Callister - An introduction - 8th edition

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A34 • Appendix C / Costs and Relative Costs for Selected Engineering Materials Material/Condition Cost ($US/kg) Relative Cost Glass, borosilicate (Pyrex), plate 9.20–11.30 7.9 Glass, soda–lime, plate 0.56–1.35 0.7 Glass-ceramic (Pyroceram), plate 12.65–16.55 11.3 Graphite • Powder, synthetic, 99% pure, particle 1.80–7.00 3.1 size, ~10 m • Isostatically pressed parts, high purity, ~20-m 50.00–125.00 65.3 particle size Silica, fused, plate 1200–1700 1100 Silicon • Test grade, undoped, 100-mm-dia. wafers, 5100–9000 5500 ~425 m thick • Prime grade, undoped, 100-mm-dia. wafers, 8000–14,000 8800 ~425 m thick Silicon carbide • -phase ball grinding media, 1 ⁄4 in. dia., sintered 250.00 194 Silicon nitride • Powder, submicron particle size 100–200 100 • Balls, finished ground, 0.25 in. to 0.50 in. diameter, hot isostatically pressed 1000–4000 1600 Zirconia (5 mol% Y 2 O 3 ), 15-mm-dia. ball 50–200 97.1 grinding media POLYMERS Butadiene-acrylonitrile (nitrile) rubber • Raw and unprocessed 4.00 3.1 • Extruded sheet ( 1 ⁄4– 1 ⁄8 in. thick) 8.25 6.4 • Calendered sheet ( 1 ⁄4– 1 ⁄8 in. thick) 5.25–7.40 4.9 Styrene-butadiene (SBR) rubber • Raw and unprocessed 1.70 1.3 • Extruded sheet ( 1 ⁄4– 1 ⁄8 in. thick) 5.05 3.9 • Calendered sheet ( 1 ⁄4– 1 ⁄8 in. thick) 3.25–3.75 2.7 Silicone rubber • Raw and unprocessed 9.90–14.00 9.5 • Extruded sheet ( 1 ⁄4– 1 ⁄8 in. thick) 28.00–29.50 22.4 • Calendered sheet ( 1 ⁄4– 1 ⁄8 in. thick) 7.75–12.00 7.7 Epoxy resin, raw form 2.20–2.80 1.9 Nylon 6,6 • Raw form 3.20–4.00 2.8 • Extruded 12.80 9.9 Phenolic resin, raw form 1.65–1.90 1.4 Poly(butylene terephthalate) (PBT) • Raw form 4.00–7.00 4.3 • Sheet 40.00–100.00 54.3 Polycarbonate (PC) • Raw form 3.00–4.70 2.9 • Sheet 10.50 8.2 Polyester (thermoset), raw form 3.10–4.30 2.7 Polyetheretherketone (PEEK), raw form 90.00–105.00 76.0 Polyethylene • Low density (LDPE), raw form 1.60–1.85 1.3 • High density (HDPE), raw form 1.20–1.75 1.2 • Ultrahigh molecular weight (UHMWPE), 2.20–3.00 2.1 raw form
Appendix C / Costs and Relative Costs for Selected Engineering Materials • A35 Material/Condition Cost ($US/kg) Relative Cost Poly(ethylene terephthalate) (PET) • Raw form 1.50–1.75 1.3 • Sheet 3.30–5.40 3.4 Poly(methyl methacrylate) (PMMA) 3.1 • Raw form 2.60–5.40 3.1 • Extruded sheet ( 1 ⁄4 in. thick) 4.65–6.05 4.1 Polypropylene (PP), raw form 1.05–1.70 1.2 Polystyrene (PS), raw form 1.55–1.95 1.4 Polytetrafluoroethylene (PTFE) • Raw form 14.80–16.90 11.9 • Rod 21.00 16.3 Poly(vinyl chloride) (PVC), raw form 1.10–1.85 1.2 FIBER MATERIALS Aramid (Kevlar 49), continuous 35.00–100.00 38.8 Carbon (PAN precursor), continuous • Standard modulus 40.00–80.00 48.1 • Intermediate modulus 60.00–130.00 69.1 • High modulus 220.00–275.00 193 E-glass, continuous 1.55–2.65 1.6 COMPOSITE MATERIALS Aramid (Kevlar 49) continuous-fiber, epoxy prepreg 75.00–100.00 66.8 Carbon continuous-fiber, epoxy prepreg • Standard modulus 49.00–66.00 43.1 • Intermediate modulus 75.00–240.00 123 • High modulus 120.00–725.00 330 E-glass continuous-fiber, epoxy prepreg 24.00–50.00 28.3 Woods • Douglas fir 0.61–0.97 0.6 • Ponderosa pine 1.15–1.50 1.0 • Red oak 3.35–3.75 2.8
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Characteristics of Selected Element
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With WileyPLUS: This online teachin
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E IGHTH E DITION Materials Science
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Dedicated to our wives, Nancy and E
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viii • Preface FEATURES THAT ARE
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x • Preface 2. Answers to Concept
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Appreciation is expressed to those
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xiv • Contents 3. The Structure o
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xvi • Contents 9.12 Development o
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xviii • Contents 15.14 Factors Th
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xx • Contents 21.14 Optical Fiber
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xxii • List of Symbols HK Knoop
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Chapter 1 Introduction A familiar i
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1.2 Materials Science and Engineeri
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1.4 Classification of Materials •
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1.5 Advanced Materials • 11 aeros
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1.6 Modern Materials’ Needs • 1
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STEELS Processing Diffusion ➣ Rec
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Question • 17 REFERENCES Ashby, M
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WHY STUDY Atomic Structure and Inte
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2.3 Electrons in Atoms • 21 Orbit
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2.3 Electrons in Atoms • 23 Table
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2.3 Electrons in Atoms • 25 Table
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2.4 The Periodic Table • 27 Metal
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2.5 Bonding Forces and Energies •
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2.6 Primary Interatomic Bonds • 3
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2.6 Primary Interatomic Bonds • 3
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2.7 Secondary Bonding or van der Wa
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2.7 Secondary Bonding or van der Wa
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Summary • 39 Primary Interatomic
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Questions and Problems • 41 QUEST
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Questions and Problems • 43 Sprea
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WHY STUDY The Structure of Crystall
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lattice 3.4 Metallic Crystal Struct
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3.4 Metallic Crystal Structures •
