Callister - An introduction - 8th edition

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390 • Chapter 10 / Phase Transformations Spreadsheet Problem 10.1SS For some phase transformation, given at least two values of fraction transformation and their corresponding times, generate a spreadsheet that will allow the user to determine the following: (a) the values of n and k in the Avrami equation, (b) the time required for the transformation to proceed to some degree of fraction transformation, and (c) the fraction transformation after some specified time has elapsed. DESIGN PROBLEMS Continuous Cooling Transformation Diagrams Mechanical Behavior of Iron–Carbon Alloys 10.D1 Is it possible to produce an iron–carbon alloy of eutectoid composition that has a minimum hardness of 90 HRB and a minimum ductility of 35%RA? If so, describe the continuous cooling heat treatment to which the alloy would be subjected to achieve these properties. If it is not possible, explain why. 10.D2 Is it possible to produce an iron–carbon alloy that has a minimum tensile strength of 690 MPa (100,000 psi) and a minimum ductility of 40%RA? If so, what will be its composition and microstructure (coarse and fine pearlites and spheroidite are alternatives)? If this is not possible, explain why. 10.D3 It is desired to produce an iron–carbon alloy that has a minimum hardness of 175 HB and a minimum ductility of 52%RA. Is such an alloy possible? If so, what will be its composition and microstructure (coarse and fine pearlites and spheroidite are alternatives)? If this is not possible, explain why. Tempered Martensite 10.D4 (a) For a 1080 steel that has been water quenched, estimate the tempering time at 425C (800F) to achieve a hardness of 50 HRC. (b) What will be the tempering time at 315C (600F) necessary to attain the same hardness? 10.D5 <strong>An</strong> alloy steel (4340) is to be used in an application requiring a minimum tensile strength of 1380 MPa (200,000 psi) and a minimum ductility of 43%RA. Oil quenching followed by tempering is to be used. Briefly describe the tempering heat treatment. 10.D6 Is it possible to produce an oil-quenched and tempered 4340 steel that has a minimum yield strength of 1400 MPa (203,000 psi) and a ductility of at least 42%RA? If this is possible, describe the tempering heat treatment. If it is not possible, explain why.
Chapter 11 Applications and Processing of Metal Alloys The photograph above shows the aluminum beverage can in various stages of production. The can is formed from a single sheet of an aluminum alloy. Production operations include drawing, dome forming, trimming, cleaning, decorating, and neck and flange forming. (PEPSI is a registered trademark of PepsiCo, Inc. Used by permission. Photograph on bottom courtesy of Daniel R. Patmore/© AP/Wide World Photos.) • 391
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Characteristics of Selected Element
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With WileyPLUS: This online teachin
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E IGHTH E DITION Materials Science
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Dedicated to our wives, Nancy and E
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viii • Preface FEATURES THAT ARE
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x • Preface 2. Answers to Concept
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Appreciation is expressed to those
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xiv • Contents 3. The Structure o
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xvi • Contents 9.12 Development o
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xviii • Contents 15.14 Factors Th
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xx • Contents 21.14 Optical Fiber
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xxii • List of Symbols HK Knoop
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Chapter 1 Introduction A familiar i
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1.2 Materials Science and Engineeri
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1.4 Classification of Materials •
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1.5 Advanced Materials • 11 aeros
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1.6 Modern Materials’ Needs • 1
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STEELS Processing Diffusion ➣ Rec
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Question • 17 REFERENCES Ashby, M
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WHY STUDY Atomic Structure and Inte
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2.3 Electrons in Atoms • 21 Orbit
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2.3 Electrons in Atoms • 23 Table
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2.3 Electrons in Atoms • 25 Table
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2.4 The Periodic Table • 27 Metal
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2.5 Bonding Forces and Energies •
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2.6 Primary Interatomic Bonds • 3
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2.6 Primary Interatomic Bonds • 3
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2.7 Secondary Bonding or van der Wa
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2.7 Secondary Bonding or van der Wa
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Summary • 39 Primary Interatomic
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Questions and Problems • 41 QUEST
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Questions and Problems • 43 Sprea
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WHY STUDY The Structure of Crystall
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lattice 3.4 Metallic Crystal Struct
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3.4 Metallic Crystal Structures •
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3.5 Density Computations • 51 EXA
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3.7 Crystal Systems • 53 Another
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3.8 Point Coordinates • 55 Concep
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3.9 Crystallographic Directions •
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3.10 Crystallographic Planes • 63
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3.12 Close-Packed Crystal Structure
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3.12 Close-Packed Crystal Structure
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3.15 Anisotropy • 73 (a) (b) grai
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3.16 X-Ray Diffraction: Determinati
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0° 3.16 X-Ray Diffraction: Determi
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3.17 Noncrystalline Solids • 79 (
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Summary • 81 Point Coordinates Cr
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Processing/Structure/Properties/Per
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Questions and Problems • 85 118.7
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Questions and Problems • 89 Inten
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WHY STUDY Imperfections in Solids?
