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N-(1,3-Dimethylbutyl)-N

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OECD SIDS<br />

N-(1,3-DIMETHYLBUTYL)-N´-PHENYL-1,4-PHENYLENEDIAMINE<br />

1. GENERAL INFORMATION ID: 793-24-8<br />

DATE: 11.05.2005<br />

1.7 USE PATTERN<br />

Type of use : Type<br />

Category : Use resulting in inclusion into or onto matrix<br />

Flag : Critical study for SIDS endpoint<br />

08.08.2003 (11)<br />

Type of use : Industrial<br />

Category : Polymers industry<br />

Result : 6PPD is used as rubber antidegradant which reacts as an excellent<br />

antiozonant. The main area of application is the rubber sector, with the<br />

majority of the manufacturing volume going into tyres.<br />

Flag : Critical study for SIDS endpoint<br />

08.08.2003 (11)<br />

Type of use : Use<br />

Category : Stabilizers<br />

Flag : Critical study for SIDS endpoint<br />

08.08.2003 (11)<br />

1.7.1 DETAILED USE PATTERN<br />

Industry category : 11 Polymers industry<br />

Use category : 49 Stabilizers<br />

Extra details on use category : Polymerization processes<br />

No extra details necessary<br />

Emission scenario document : not available<br />

Product type/subgroup : 09 Fibre, leather, rubber and polymerised materials<br />

preservatives<br />

Tonnage for Application :<br />

Year :<br />

Fraction of tonnage for application : 1<br />

Fraction of chemical in formulation : .008<br />

Production : yes: Ib Intermed. stored on-site/continuous prod.<br />

Formulation : no:<br />

Processing : no:<br />

Private use : No<br />

Recovery : No<br />

Remark : According to Hawley (1977), product is used as antiozonant, antioxidant,<br />

and polymer stabilizer<br />

24.06.2003 (1)<br />

1.7.2 METHODS OF MANUFACTURE<br />

Origin of substance : Synthesis<br />

Type : Production<br />

Method : In a continuously working closed system 4-aminodiphenylamine is reacted<br />

with an excess of methyl isobutyl ketone (MIBK) to a Schiff´s base. This<br />

base is then hydrogenated catalytically.<br />

03.08.2003 (10)<br />

44<br />

UNEP PUBLICATIONS

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