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Properties of hemp fibre polymer composites -An optimisation of ...

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E<br />

⎛ dσ<br />

c ⎞<br />

= ⎜ ⎟<br />

⎝ dε<br />

⎠<br />

c Equation 7b<br />

ε = 0−0.<br />

1%<br />

Pure epoxy sheets were tested to obtain a stress-strain curve for the matrix material,<br />

which was fitted to a second order polynomial, giving Em=2.93 GPa and k=32.5 GPa<br />

(Figure ):<br />

( )<br />

σ ε ε<br />

2<br />

m = Em× − k×ε<br />

Equation 8<br />

The <strong>fibre</strong> strength σfu was calculated with the rule <strong>of</strong> mixtures using the matrix stress σm<br />

at the strain <strong>of</strong> composite failure εu and the <strong>fibre</strong> stiffness Ef was calculated using Em<br />

(Hull & Clyne, 1996). With porosity in the <strong>composites</strong>, σcu and Ec are reduced to a larger<br />

extent than caused by the reduction <strong>of</strong> Vf and Vm; this is due to the potential stress<br />

concentrations originating at the porosities, and is taken into account by the term (1-Vp) n<br />

(T<strong>of</strong>tegaard & Lilholt, 2002). Based on detailed investigation <strong>of</strong> the <strong>composites</strong> in this<br />

study, it was chosen to use nσ=2.1 and nE=1 for correction for porosity (Thygesen, 2006).<br />

The <strong>fibre</strong> strength σfu and the <strong>fibre</strong> stiffness Ef are thus calculated from Equation 9.<br />

n<br />

n σ cup −V<br />

m × σ m ( ε u )<br />

σ<br />

σ<br />

σ cu = ( V f × σ fu + Vm<br />

× σ m ( ε u ) )( 1 −V<br />

p ) = σ cup ( 1−<br />

V p ) ⇔ σ fu =<br />

Equation 9a<br />

V f<br />

E<br />

c<br />

nE<br />

( V × E + V × E )( −V<br />

) = E ( −V<br />

)<br />

f<br />

f<br />

m<br />

−V<br />

× E<br />

nE<br />

cp m m<br />

m 1 p cp p ⇔ E f =<br />

Equation 9b<br />

V f<br />

= 1<br />

Figure 1. Stress versus strain for epoxy sheets and <strong>composites</strong> with 33% (v/v) P. radiata<br />

defibrated <strong>hemp</strong> <strong>fibre</strong>s, to show the fracture strain (εu) and stress (σ) <strong>of</strong> matrix (σm),<br />

composite (σcu) and <strong>fibre</strong>s (σfu).<br />

Risø-PhD-11 127<br />

E

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