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self-interstitial increases exponen
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2. Crystal structure. For appreciab
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4.4 Specification of Composition
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4.5 Dislocations—Linear Defects
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4.5 Dislocations—Linear Defects
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4.6 Interfacial Defects • 103 Ang
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4.6 Interfacial Defects • 105 MAT
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the order of 10 13 vibrations per s
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4.10 Microscopic Techniques • 109
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4.10 Microscopic Techniques • 111
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4.11 GRAIN SIZE DETERMINATION grain
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Summary • 115 Specification of Co
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Summary • 117 List of Symbols Sym
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Questions and Problems • 119 (a)
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Design Problems • 121 (a) at a ma
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WHY Study Diffusion? Materials of a
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5.2 Diffusion Mechanisms • 125 se
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5.3 Steady-State Diffusion • 127
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5.4 Nonsteady-State Diffusion • 1
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5.4 Nonsteady-State Diffusion • 1
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5.5 Factors That Influence Diffusio
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5.5 Factors That Influence Diffusio
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5.6 Diffusion in Semiconducting Mat
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is only an approximation), then the
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5.6 Diffusion in Semiconducting Mat
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Summary • 143 Diffusion in Semico
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Questions and Problems • 145 QUES
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Diffusion coefficient (m 2 /s) 10 -
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Design Problems • 149 the process
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WHY STUDY The Mechanical Properties
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6.2 Concepts of Stress and Strain
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6.2 Concepts of Stress and Strain
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6.3 Stress-Strain Behavior • 157
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6.4 Anelasticity • 159 Figure 6.8
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6.5 Elastic Properties Of Materials
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6.6 Tensile Properties • 163 Figu
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6.6 Tensile Properties • 165 in F
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6.6 Tensile Properties • 167 Brit
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6.6 Tensile Properties • 169 y F
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6.7 True Stress and Strain • 171
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6.9 Compressive, Shear, and Torsion
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Table 6.5 Hardness-Testing Techniqu
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Brinell Hardness Tests 15 6.10 Hard
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6.10 Hardness • 179 are contained
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6.11 Variability Of Material Proper
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6.12 Design/Safety Factors • 183
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Summary • 185 • For an isotropi
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Summary • 187 6.15 s T F True st
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Questions and Problems • 189 a lo
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Questions and Problems • 191 tens
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Questions and Problems • 193 modu
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Design Problems • 195 (a) Determi
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Chapter 7 Dislocations and Strength
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Dislocations and Plastic Deformatio
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7.3 Characteristics of Dislocations
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7.4 Slip Systems • 203 D B A (a)
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7.5 Slip in Single Crystals • 205
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7.5 Slip in Single Crystals • 207
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7.6 Plastic Deformation of Polycrys
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7.7 Deformation by Twinning • 211
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7.9 Solid-Solution Strengthening
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7.10 Strain Hardening • 215 (a) (
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7.10 Strain Hardening • 217 600 2
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7.11 RECOVERY recovery 7.12 RECRYST
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7.12 Recrystallization • 221 (e)
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7.12 Recrystallization • 223 DESI
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Summary • 225 Figure 7.25 The log
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Summary • 227 Strain Hardening
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Questions and Problems • 229 Iron
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Questions and Problems • 231 and
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Design Problems • 233 Spreadsheet
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WHY STUDY Failure? The design of a
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8.3 Ductile Fracture • 237 Figure
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8.4 Brittle Fracture • 239 8.4 BR
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8.4 Brittle Fracture • 241 SEM Mi
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8.5 Principles of Fracture Mechanic
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8.6 Fracture Toughness Testing •
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8.6 Fracture Toughness Testing •
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8.7 Cyclic Stresses • 255 Most ce
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8.8 The S-N Curve • 257 fatigue l
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8.9 Crack Initiation and Propagatio
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8.9 Crack Initiation and Propagatio
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8.10 Factors that Affect Fatigue Li
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8.12 Generalized Creep Behavior •
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8.13 Stress and Temperature Effects
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8.15 Alloys For High-Temperature Us
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Summary • 271 Ductile Fracture
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Summary • 273 • The presence of
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fatigue limit fatigue strength frac
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Questions and Problems • 277 Cycl
