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Annex 3C Industrial Processes. CRF sector 2 Lime production CRF source category 2.A Mineral Products, 2. Lime Production. SNAP source category 040614. Lime (decarbonizing). Source category description This source includes CO 2 emissions from production of lime/hydrated lime and bricks and represents as such a combined activity in the CRF tables. This Annex serves to explain the source. The source is not a key source neither for the trend nor for the level key source analyses in this report. The production of lime has a slightly falling trend in the time-series 1990-2003, while the production of bricks is slightly increasing until 2000. As a result the CO 2 emission for the combined activity in year 2003 is lower than in 1990, refer to the table below. Methodology The CO 2 emission from production of Lime is calculated according to the IPCC guidelines, Reference Manual p 2.8, with the emission factor of 0.79 kg CO 2 / kg Lime. The CO 2 emission factor for production of Hydrated Lime - 0.541 kg CO 2 /Hydrated Lime - is calculated from the above mentioned emission factor and information on water content obtained from the company. These emission factors are multiplied by activity data from production statistics published by Statistics Denmark, refer the Table below. The emission factor from production of yellow bricks is calculated the following way. When limestone (CaCO 3 ) is heated it decomposes into lime (CaO) and CO 2 . Using the molecular weights, implies that 44 kg of CO 2 is emitted for every 100 kg CaCO 3 decomposed. Since clay used to produce yellow bricks contains 18% of limestone, the emission factor is 0.18*0.44=0.079 kg CO 2 / kg yellow bricks. This emission factor is multiplied by activity data from production statistics published by Statistics Denmark. This Statistics accounts for the number of bricks produced, the average weight of a brick is estimated to 2 kg. Refer to the Table below for the data and the emissions calculated. The activity data and the resulting emissions from production of lime and bricks are aggregated in the CRF, in Table 2(I).A-G sheet 1. The underlying data and the resulting aggregated data are given in the table below. 358
Table. Production of Lime/Hydrated Lime and Bricks, CO 2 emission factors and CO 2 emissions. Ã ÃÃ Production Production of burned CO2 of hydrated CO2 Production CO2 Production CO2 Combined lime emission lime emission emission emission emission factor (1) (2) (1) (3) (4) (5) (6) (6) (6) (t) (Mg) (t) (Mg) (t) (Mg) (kt) (Gg) (t/t) 1990 126706 99555 27686 14978 291348 23016 445,74 137,55 0,31 1991 86226 67749 27561 14911 291497 23028 405,28 105,69 0,26 1992 104526 82128 23821 12887 303629 23987 431,98 119,00 0,28 1993 106587 83747 18482 9999 278534 22004 403,60 115,75 0,29 1994 112480 88377 14781 7996 389803 30794 517,06 127,17 0,25 1995 100929 79301 15865 8583 365149 28847 481,94 116,73 0,24 1996 95028 74665 13600 7358 397206 31379 505,83 113,40 0,22 1997 102587 80604 12542 6785 419431 33135 534,56 120,52 0,23 1998 88922 69867 8445 4569 417301 32967 514,67 107,40 0,21 1999 95137 74751 7654 4141 405241 32014 508,03 110,91 0,22 2000 92002 72287 8159 4414 412082 32554 512,24 109,26 0,21 2001 96486 75810 9012 4875 351955 27804 457,45 108,49 0,24 2002 122641 96361 12006 6495 346633 27384 481,28 130,24 0,27 2003 87549 68789 11721 6341 341981 27016 441,25 102,15 0,23 Notes: (1) Statistics Denmark: Sales Statistics for manufacturing industries. (2) Emission factor 0,786 kg CO2/kg; 1996 IPCC guidelines; reference manual p. 2.8 (3) Emission factor 0,5410 kg CO2/kg; according to producer (Faxe Kalk) (4) Statistics Denmark: Sales Statistics for manufacturing industries, assuming that of the bricks produced and sold, 50% is yellow bricks each with and average weight of 2 kg. (5) Emission factor 0,079 kg CO2/kg, further information in the text. (6) Corresponding to the values in the CRF Table 2(I).A-Gs1, A.2. in this report for the respective years (apart from roundings). Source specific planned improvements The review team in their report on the April 15 2004 submission made a note on the implied emission factor in the CRF tables on this activity. We have considered reporting the two activities separately in the CRF. However, we find the activities so much related both being a decarbonizing process that we find a combination of the activities justified with the explanations given in this Annex. 359
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National Environmental Research Ins
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National Environmental Research Ins
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Contents Executive summary 9 ES.1.
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4.3 Chemical industry (2B) 122 4.3.
