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OVERVIEW OF THE IMPACT OF MINING ON THE ... - IIED pubs

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• Antimony, cadmium and tin contamination of surface waters in Greenstone Formations mined for these<br />

metals, or as contaminants in gold mining operations located in Greenstone rock formations in South Africa<br />

and Zimbabwe. Specific examples are the Murchison and Giyani Greenstone Formations in South Africa.<br />

• Copper contamination of various levels arising from copper mines and smelters on the Zambian Copperbelt,<br />

the areas close to the Great Dyke in Zimbabwe, the Selibe-Phikwe copper-nickel mine in eastern Botswana<br />

and the Phalaborwa area in South Africa.<br />

• Iron and manganese contamination of surface streams, either in solution or as unsightly oxy-hydroxide<br />

precipitates, caused by aeration of iron-rich acidic solutions associated with pyrite oxidation and AMD.<br />

Specific examples occur in several iron ore mines and in gold and coalmines in South Africa and Zimbabwe.<br />

• Zinc and lead contamination associated with AMD of low-grade ore stockpiles at Kabwe in Zambia and the<br />

Letaba Mine in South Africa.<br />

• Antimony contamination associated with mines located on the Murchison Greenstone Formation in South<br />

Africa.<br />

6.1.3 Impacts due to the release of potentially toxic substances<br />

The most important issues here relates to the potential for contamination posed by organics and solvents used<br />

to separate metals from their ores during the processing phases. Most attention has been paid to cyanide used<br />

in gold mining because of the very large volumes of cyanide that are used and its toxicity to most forms of life.<br />

Importantly, cyanide can exist in numerous different forms and not all of these forms are equally toxic. In<br />

addition, cyanide is rapidly photo-oxidized to harmless carbon dioxide and nitrogen gas in sunlight, thereby<br />

greatly reducing the potential toxicity risk; the general public seldom appreciates this feature.<br />

Discussions with stakeholders have revealed that their specific areas of concern around potentially toxic<br />

substances relate entirely to issues associated with cyanide and are seldom attributable to any specific mine or<br />

mining operation:<br />

• The discharge of cyanide-rich tailings to tailings dams at most gold mines and their subsequent seepage<br />

from these sites into the aquatic environment.<br />

• Inadequate control maintained over cyanide processes on gold mines such that spillages occur and<br />

contamination results.<br />

• Occasional spillages caused by rupturing of cyanide storage tanks at gold mines, resulting in localized<br />

contamination.<br />

• The potential for the release of toxic hydrocyanic acid (HCN) gas from cyanide-rich tailings at most gold<br />

mines.<br />

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