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Callister - An introduction - 8th edition

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124 • Chapter 5 / Diffusion<br />

Cu<br />

(a)<br />

Ni<br />

Figure 5.1 (a) A copper–nickel diffusion couple<br />

before a high-temperature heat treatment. (b)<br />

Schematic representations of Cu (red circles) and<br />

Ni (blue circles) atom locations within the diffusion<br />

couple. (c) Concentrations of copper and nickel as a<br />

function of position across the couple.<br />

(b)<br />

Concentration of Ni, Cu<br />

100<br />

0<br />

Cu<br />

Position<br />

Ni<br />

(c)<br />

interdiffusion<br />

impurity diffusion<br />

both metals vary with position as shown in Figure 5.2c. This result indicates that<br />

copper atoms have migrated or diffused into the nickel, and that nickel has diffused<br />

into copper. This process, whereby atoms of one metal diffuse into another,<br />

is termed interdiffusion, or impurity diffusion.<br />

Cu<br />

Diffusion of Cu atoms<br />

Cu–Ni alloy<br />

Diffusion of Ni atoms<br />

(a)<br />

Ni<br />

Figure 5.2 (a) A copper–nickel diffusion couple<br />

after a high-temperature heat treatment, showing the<br />

alloyed diffusion zone. (b) Schematic representations<br />

of Cu (red circles) and Ni (blue circles) atom<br />

locations within the couple. (c) Concentrations of<br />

copper and nickel as a function of position across<br />

the couple.<br />

(b)<br />

Concentration of Ni, Cu<br />

100<br />

0<br />

Cu Ni<br />

Position<br />

(c)

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