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3.5 Density Computations • 51 EXA
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3.7 Crystal Systems • 53 Another
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3.8 Point Coordinates • 55 Concep
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3.9 Crystallographic Directions •
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3.10 Crystallographic Planes • 63
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3.12 Close-Packed Crystal Structure
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3.12 Close-Packed Crystal Structure
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3.15 Anisotropy • 73 (a) (b) grai
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3.16 X-Ray Diffraction: Determinati
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0° 3.16 X-Ray Diffraction: Determi
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3.17 Noncrystalline Solids • 79 (
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Summary • 81 Point Coordinates Cr
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Processing/Structure/Properties/Per
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Questions and Problems • 85 118.7
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Questions and Problems • 89 Inten
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WHY STUDY Imperfections in Solids?
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self-interstitial increases exponen
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2. Crystal structure. For appreciab
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4.4 Specification of Composition
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4.5 Dislocations—Linear Defects
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4.5 Dislocations—Linear Defects
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4.6 Interfacial Defects • 103 Ang
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4.6 Interfacial Defects • 105 MAT
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the order of 10 13 vibrations per s
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4.10 Microscopic Techniques • 109
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4.10 Microscopic Techniques • 111
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4.11 GRAIN SIZE DETERMINATION grain
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Summary • 115 Specification of Co
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Summary • 117 List of Symbols Sym
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Questions and Problems • 119 (a)
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Design Problems • 121 (a) at a ma
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WHY Study Diffusion? Materials of a
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5.2 Diffusion Mechanisms • 125 se
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5.3 Steady-State Diffusion • 127
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5.4 Nonsteady-State Diffusion • 1
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5.4 Nonsteady-State Diffusion • 1
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5.5 Factors That Influence Diffusio
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5.5 Factors That Influence Diffusio
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5.6 Diffusion in Semiconducting Mat
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is only an approximation), then the
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5.6 Diffusion in Semiconducting Mat
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Summary • 143 Diffusion in Semico
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Questions and Problems • 145 QUES
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Diffusion coefficient (m 2 /s) 10 -
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Design Problems • 149 the process
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WHY STUDY The Mechanical Properties
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6.2 Concepts of Stress and Strain
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6.2 Concepts of Stress and Strain
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6.3 Stress-Strain Behavior • 157
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6.4 Anelasticity • 159 Figure 6.8
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6.5 Elastic Properties Of Materials
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6.6 Tensile Properties • 163 Figu
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6.6 Tensile Properties • 165 in F
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6.6 Tensile Properties • 167 Brit
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6.6 Tensile Properties • 169 y F
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6.7 True Stress and Strain • 171
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6.9 Compressive, Shear, and Torsion
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Table 6.5 Hardness-Testing Techniqu
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Brinell Hardness Tests 15 6.10 Hard
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6.10 Hardness • 179 are contained
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6.11 Variability Of Material Proper
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6.12 Design/Safety Factors • 183
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Summary • 185 • For an isotropi
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Summary • 187 6.15 s T F True st
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Questions and Problems • 189 a lo
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Questions and Problems • 191 tens
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Questions and Problems • 193 modu
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Design Problems • 195 (a) Determi
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Chapter 7 Dislocations and Strength
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Dislocations and Plastic Deformatio
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7.3 Characteristics of Dislocations
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7.4 Slip Systems • 203 D B A (a)
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7.5 Slip in Single Crystals • 205
