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NASA Scientific and Technical Aerospace Reports

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13.4% on a non-textured single-sided heterojunction solar cell on p-type CZ-Si processed with optimized surface treatment.<br />

NTIS<br />

Crystal Surfaces; Crystals; Heterojunction Devices; Passivity; Silicon; Solar Cells; Vapor Deposition<br />

20060002209 National Renewable Energy Lab., Golden, CO USA<br />

Relationship of Recombination Lifetime <strong>and</strong> Dark Current In Silicon p-n Junctions<br />

Ahrenkiel, R. K.; Metzger, W.; Page, M.; Reedy, R.; Feb. 2005; 12 pp.; In English<br />

Report No.(s): DE2005-15016492; NREL/CP-520-37438; No Copyright; Avail.: National <strong>Technical</strong> Information Service<br />

(NTIS)<br />

Measurement of recombination <strong>and</strong> minority-carrier lifetimes has become a central activity in photovoltaic technology.<br />

The primary measurement techniques for silicon technologies are based on photoconductive decay (PCD) <strong>and</strong> microwave<br />

reflectance (mPCD). The measurement of the correct recombination lifetime depends on the carriers being confined to a given<br />

spatial region of a diagnostic structure. The internal electric fields separate the charges, <strong>and</strong> the measured value does not<br />

represent the real minority-carrier lifetime. In these cases, the measured quantity is a function of the true lifetime <strong>and</strong> the<br />

sample structure. Here, we examine these effects, both experimentally <strong>and</strong> theoretically, for the n(sup +)-p device structure<br />

common to terrestrial photovoltaics.<br />

NTIS<br />

Dark Current; P-N Junctions; Silicon; Silicon Junctions<br />

20060002210 National Renewable Energy Lab., Golden, CO USA<br />

Comprehensive Model of Hydrogen Transport into a Solar Cell During Silicon Nitride Processing for Fire-Through<br />

Metallization<br />

Sopori, B.; Reedy, R.; Jones, K.; Al-Jassim, M.; Aug. 2004; 12 pp.; In English<br />

Report No.(s): DE2005-15016499; NREL/CP-520-37477; No Copyright; Avail.: National <strong>Technical</strong> Information Service<br />

(NTIS)<br />

A mechanism for the transport of H into a Si solar cell during plasma-enhanced chemical vapor deposition (PECVD) of<br />

a hydrogenated silicon nitride (SiN:H) layer <strong>and</strong> its subsequent fire-through metallization process is described. The PECVD<br />

process generates process-induced traps, which ‘’store’’ H at the surface of the solar cell. This stored H is released <strong>and</strong> diffuses<br />

rapidly into the bulk of Si during the high-temperature metallization-firing process. During the ramp-down, the diffused H<br />

associates with impurities <strong>and</strong> defects <strong>and</strong> passivates them. The firing step partially heals up the surface damage. The proposed<br />

model explains a variety of observations <strong>and</strong> experimental results.<br />

NTIS<br />

Fires; Hydrogen; Metallizing; Silicon Nitrides; Solar Cells<br />

20060002211 National Renewable Energy Lab., Golden, CO USA<br />

Effective Interfaces in Silicon Heterojunction Solar Cells<br />

Wang, T. H.; Iwaniczko, E.; Page, M. R.; Levi, D. H.; Feb. 2005; 12 pp.; In English<br />

Report No.(s): DE2005-15016495; NREL/CP-37457; No Copyright; Avail.: National <strong>Technical</strong> Information Service (NTIS)<br />

This paper reviews the current commercial status of CuInSe2 alloys (collectively, CIS) <strong>and</strong> CdTe-based photovoltaic (PV)<br />

modules, comparing the performance of commercial products with the results achieved for solar cell <strong>and</strong> prototype module<br />

champions. We provide an update for these PV cell <strong>and</strong> module technologies, <strong>and</strong> also compare CIS <strong>and</strong> CdTe performance<br />

levels to the results achieved by the crystalline Si PV industry. This comparison shows that CIS <strong>and</strong> CdTe module technology<br />

presently offers the best (<strong>and</strong> perhaps only) approach for significantly exceeding the cost/performance levels established by<br />

crystalline Si PV technologies. A semi-empirical methodology is used for comparing ‘’champion’’ solar cell <strong>and</strong> prototype<br />

module data with performance achieved on manufacturing lines. Using a conservative assumption that thin-film technologies<br />

will eliminate the 40% of PV module costs arising from the Si wafer or ribbon, we estimate the future performance of all<br />

established PV module c<strong>and</strong>idates, <strong>and</strong> conclude that, based on 2004 knowledge about each PV technology, CIS <strong>and</strong> CdTe<br />

should provide cost-competitive advantages over crystalline Si.<br />

NTIS<br />

Heterojunction Devices; Heterojunctions; Silicon; Solar Cells<br />

20060002212 National Renewable Energy Lab., Golden, CO USA<br />

Enhanced-Depletion-Width GalnNAs Solar Cells Grown by Molecular-Beam Epitaxy<br />

Ptak, A. J.; Friedman, D. J.; Kurtz, S.; Kiehl, J.; Feb. 2005; 12 pp.; In English<br />

Report No.(s): DE2005-15016500; NREL/CP-520-37479; No Copyright; Avail.: Department of Energy Information Bridge<br />

96

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