of C graphite consist of Kepler (Archimedean) net 666. This net consists of
hexagons that shared all edges. Every vertex is surrounded by 3 hexagons. The net 666
comprise latent bands and ensembles of hexagons. The net 666 is precursor of many new nets
and ensembles. It was found by D. Bird (M. Gardner, 1975, B. Grunbaum and G.C. Shephard,
1987) that polycycles consisting of 1, 2, 3, 4, 5 hexagons form 1, 1, 3, 7, 22 ensembles
(n-hexes), in all 34. It was revealed (Smirnova N.L., 1976) 13 different ensembles (condensed
polycycles or n-hexes) with hexagon surrounded by 0 – 6 hexagons. It was supposed that all
these ensembles № 11, 21, 31, 32, 33, 41, 42, 43, 51, 52, 54, 61, 71 (Fig.) are self-organized
in nature as structures of inorganic substances and organic molecules. It was found that 19 out
of 34 n-hexes and all 13 ensembles were realized. There are 11 n-hexes out of 19 that are
comprised in 13 n-hexes. The other 8 n-hexes are №№ 45, 46, 47, 53, 55, 56, 58, 5.13.
We suppose in 1950 th that all new structures are self-organized by ordering of the same or
different 0, 1, 2, 3-dimensional elements and their ensembles. During this process in all
systems superstructures and homological series arise. All new data confirmed this law. In the
set of ensembles there is S series of straight homologs, W series of wavy homologs and SW
series of partly straight and partly wavy homologs. There are also C series of homologes with
central nuclear № 33, 42, 43, 44, 54, 71. One - two 1, 2-hexes are condensed with nuclear:
№ 33 (59, 5.10, 5.11, 63), № 43 (66, 74), № 42 (52, 53, 67, 68, 82, 83), № 54 (92, 84, 76, 77)
and so on. New series of central homologs are self-organized.
Let us denote n-gons as 3 (trigon), 4 (tetragon), 5 (pentagon), 6, 7, 8, 9. Ensembles №№
31, 32, 33 can consist of 3 cycles aaa, aab, aba, abc. There were found for ensemble № 31
superstructures 555, 556, 565, 566, 656, 667, 676, 677, 767, 668, 576, 658, for ensemble
№ 32 – 566, 565, 575, 676, 677, 366, 576, for ensemble № 33 – 566, 556. Ensemble № 31 is
third member of S series, № 32 is third member W series. There are some members of
SW series (№№ 47, 57, 72, 58, 5.12, 64, 65).
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