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II International Symposium on Carbon for Catalysis ABSTRACTS

II International Symposium on Carbon for Catalysis ABSTRACTS

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GROWTH OF CARBON NANOFIBERS ON METALLIC FILTERS<br />

PP-<str<strong>on</strong>g>II</str<strong>on</strong>g>-26<br />

Tribolet P., Kiwi-Minsker L.<br />

Swiss Federal Institute of Technology (EPFL), SB-ISIC-LGRC, CH-1015 Lausanne, Switzerland<br />

e-mail: pascal.tribolet@epfl.ch<br />

During the last decade, carb<strong>on</strong> nanofibers (CNF) have attracted a lot of interest due to<br />

their outstanding mechanical, thermal and electrical properties [1]. The easiest way to grow<br />

up carb<strong>on</strong> nanofibers is by catalytic decompositi<strong>on</strong> of a gaseous carb<strong>on</strong> precursor. Up to now,<br />

the majority of CNF produced by this method needs supported metal catalysts or metals in a<br />

powder <strong>for</strong>m. It requires either a step of metal depositi<strong>on</strong> <strong>on</strong> a support or leads to unsupported<br />

CNF, which can be very difficult to handle.<br />

We propose to use metallic filters as supports and catalysts <strong>for</strong> the carb<strong>on</strong> nanofibers<br />

synthesis. With an adequate metallic compositi<strong>on</strong>, it is possible to grow up CNF directly <strong>on</strong><br />

the filter. This leads to a structured composite material c<strong>on</strong>sisting of a filter where the metal<br />

wires are surrounded by a layer of CNF. This composite has a graphitic external surface,<br />

coming from the nature of the CNF and a high specific surface area due to the small diameter<br />

of the nanofibers [2]. Being a combinati<strong>on</strong> of two electro- and thermo-c<strong>on</strong>ductive compounds,<br />

the resulting material keeps these properties. It is suitable <strong>for</strong> various applicati<strong>on</strong>s, like a<br />

catalytic support, a rein<strong>for</strong>cement material, or a catalytic electrode.<br />

Figure 1: Optical and SEM pictures of carb<strong>on</strong> nanofibers grown <strong>on</strong> sintered Inc<strong>on</strong>el fiber filter by catalytic<br />

decompositi<strong>on</strong> of C 2 H 6 . Magnitude: A. 40x, B. 300x, C. 3000x, D. 20000x.<br />

We report hereby the <strong>on</strong>e-step synthesis of a novel composite material c<strong>on</strong>sisting of<br />

CNF grown <strong>on</strong> Inc<strong>on</strong>el sintered metal fibers filters (CNF/SMFInc<strong>on</strong>el, Figure 1). The SMF<br />

filters have a thickness of 490 μm and c<strong>on</strong>sist of fibers of 8 μm diameter. They possess an<br />

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