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Callister - An introduction - 8th edition

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400 • Chapter 11 / Applications and Processing of Metal Alloys<br />

Figure 11.2 The<br />

true equilibrium<br />

iron–carbon phase<br />

diagram with<br />

graphite instead of<br />

cementite as a stable<br />

phase. [Adapted<br />

from Binary Alloy<br />

Phase Diagrams,<br />

T. B. Massalski<br />

(Editor-in-Chief),<br />

1990. Reprinted by<br />

permission of ASM<br />

International,<br />

Materials Park, OH.]<br />

Temperature (°C)<br />

Composition (at% C)<br />

0 5 10 15 98<br />

1600<br />

1400<br />

1200<br />

1000<br />

800<br />

(Austenite)<br />

+ L<br />

Liquid<br />

1153°C<br />

2.1 wt% C<br />

740°C<br />

4.2 wt% C<br />

+ Graphite<br />

Liquid<br />

+<br />

Graphite<br />

2500<br />

2000<br />

1500<br />

Temperature (°F)<br />

600<br />

0.65 wt% C<br />

(Ferrite)<br />

+ Graphite<br />

1000<br />

400 0 1 2 3 4<br />

Composition (wt% C)<br />

90 100<br />

Graphite<br />

gray cast iron<br />

Gray Iron<br />

The carbon and silicon contents of gray cast irons vary between 2.5 and 4.0 wt%<br />

and 1.0 and 3.0 wt%, respectively. For most of these cast irons, the graphite exists<br />

in the form of flakes (similar to corn flakes), which are normally surrounded by an<br />

-ferrite or pearlite matrix; the microstructure of a typical gray iron is shown in Figure<br />

11.3a. Because of these graphite flakes, a fractured surface takes on a gray appearance,<br />

hence its name.<br />

(a)<br />

20 m<br />

(b)<br />

50 m

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