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Adding gas from biomass to the gas grid - SGC

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Plant examplesParameter Unit Process Plant 1 Plant 2 Plant 3Location/name Ellinge Bromma KristianstadCapacity range m 3 10 - 1000 70 55 175bio<strong>gas</strong>/hInput· methane%45 - 75 58 - 60 61 - 6660· carbon dioxide%25 - 55 40 - 42 33 - 3840· nitrogen%< 10 0.4 - 1.60· hydrogen sulphideppm< 1000< 10 < 0.5no dataOutput· methane· carbon dioxide· air· dewpoint%%%°C> 98< 2< 120 - 3596 - 990.5 - 30.8-6096 - 972 - 31-5097 - 981.5 - 20 - 0.5< -20Process conditions· adsorption pressure bar6 - 12 7 - 11228 - 10· water flowm 3 /h 10 - 15 9 8 - 20 5 - 1520 - 25· adsorption temperature °C10 - 25 10 - 25 10-2510 - 25· pressure in flash tank bar2 - 5 no flash tank no data1.5 - 2Supplier Ellinge FEAB Malmberg WaterTable 14: Removal of carbon dioxide using water wash without regenerationRemoval of carbon dioxide using SelexolSelexol is a registered trade mark for a polyglycol e<strong>the</strong>r. The chemical is dissolved in water and hasa very low vapour pressure. This means that <strong>the</strong> losses of chemicals are very low in <strong>the</strong> process.Selexol removes carbon dioxide, hydrogen sulphide and water simultaneously.The selectivity for hydrogen sulphide is very high compared <strong>to</strong> carbon dioxide and regeneration<strong>from</strong> H 2 S requires increased energy input.Carbon dioxide is absorbed in a circulating Selexol solution at elevated pressure. Cleaned bio<strong>gas</strong> iscompressed and fed in<strong>to</strong> <strong>the</strong> bot<strong>to</strong>m of an absorption column. Selexol is fed <strong>from</strong> <strong>the</strong> <strong>to</strong>p of <strong>the</strong>column <strong>to</strong> achieve a <strong>gas</strong>-liquid counter flow. The column is equipped with random packing <strong>to</strong> give alarge surface for <strong>gas</strong>-liquid contact and internals for <strong>the</strong> collecting and redistribution of Selexol.Carbon dioxide is absorbed by <strong>the</strong> Selexol solution and <strong>the</strong> <strong>gas</strong> leaving <strong>the</strong> <strong>to</strong>p of <strong>the</strong> column isstripped <strong>from</strong> most of <strong>the</strong> carbon dioxide content.Methane is partly soluble in pressurised Selexol solution and <strong>the</strong>refore some methane will beremoved with <strong>the</strong> liquid. To minimise <strong>the</strong> losses of methane, <strong>the</strong> Selexol solution is depressurised ina flash tank after leaving <strong>the</strong> absorption column. The released <strong>gas</strong> mixture is rich in methane and isrecirculated <strong>to</strong> <strong>the</strong> compressor inlet.9Depending on <strong>the</strong> absorption pressure, for every 100 m 3 /h processed bio<strong>gas</strong>page: 41

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