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Design Problems • 279 8.31 A cyli
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Chapter 9 Phase Diagrams The graph
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Definitions and Basic Concepts 9.2
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9.5 PHASE EQUILIBRIA equilibrium fr
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phases is along curve aO—likewise
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9.8 Interpretation of Phase Diagram
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9.9 Development of Microstructure i
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9.10 Mechanical Properties of Isomo
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9.11 Binary Eutectic Systems • 29
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9.12 Development of Microstructure
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9.13 Equilibrium Diagrams Having In
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9.14 Eutectoid and Peritectic React
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9.15 Congruent Phase Transformation
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9.17 The Gibbs Phase Rule • 317 F
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The Iron-Carbon System 9.18 The Iro
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9.18 The Iron-Iron Carbide (Fe-Fe 3
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Summary • 331 SUMMARY Introductio
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Summary • 333 Development of Micr
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Questions and Problems • 335 Impo
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Questions and Problems • 337 (b)
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Page 369 and 370: Questions and Problems • 341 9.54
Page 371 and 372: WHY STUDY Phase Transformations? Th
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Page 407 and 408: 10.9 Review of Phase Transformation
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Page 413 and 414: Questions and Problems • 385 Stee
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Page 417: Questions and Problems • 389 (c)
Page 421 and 422: 11.2 Ferrous Alloys • 393 Types o
Page 423 and 424: 11.2 Ferrous Alloys • 395 Table 1
Page 425 and 426: 11.2 Ferrous Alloys • 397 Table 1
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Page 431 and 432: Table 11.5 Designations, Minimum Me
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Page 435 and 436: 11.3 Nonferrous Alloys • 407 Tabl
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Page 445 and 446: 11.4 Forming Operations • 417 Met
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Page 449 and 450: 11.6 Miscellaneous Techniques • 4
Page 451 and 452: 11.7 Annealing Processes • 423 ox
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Page 455 and 456: 11.8 Heat Treatment of Steels • 4
Page 465 and 466: 11.9 Precipitation Hardening • 43
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11.9 Precipitation Hardening • 44
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Summary • 443 Forming Operations
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Summary • 445 PROCESSING Recrysta
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Questions and Problems • 447 REFE
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Design Problems • 449 and temperi
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Chapter 12 Structures and Propertie
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12.2 Crystal Structures • 453 Con
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12.2 Crystal Structures • 455 Tab
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12.2 Crystal Structures • 457 Fur
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12.2 Crystal Structures • 459 VMS
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12.2 Crystal Structures • 461 Tet
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12.2 Crystal Structures • 463 EXA
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12.3 Silicate Ceramics • 465 Si 4
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12.3 Silicate Ceramics • 467 Figu
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12.4 Carbon • 469 Figure 12.16 Sc
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Another molecular form of carbon ha
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12.5 Imperfections in Ceramics •
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12.5 Imperfections in Ceramics •
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12.7 Ceramic Phase Diagrams • 477
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12.7 Ceramic Phase Diagrams • 479
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12.8 Brittle Fracture of Ceramics
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12.8 Brittle Fracture of Ceramics
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flexural strength Flexural strength
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12.10 Mechanisms of Plastic Deforma
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viscosities at ambient temperatures
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Summary • 491 Table 12.6 Vickers
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Summary • 493 • Diagrams for Al
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Questions and Problems • 495 visc
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Questions and Problems • 497 does
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Questions and Problems • 499 Stre
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Chapter 13 Applications and Process
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13.3 Glass-Ceramics • 503 Ceramic
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13.5 Refractories • 505 Glass-cer
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13.6 Abrasives • 507 (2910F). Thu
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13.8 Advanced Ceramics • 509 Seve
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13.8 Advanced Ceramics • 511 opti
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13.9 Fabrication and Processing of
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13.11 Powder Pressing • 523 a sca
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13.12 Tape Casting • 525 Figure 1
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Summary • 527 • Requirements fo
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Summary • 529 This chapter also d
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13.12 Compare the softening points
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WHY STUDY Polymer Structures? A rel
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14.3 Polymer Molecules • 535 Tabl
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14.4 The Chemistry of Polymer Molec
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14.4 The Chemistry of Polymer Molec
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Figure 14.3 Hypothetical polymer mo
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14.5 Molecular Weight • 543 Table
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14.7 Molecular Structure • 545 Fi
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14.8 Molecular Configurations • 5
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14.8 Molecular Configurations • 5
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14.10 Copolymers • 551 adjacent c
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14.11 Polymer Crystallinity • 553
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For copolymers, as a general rule,
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14.12 Polymer Crystals • 557 ~ 10
