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Medical Hydrology and Balneology: Environmental Aspects

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Mud maturation in Copahue, Argentina: the<br />

presence of sulphur<br />

Baschini M (1) , Pettinari G (1) , Valles J (1) , Monasterio AM (2) ,<br />

Giménez JC (3) , López Galindo A (3) , Setti M (4)<br />

(1) Facultad de Ingeniería. Universidad Nacional del Comahue. Neuquén. Argentina<br />

(2) Ente Provincial de Termas del Neuquén. Argentina<br />

(3) Instituto Andaluz de Ciencias de la Tierra. CSIC. Granada, Spain<br />

(4) Department Scienze della Terra e dell'Ambiente.<br />

Università degli Studi di Pavia. Pavia. Italy<br />

miriabaschini@yahoo.com<br />

Introduction <strong>and</strong> Objectives<br />

Copahue volcano is situated in the province of Neuquén, Argentina. Several geothermal<br />

features (hot springs, ponds <strong>and</strong> fumaroles) occur in the surroundings of<br />

Villa Copahue. The associated geothermal system causes the occurrence of singular<br />

thermal muds that are intensively used in the Copahue Thermal Center (CTC), an<br />

international-level thermal complex.<br />

The natural mud have a composition rich in sulfur, as well as clay minerals kaolinite<br />

<strong>and</strong> smectite type, which are in contact with a highly acidic liquid phase with<br />

high salt content <strong>and</strong> dissolved gases (Baschini, et al 2010). These peloids are<br />

extensively used for the treatment of several rheumatic, muscles, neurological <strong>and</strong><br />

dermatological pathologies (Monasterio <strong>and</strong> Grenóvero, 2008). The winter station<br />

covers the entire thermal center with several meters of snow each year <strong>and</strong> turns<br />

inaccessible the use of these materials.<br />

The objective of this study was carried out an experimental maturation of muds<br />

in the CTC, from regional clay minerals <strong>and</strong> acid water located near Copahue, in<br />

order to<br />

obtain appropriate material for therapeutic uses that can be transported out of<br />

Copahue during the winter, <strong>and</strong> used during the winter period.<br />

Materials <strong>and</strong> Methods<br />

An Experimental Station was built with a wooden container with about 4000 L<br />

of capacity, where kaolinite <strong>and</strong> smectite (APM <strong>and</strong> CATAE in proportions 75:25)<br />

from regional deposits were mixed with natural thermal acidic waters. The pH value<br />

of the system was about 3, the temperature was about 55º C, <strong>and</strong> water conductivity<br />

was between 2.67 to 4.70 mS/ cm, during the experience (1 year). At different times<br />

samples from the Experimental Station were taken <strong>and</strong> analyzed. In previous work<br />

cationic exchange capacity, specific surface, Atterberg limits, kinetic cooling <strong>and</strong><br />

color were analyzed (Baschini et al, 2011). In this presentation we focus on the<br />

Balnea<br />

2012, núm. 6, 402-403<br />

402<br />

ISBN: 978-84-669-1887-0<br />

978-84-669-3482-4

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