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7.5 Slip in Single Crystals • 207
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7.6 Plastic Deformation of Polycrys
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7.7 Deformation by Twinning • 211
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7.9 Solid-Solution Strengthening
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7.10 Strain Hardening • 215 (a) (
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7.10 Strain Hardening • 217 600 2
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7.11 RECOVERY recovery 7.12 RECRYST
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7.12 Recrystallization • 221 (e)
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7.12 Recrystallization • 223 DESI
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Summary • 225 Figure 7.25 The log
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Summary • 227 Strain Hardening
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Questions and Problems • 229 Iron
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Questions and Problems • 231 and
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Design Problems • 233 Spreadsheet
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WHY STUDY Failure? The design of a
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8.3 Ductile Fracture • 237 Figure
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8.4 Brittle Fracture • 239 8.4 BR
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8.4 Brittle Fracture • 241 SEM Mi
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8.5 Principles of Fracture Mechanic
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8.6 Fracture Toughness Testing •
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8.6 Fracture Toughness Testing •
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8.7 Cyclic Stresses • 255 Most ce
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8.8 The S-N Curve • 257 fatigue l
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8.9 Crack Initiation and Propagatio
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8.9 Crack Initiation and Propagatio
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8.10 Factors that Affect Fatigue Li
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8.12 Generalized Creep Behavior •
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8.13 Stress and Temperature Effects
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8.15 Alloys For High-Temperature Us
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Summary • 271 Ductile Fracture
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Summary • 273 • The presence of
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fatigue limit fatigue strength frac
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Questions and Problems • 277 Cycl
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Design Problems • 279 8.31 A cyli
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Chapter 9 Phase Diagrams The graph
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Definitions and Basic Concepts 9.2
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9.5 PHASE EQUILIBRIA equilibrium fr
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phases is along curve aO—likewise
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9.8 Interpretation of Phase Diagram
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9.9 Development of Microstructure i
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9.10 Mechanical Properties of Isomo
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9.11 Binary Eutectic Systems • 29
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9.12 Development of Microstructure
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9.13 Equilibrium Diagrams Having In
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9.14 Eutectoid and Peritectic React
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9.15 Congruent Phase Transformation
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9.17 The Gibbs Phase Rule • 317 F
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The Iron-Carbon System 9.18 The Iro
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9.18 The Iron-Iron Carbide (Fe-Fe 3
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Summary • 331 SUMMARY Introductio
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Summary • 333 Development of Micr
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Questions and Problems • 335 Impo
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Questions and Problems • 337 (b)
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Questions and Problems • 339 Figu
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WHY STUDY Phase Transformations? Th
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10.3 The Kinetics of Phase Transfor
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10.4 Metastable versus Equilibrium
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10.5 Isothermal Transformation Diag
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10.6 Continuous Cooling Transformat
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10.6 Continuous Cooling Transformat
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10.7 Mechanical Behavior of Iron-Ca
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10.7 Mechanical Behavior of Iron-Ca
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10.8 TEMPERED MARTENSITE In the as-
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10.8 Tempered Martensite • 377 (b
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10.9 Review of Phase Transformation
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Summary • 381 Figure 10.37. Of co
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Summary • 383 Spheroidite—is co
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Questions and Problems • 385 Stee
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Questions and Problems • 389 (c)
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Chapter 11 Applications and Process
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11.2 Ferrous Alloys • 393 Types o
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11.2 Ferrous Alloys • 395 Table 1