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14.14 Diffusion in Polymeric Materi
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Summary • 561 PET is permeable to
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Equation Summary Summary • 563 Po
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Important Terms and Concepts Questi
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Questions and Problems • 567 age
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Chapter 15 Characteristics, Applica
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15.2 Stress-Strain Behavior • 571
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15.3 Macroscopic Deformation • 57
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15.4 Viscoelastic Deformation • 5
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15.4 Viscoelastic Deformation • 5
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15.5 Fracture of Polymers • 579 F
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15.7 Deformation of Semicrystalline
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t 0 t t 0 t 0 Stage 1 Stage 2 (a) (
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15.8 Factors That Influence the Mec
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15.8 Factors That Influence the Mec
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15.9 Deformation of Elastomers •
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15.10 Crystallization • 591 Norma
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15.13 Melting and Glass Transition
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15.14 Factors That Influence Meltin
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15.15 Plastics • 597 Table 15.3 (
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15.16 Elastomers • 599 ing phenol
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15.18 Miscellaneous Applications
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15.19 Advanced Polymeric Materials
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15.19 Advanced Polymeric Materials
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The tensile modulus of this TPE mat
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15.20 Polymerization • 609 Additi
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15.22 Forming Techniques for Plasti
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15.22 Forming Techniques for Plasti
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15.24 Fabrication of Fibers and Fil
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Factors That Influence the Mechanic
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Summary • 619 Equation Summary Eq
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Questions and Problems • 621 McCr
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Questions and Problems • 623 Tens
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Design Questions • 625 Elastomers
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3.1 Hardness • 627 WHY STUDY Comp
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16.1 Introduction • 629 Dispersed
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16.2 Large-Particle Composites •
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16.2 Large-Particle Composites •
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Critical fiber length—dependence
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16.5 Influence of Fiber Orientation
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ut, because s/E, 16.5 Influence o
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16.6 The Fiber Phase • 645 Applic
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eactions with the environment. Such
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16.8 Polymer-Matrix Composites •
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16.8 Polymer-Matrix Composites •
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16.9 Metal-Matrix Composites • 65
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The high-temperature creep and rupt
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16.12 HYBRID COMPOSITES hybrid comp
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16.13 Processing of Fiber-Reinforce
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16.15 Sandwich Panels • 661 Figur
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Summary • 663 they remain separat
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Summary • 665 When l l c , Equat
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References • 667 List of Symbols
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Design Problems • 671 to be align
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Chapter 17 Corrosion and Degradatio
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Corrosion of Metals 17.2 Electroche
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17.2 Electrochemical Considerations
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17.4 Prediction of Corrosion Rates
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17.5 Passivity • 691 to further c
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17.7 Forms of Corrosion • 693 sur
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17.7 Forms of Corrosion • 695 Fig
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sodium chloride. Dilute sulfuric ac
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17.10 Oxidation • 703 Zinc coatin
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17.10 Oxidation • 705 Table 17.3
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Ceramic materials are frequently us
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17.12 Bond Rupture • 709 17.12 BO
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Summary • 711 marily a result of
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Summary • 713 Corrosion Preventio
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Questions and Problems • 715 REFE
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Chapter 18 Electrical Properties (b
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18.3 Electrical Conductivity • 72
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18.5 Energy Band Structures in Soli
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valence band conduction band energy
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covalent) and relatively weak, whic
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18.8 Electrical Resistivity of Meta
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18.9 Electrical Characteristics of
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18.10 Intrinsic Semiconduction •
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18.10 Intrinsic Semiconduction •
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18.11 Extrinsic Semiconduction •
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18.11 Extrinsic Semiconduction •
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18.12 The Temperature Dependence of
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18.13 Factors That Affect Carrier M
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DESIGN EXAMPLE 18.1 Acceptor Impuri
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18.14 The Hall Effect • 747 Depen
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18.15 Semiconductor Devices • 749
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18.16 Conduction in Ionic Materials
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ands that overlap the valence and c
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18.19 Field Vectors and Polarizatio
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18.19 Field Vectors and Polarizatio