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8.3.6 Recalculations 209 8.3.7 Plan
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Executive summary ES.1. Background
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electricity. Also lower outdoor tem
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• The GHG emission inventories fo
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effekten af de forskellige drivhusg
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Som beskrevet i rapportens kapitel
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1 Introduction 1.1 Background infor
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The role of the European Union The
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Table 1.1 List of current data stru
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1.4 Brief general description of me
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1A2f (Industry-other), 1A3a (Civil
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is calculated. It is found that tha
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(see the reference list at Chapter
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1 Quality control (QC) Quality plan
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The different CCP’s are not indep
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When new data are introduced they c
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Inventory report for year 3 Invento
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The uncertainty on N 2 O from stati
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1.8 General assessment of the compl
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2 Trends in Greenhouse Gas Emission
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to change in traditional stable sys
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from national fishing and off-road
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3 Energy (CRF sector 1) 3.1 Overvie
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Table 3.3 CH 4 emission from the en
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Fuel consumption time-series for st
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Degree days Fuel consumption adjust
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Table 3.7 CO 2 emission from subsec
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The CH 4 emission from stationary c
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3.2.1.3.4 SO , NO , NMVOC and CO 2
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The fuel consumption of area source
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Table 3.12 CH 4 emission factors 19
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− Gruijthuijsen & Jensen 2000 −
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ues from Pulles & Aardenne 2001. Th
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• Disaggregation of fuel consumpt
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3.3.1.1 Fuel consumption Table 3.18
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3-@ 90 80 70 60 50 40 30 20 10 0 19
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1,4 1,2 1,0 0,8 0,6 0,4 0,2 0,0 198
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Table 3.19 Emissions of CO 2 , CH 4
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Passenger cars 56% Passenger cars 8
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WRQV@ 120 100 80 60 40 20 0 1985 19
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70000 60000 50000 40000 30000 20000
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The NO X emission trend for Agricul
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Bunkers The most important emission
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Ã Ã Ã Ã Ã Ã
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age the emissions from catalyst car
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Where S C is the soak emission, l t
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3.3.2.2 Methodologies and reference
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Table 3.26 Fuel specific emission f
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Where E = emission, FC = fuel consu
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For non-road machinery and working
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Emission factors The Danish greenho
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A comparison of the national approa
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( , 4 = = ( ; 4 + ( , 4 −2
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In the 1990-1999 inventories fugiti
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Table 3.38 Uncertainty, CRF sector
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4 Industrial processes (CRF Sector
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The time-series for emission of CO
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4.2.5 Recalculations No source spec
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4.4 Metal production (2C) 4.4.1 Sou
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Table 4.8 Consumption of HFCs in fo
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The potential emissions have been c
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cedure consisted of a check of the
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Danish Environmental Protection Age
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Table 5.1 Emission of chemicals in
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5.2.2 Methodological issues The emi
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(ii) Collection of data for quantif
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6 The emission of greenhouse gases
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Table 6.2 List of institutes involv
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NERI receives the data from differe
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approximately 6%, which nearly corr
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6.3.2 Methodological issues 6.3.2.1
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Table 6.11 Nitrogen excretion, annu
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Table 6.14 Emissions factor - N 2 O
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153
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Table 6.20 Emissions from crop resi
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Ã Ã Ã Ã Ã 80
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6.5 NMVOC emission Less than 1% of
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• This years data delivery agreem
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Husted, 1994: Waste Management, Sea
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7 The Specific methodologies regard
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In 1990, the forested area with tre
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inventory will be quite similar to
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Table 7.4 Data on gross uptake of C
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place during the first 30 years fol
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7.2.5 Recalculations Since the subm
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Table 7.8 Agricultural areas in Den
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7.3.2.1 Emission from mineral soils
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Table 7.17 C-emission from organic
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Table 7.19 Area classification of t
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The LULUCF sector contributes to a
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Schöne, D. and Schulte, A. (1999).
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Table A2.3 ÃÃÃÃÃÃÃÃÃÃ
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As a result the sectoral total in C
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Since, the Danish SWDSs are well-ma
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Table 8.8. Amounts of waste and CH
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Combustible” and “Other not Com
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which disaggregation level that can
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tion, technical upgrades of the WWT
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assuming that the treatment is 100%
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intermediate of both processes. Dan
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Table 8.19. Uncertainties for main
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In general country-specific TOW val
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Danish Environmental Protection Age
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9 Other (CRF sector 7) Chapter 9 is
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Table 10.1 Recalculation performed
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Table 10.2. Recalculation performed
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For the Industrial Sector uncertain
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Annex 1 Key source analyses Descrip
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7KH UHVXOW RI WKH NH\ VRXUFH DQDO\V
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7DEOHV $ ± $ RI WKH *RRG 3UDFWLFH
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Table 3. Key source analysis 1990-2
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Annex 3 Other detailed methodologic
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1 Introduction The Danish atmospher
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Stationary combustion plants are in
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Emissions from non-energy use of fu
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Coke oven coke The emission factor
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Kerosene The emission factor 72 kg/
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Illerup 2003. The estimated emissio
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The emission factor for CHP plants
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− Fuel consumption for transport.