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11.2 Ferrous Alloys • 397 Table 1
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11.2 Ferrous Alloys • 399 is exte
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11.2 Ferrous Alloys • 401 (c) 20
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Table 11.5 Designations, Minimum Me
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11.2 Ferrous Alloys • 405 is pres
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11.3 Nonferrous Alloys • 407 Tabl
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Table 11.9 Compositions, Mechanical
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11.3 Nonferrous Alloys • 415 or n
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11.4 Forming Operations • 417 Met
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11.5 Casting • 419 that have rath
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11.6 Miscellaneous Techniques • 4
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11.7 Annealing Processes • 423 ox
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modification of mechanical properti
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11.8 Heat Treatment of Steels • 4
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11.9 Precipitation Hardening • 43
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Summary • 443 Forming Operations
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Summary • 445 PROCESSING Recrysta
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Questions and Problems • 447 REFE
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Design Problems • 449 and temperi
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Chapter 12 Structures and Propertie
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12.2 Crystal Structures • 453 Con
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12.2 Crystal Structures • 455 Tab
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12.2 Crystal Structures • 457 Fur
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12.2 Crystal Structures • 459 VMS
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12.2 Crystal Structures • 461 Tet
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12.2 Crystal Structures • 463 EXA
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12.3 Silicate Ceramics • 465 Si 4
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12.3 Silicate Ceramics • 467 Figu
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12.4 Carbon • 469 Figure 12.16 Sc
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Another molecular form of carbon ha
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12.5 Imperfections in Ceramics •
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12.5 Imperfections in Ceramics •
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12.7 Ceramic Phase Diagrams • 477
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12.7 Ceramic Phase Diagrams • 479
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12.8 Brittle Fracture of Ceramics
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12.8 Brittle Fracture of Ceramics
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flexural strength Flexural strength
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12.10 Mechanisms of Plastic Deforma
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viscosities at ambient temperatures
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Summary • 491 Table 12.6 Vickers
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Summary • 493 • Diagrams for Al
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Questions and Problems • 495 visc
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Questions and Problems • 497 does
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Questions and Problems • 499 Stre
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Chapter 13 Applications and Process
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13.3 Glass-Ceramics • 503 Ceramic
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13.5 Refractories • 505 Glass-cer
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13.6 Abrasives • 507 (2910F). Thu
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13.8 Advanced Ceramics • 509 Seve
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13.8 Advanced Ceramics • 511 opti
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13.9 Fabrication and Processing of
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13.11 Powder Pressing • 523 a sca
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13.12 Tape Casting • 525 Figure 1
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Summary • 527 • Requirements fo
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Summary • 529 This chapter also d
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13.12 Compare the softening points
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WHY STUDY Polymer Structures? A rel
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14.3 Polymer Molecules • 535 Tabl
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14.4 The Chemistry of Polymer Molec
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14.4 The Chemistry of Polymer Molec
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Figure 14.3 Hypothetical polymer mo
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14.5 Molecular Weight • 543 Table
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14.7 Molecular Structure • 545 Fi
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14.8 Molecular Configurations • 5
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14.8 Molecular Configurations • 5
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14.10 Copolymers • 551 adjacent c
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14.11 Polymer Crystallinity • 553
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For copolymers, as a general rule,
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14.12 Polymer Crystals • 557 ~ 10
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14.14 Diffusion in Polymeric Materi
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Summary • 561 PET is permeable to
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Equation Summary Summary • 563 Po