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ionic polarization Electric dipole
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18.23 Dielectric Materials • 765
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Summary • 767 + + + + + + + + +
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Summary • 769 • With these mate
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Summary • 771 18.11 r i Ac i 11
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Summary • 773 One common use for
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Questions and Problems • 775 Elec
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Questions and Problems • 777 The
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Design Problems • 779 DESIGN PROB
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Chapter 19 Thermal Properties (a) (
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19.2 Heat Capacity • 783 Figure 1
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19.3 Thermal Expansion • 785 Tabl
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19.3 Thermal Expansion • 787 For
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19.4 THERMAL CONDUCTIVITY Thermal c
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19.4 Thermal Conductivity • 791 F
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19.5 Thermal Stresses • 793 speci
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Summary • 795 • Coefficient-of-
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Design Problems • 799 rod be fabr
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WHY STUDY the Magnetic Properties o
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20.2 Basic Concepts • 803 I B 0 =
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20.3 Diamagnetism and Paramagnetism
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20.4 Ferromagnetism • 807 Table 2
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20.5 Antiferromagnetism and Ferrima
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20.5 Antiferromagnetism and Ferrima
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20.6 The Influence of Temperature o
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20.7 Domains and Hysteresis • 815
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20.7 Domains and Hysteresis • 817
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20.9 Soft Magnetic Materials • 81
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20.9 Soft Magnetic Materials • 82
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20.10 Hard Magnetic Materials • 8
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20.11 Magnetic Storage • 825 requ
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20.11 Magnetic Storage • 827 Figu
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20.12 Superconductivity • 829 Ele
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20.12 Superconductivity • 831 Tab
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Summary • 833 • For cubic ferri
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Questions and Problems • 835 List
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Questions and Problems • 837 with
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Design Problems • 839 H C 1T 2 H
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WHY STUDY the Optical Properties of
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21.3 Light Interactions with Solids
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21.4 Atomic and Electronic Interact
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21.5 Refraction • 847 Velocity of
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21.7 ABSORPTION Nonmetallic materia
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21.7 Absorption • 851 Reaction de
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21.9 Color • 853 21.9 COLOR color
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21.11 Luminescence • 855 Figure 2
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21.11 Luminescence • 857 n- and p
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21.13 Lasers • 859 Ruby Flash lam
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21.13 Lasers • 861 Partially refl
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21.4 Optical Fibers in Communicatio
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Summary • 865 Input impulse Outpu
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Summary • 867 Transparent nonmeta
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Questions and Problems • 869 Impo
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Design Problem • 871 fiber glass
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WHY STUDY Economic, Environmental,
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Environmental and Societal Consider
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Environmental and Societal Consider
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22.5 Recycling Issues in Materials
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Design Questions • 885 Environmen
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A2 • Appendix A / The Internation
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A4 • Appendix B / Properties of S
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A10 • Appendix B / Properties of
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A32 • Appendix C / Costs and Rela
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A34 • Appendix C / Costs and Rela
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Appendix D Repeat Unit Structures f
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A38 • Appendix D / Repeat Unit St
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Appendix E Glass Transition and Mel
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G2 • Glossary atomic mass units (
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G4 • Glossary according to unit c
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G6 • Glossary Fick’s first law.
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G8 • Glossary J Jominy end-quench
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G10 • Glossary alternating layers
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G12 • Glossary stock; also, elong
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G14 • Glossary tempered martensit
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Answers to Selected Problems Chapte
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S2 • Answers to Selected Problems
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S4 • Answers to Selected Problems
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plane strain fracture toughness, 24
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Clay, characteristics, 518-519 Clay
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Die casting, 419 Dielectric breakdo
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Fatigue life, 258, G4 factors that
Page 985 and 986:
Heat treatable, definition of, 406
Page 987 and 988:
modulus of elasticity, 486 thermal
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Nanotubes, carbon, 13, 471 Natural
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fatigue behavior (PET), 580 magneti
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single crystal, 451 structure of, 4
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Stabilized zirconia, 478, 655 Stabi
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Transparency, 844, G13 Transverse b
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Power 1 W 0.239 cal/s 1 cal/s 4.1
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Callister - An introduction - 8th edition

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