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tricity trade, fuel consumption and
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Figure 3A-6 depicts the time-series
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1A4a Commercial / Institutional 2%
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CO 2 [Tg] 60 50 40 30 20 10 0 1990
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Other stationary combustion plants
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1A4a Commercial / Institutional 2%
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only accounted for a small portion
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Electricity and heat production is
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The use of wood in residential boil
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straw consumption in residential pl
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• The IPCC reference approach val
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Table 3A-21 Key sources, stationary
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emission are N 2 O emission (all pl
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enewable fuels has increased. The D
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Jørgensen, L. & Johansen, L. P. 20
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Appendix 3A-1 The Danish emission i
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030203 Blast furnace cowpers 1A2a 0
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Table 3A-28 Detailed fuel consumpti
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1A2f 118 SEWAGE SLUDGE 030311 40162
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Appendix 3A-4 Emission factors Tabl
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Table 3A-33 N 2 O emission factors
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7. Bjerrum M., 2002. Danish Technol
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NOX NATURAL GAS 010105 1A1a 276 241
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019 Enstedvaerket 04 010101 204 GAS
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Table 3A-39 Large point sources, pl
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Appendix 3A-6 Uncertainty estimates
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Table 3A-42 Uncertainty estimation,
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Table 3A-47 Uncertainty estimation,
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Table 3A-49 Fuel category correspon
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Appendix 3A-9 Reference approach Ã
Page 309 and 310: Table 3A-51 Fuel category correspon
Page 311 and 312: 20201 - - - - - - - - - - - - - - -
Page 313 and 314: Passenger Cars Diesel >2.0 l Euro I
Page 315 and 316: Passenger Cars Gasoline 2.0 l Euro
Page 317 and 318: Buses Urban Buses Conventional 0 19
Page 319 and 320: Sector Subsector Tech FYear LYear 1
Page 325 and 326: Sector Subsector Tech FCu FCr FCh C
Page 327 and 328: Sector Subsector Tech COu COr COh N
Page 329 and 330: Sector Subsector Tech COuR COrR COh
Page 331 and 332: Annex 3B-5: Fuel use factors (MJ/km
Page 333 and 334: 2-wheelers 1999 1.195 1.264 1.578 8
Page 335 and 336: 2-wheelers 1991 6.249 4.379 2.011 6
Page 337 and 338: 2002 Heavy Duty Vehicles 37849451 8
Page 339 and 340: Annex 3B-7: COPERT III:DEA statisti
Page 341 and 342: 0808 Excavators (wheel type) 1000 1
Page 343 and 344: 0808 Forklifts 5-10 tons (diesel) 0
Page 345 and 346: 0809 Trimmers 60000 0.8 0.5 15 10 1
Page 347 and 348: 1990 80502 Air traffic. other airpo
Page 349 and 350: 2003 80403 Fishing Kerosene 731 4.6
Page 351 and 352: Year Category Mode SO2 NOx NMVOC CH
Page 353 and 354: Pollutant CRF ID Unit 1985 1986 198
Page 355 and 356: Pollutant CRF ID Unit 1985 1986 198
Page 357 and 358: Uncertainty estimation, CH 4 Gas Ba
Page 359: Uncertainty estimation, N 2 O IPCC
Page 363 and 364: Suckling cattle 170.2 Swine Average
Page 365 and 366: 7DEOH 'HWDLOHG LQIRUPDWLRQ UHODWHG
Page 367 and 368: 7DEOH &KDQJHV LQ VWDEOH W\SH ± Liv
Page 369 and 370: Pullet, consumption, floor (100 pcs
Page 371 and 372: Annex 3E Solid Waste Disposal on La
Page 373 and 374: B = Biological N = Nitrification (r
Page 375 and 376: Table 3E.7. Stabilisation of sludge
Page 377 and 378: in Table 3E.9. Table 3E.9 Gross emi
Page 379 and 380: 5HFRYHUHG &+ Ã HPLVVLRQV >*J@ 14.
Page 381 and 382: Annex 3F Solvents National Atmosphe
Page 383 and 384: 83 1-ethyl-2,2,6-trimethylcyclohexa
Page 385 and 386: 191 2-methoxy-2-methylpropane 192 2
Page 387 and 388: 299 acetaldehyde 300 acetic acid 30
Page 389 and 390: 407 cyclopentane 408 cyclopenta-phe
Page 391 and 392: 515 methyl naphthalenes 516 methyl
Page 393 and 394: 624 trans-3-hexene 625 trialkyl pho
Page 395 and 396: Annex 5 Assessment of completeness
Page 397 and 398: Annex 6.1 Annex 6.1. Additional inf
Page 399 and 400: Table A6.1.2 ÃÃÃÃ Kingdom DK Ã
Page 401 and 402: Table A6.1.4 ÃÃÃÃÃÃÃÃÃ Kin
Page 403 and 404: Annex 6.2 Additional information to
Page 405 and 406: Annex 7 Table 6.1 and 6.2 of the IP
Page 407 and 408: Annex 8 Other annexes - (Any other
Page 409 and 410: PM 2.2: An explicit description in
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Correctness The data at level 3 has
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Level 6 Transparency The background
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Table A9.1 ÃÃÃÃ Denmark ÃÃÃ
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Table A9.3 ÃÃÃÃ Denmark ÃÃÃ
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