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Important Terms and Concepts Questi
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Questions and Problems • 567 age
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Chapter 15 Characteristics, Applica
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15.2 Stress-Strain Behavior • 571
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15.3 Macroscopic Deformation • 57
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15.4 Viscoelastic Deformation • 5
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15.4 Viscoelastic Deformation • 5
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15.5 Fracture of Polymers • 579 F
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15.7 Deformation of Semicrystalline
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t 0 t t 0 t 0 Stage 1 Stage 2 (a) (
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15.8 Factors That Influence the Mec
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15.8 Factors That Influence the Mec
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15.9 Deformation of Elastomers •
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15.10 Crystallization • 591 Norma
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15.13 Melting and Glass Transition
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15.14 Factors That Influence Meltin
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15.15 Plastics • 597 Table 15.3 (
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15.16 Elastomers • 599 ing phenol
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15.18 Miscellaneous Applications
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15.19 Advanced Polymeric Materials
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15.19 Advanced Polymeric Materials
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The tensile modulus of this TPE mat
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15.20 Polymerization • 609 Additi
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15.22 Forming Techniques for Plasti
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15.22 Forming Techniques for Plasti
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15.24 Fabrication of Fibers and Fil
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Factors That Influence the Mechanic
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Summary • 619 Equation Summary Eq
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Questions and Problems • 621 McCr
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Questions and Problems • 623 Tens
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Design Questions • 625 Elastomers
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3.1 Hardness • 627 WHY STUDY Comp
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16.1 Introduction • 629 Dispersed
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16.2 Large-Particle Composites •
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16.2 Large-Particle Composites •
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Critical fiber length—dependence
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16.5 Influence of Fiber Orientation
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ut, because s/E, 16.5 Influence o
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16.6 The Fiber Phase • 645 Applic
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eactions with the environment. Such
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16.8 Polymer-Matrix Composites •
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16.8 Polymer-Matrix Composites •
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16.9 Metal-Matrix Composites • 65
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The high-temperature creep and rupt
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16.12 HYBRID COMPOSITES hybrid comp
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16.13 Processing of Fiber-Reinforce
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16.15 Sandwich Panels • 661 Figur
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Summary • 663 they remain separat
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Summary • 665 When l l c , Equat
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References • 667 List of Symbols
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Design Problems • 671 to be align
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Chapter 17 Corrosion and Degradatio
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Corrosion of Metals 17.2 Electroche
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17.2 Electrochemical Considerations
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17.4 Prediction of Corrosion Rates
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17.5 Passivity • 691 to further c
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17.7 Forms of Corrosion • 693 sur
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17.7 Forms of Corrosion • 695 Fig
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sodium chloride. Dilute sulfuric ac
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17.10 Oxidation • 703 Zinc coatin
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17.10 Oxidation • 705 Table 17.3
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Ceramic materials are frequently us
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17.12 Bond Rupture • 709 17.12 BO
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Summary • 711 marily a result of
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Summary • 713 Corrosion Preventio
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Questions and Problems • 715 REFE
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Chapter 18 Electrical Properties (b
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18.3 Electrical Conductivity • 72
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18.5 Energy Band Structures in Soli
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valence band conduction band energy
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covalent) and relatively weak, whic
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18.8 Electrical Resistivity of Meta
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18.9 Electrical Characteristics of
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18.10 Intrinsic Semiconduction •
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18.10 Intrinsic Semiconduction •
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18.11 Extrinsic Semiconduction •
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18.11 Extrinsic Semiconduction •
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18.12 The Temperature Dependence of
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18.13 Factors That Affect Carrier M
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DESIGN EXAMPLE 18.1 Acceptor Impuri
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18.14 The Hall Effect • 747 Depen
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18.15 Semiconductor Devices • 749
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18.16 Conduction in Ionic Materials
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ands that overlap the valence and c
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18.19 Field Vectors and Polarizatio
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18.19 Field Vectors and Polarizatio
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ionic polarization Electric dipole
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18.23 Dielectric Materials • 765
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Summary • 767 + + + + + + + + +
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Summary • 769 • With these mate
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Summary • 771 18.11 r i Ac i 11
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Summary • 773 One common use for
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Questions and Problems • 775 Elec
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Questions and Problems • 777 The
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Design Problems • 779 DESIGN PROB
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Chapter 19 Thermal Properties (a) (
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19.2 Heat Capacity • 783 Figure 1
Page 813 and 814:
19.3 Thermal Expansion • 785 Tabl
Page 815 and 816:
19.3 Thermal Expansion • 787 For
Page 817 and 818:
19.4 THERMAL CONDUCTIVITY Thermal c
Page 819 and 820:
19.4 Thermal Conductivity • 791 F
Page 821 and 822:
19.5 Thermal Stresses • 793 speci
Page 823 and 824:
Summary • 795 • Coefficient-of-
Page 825 and 826:
Page 827 and 828:
Design Problems • 799 rod be fabr
Page 829 and 830:
WHY STUDY the Magnetic Properties o
Page 831 and 832:
20.2 Basic Concepts • 803 I B 0 =
Page 833 and 834:
20.3 Diamagnetism and Paramagnetism
Page 835 and 836:
20.4 Ferromagnetism • 807 Table 2
Page 837 and 838:
20.5 Antiferromagnetism and Ferrima
Page 839 and 840:
20.5 Antiferromagnetism and Ferrima
Page 841 and 842:
20.6 The Influence of Temperature o
Page 843 and 844:
20.7 Domains and Hysteresis • 815
Page 845 and 846:
20.7 Domains and Hysteresis • 817
Page 847 and 848:
20.9 Soft Magnetic Materials • 81
Page 849 and 850:
20.9 Soft Magnetic Materials • 82
Page 851 and 852:
20.10 Hard Magnetic Materials • 8
Page 853 and 854:
20.11 Magnetic Storage • 825 requ
Page 855 and 856:
20.11 Magnetic Storage • 827 Figu
Page 857 and 858:
20.12 Superconductivity • 829 Ele
Page 859 and 860:
20.12 Superconductivity • 831 Tab
Page 861 and 862:
Summary • 833 • For cubic ferri
Page 863 and 864:
Questions and Problems • 835 List
Page 865 and 866:
Questions and Problems • 837 with
Page 867 and 868:
Design Problems • 839 H C 1T 2 H
Page 869 and 870:
WHY STUDY the Optical Properties of
Page 871 and 872:
21.3 Light Interactions with Solids
Page 873 and 874:
21.4 Atomic and Electronic Interact
Page 875 and 876:
21.5 Refraction • 847 Velocity of
Page 877 and 878:
21.7 ABSORPTION Nonmetallic materia
Page 879 and 880:
21.7 Absorption • 851 Reaction de
Page 881 and 882:
21.9 Color • 853 21.9 COLOR color
Page 883 and 884:
21.11 Luminescence • 855 Figure 2
Page 885 and 886:
21.11 Luminescence • 857 n- and p
Page 887 and 888:
21.13 Lasers • 859 Ruby Flash lam
Page 889 and 890:
21.13 Lasers • 861 Partially refl
Page 891 and 892:
21.4 Optical Fibers in Communicatio
Page 893 and 894:
Summary • 865 Input impulse Outpu
Page 895 and 896:
Summary • 867 Transparent nonmeta
Page 897 and 898: Questions and Problems • 869 Impo
Page 899 and 900: Design Problem • 871 fiber glass
Page 901 and 902: WHY STUDY Economic, Environmental,
Page 903 and 904: Environmental and Societal Consider
Page 905 and 906: Environmental and Societal Consider
Page 907 and 908: 22.5 Recycling Issues in Materials
Page 913: Design Questions • 885 Environmen
Page 916 and 917: A2 • Appendix A / The Internation
Page 918 and 919: A4 • Appendix B / Properties of S
Page 924 and 925: A10 • Appendix B / Properties of
Page 946 and 947: A32 • Appendix C / Costs and Rela
Page 950 and 951: Appendix D Repeat Unit Structures f
Page 952 and 953: A38 • Appendix D / Repeat Unit St
Page 954 and 955: Appendix E Glass Transition and Mel
Page 956 and 957: G2 • Glossary atomic mass units (
Page 958 and 959: G4 • Glossary according to unit c
Page 960 and 961: G6 • Glossary Fick’s first law.
Page 962 and 963: G8 • Glossary J Jominy end-quench
Page 964 and 965: G10 • Glossary alternating layers
Page 966 and 967: G12 • Glossary stock; also, elong
Page 968 and 969: G14 • Glossary tempered martensit
Page 970 and 971: Answers to Selected Problems Chapte
Page 972 and 973: S2 • Answers to Selected Problems
Page 974: S4 • Answers to Selected Problems
Page 977 and 978: plane strain fracture toughness, 24
Page 979 and 980: Clay, characteristics, 518-519 Clay
Page 981 and 982: Die casting, 419 Dielectric breakdo
Page 983 and 984: Fatigue life, 258, G4 factors that
Page 985 and 986: Heat treatable, definition of, 406
Page 987 and 988: modulus of elasticity, 486 thermal
Page 989 and 990: Nanotubes, carbon, 13, 471 Natural
Page 991 and 992: fatigue behavior (PET), 580 magneti
Page 993 and 994: single crystal, 451 structure of, 4
Page 995 and 996: Stabilized zirconia, 478, 655 Stabi
Page 997 and 998: Transparency, 844, G13 Transverse b
Page 999 and 1000:
Power 1 W 0.239 cal/s 1 cal/s 4.1
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Callister - An introduction - 8th edition

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