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Properties of hemp fibre polymer composites -An optimisation of ...

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Figure 9. Hemp stem shown at increasing magnification using different transverse<br />

sections in SEM: A: Xylem + cambium + cortex + epidermis; B: Primary and secondary<br />

single <strong>fibre</strong>s; C: Major layers in primary single <strong>fibre</strong>; D: Thin lamellae within the S2<br />

layer (Paper II).<br />

The micr<strong>of</strong>ibril angle through the <strong>fibre</strong> wall was investigated by polarised light<br />

microscopy and scanning electron microscopy. It was found that the micr<strong>of</strong>ibrils in<br />

<strong>fibre</strong>s <strong>of</strong> Felina <strong>hemp</strong> had a main orientation <strong>of</strong> 0-5° in the S2-layer. The presence <strong>of</strong> Zhelical<br />

angles in the range 25-30° was observed (Figure 11A), but with variation<br />

between the <strong>fibre</strong>s (Paper II). Difference in micr<strong>of</strong>ibril angle is also present between<br />

early wood and late wood (Table 2). Superficial attack <strong>of</strong> <strong>hemp</strong> <strong>fibre</strong>s (Figure 11C) and<br />

polarization light microscopy showed the S1 layer with micr<strong>of</strong>ibril angles in the range <strong>of</strong><br />

70-90° (Paper II). The average MFA in <strong>hemp</strong> <strong>fibre</strong>s <strong>of</strong> 4° that is measured by X-ray<br />

diffraction (Fink et al., 1999) is thereby confirmed with more detailed information. The<br />

low overall MFA in <strong>hemp</strong> <strong>fibre</strong>s explains the high stiffness in the range 50-80 MPa<br />

compared with sisal (6-22 GPa) with similar cellulose content and higher MFA i.e. 10-<br />

25° (Table 2,Table 3).<br />

Figure 10. Single <strong>fibre</strong>s partially decayed by fungi (transverse sections). A: P. mutabilis<br />

decay <strong>of</strong> the thick layers in S2. B: P. radiata (wild) decay <strong>of</strong> the cell wall from the lumen<br />

side. C: P. radiata Cel 26 decay <strong>of</strong> the thin layers between the thick concentric S2 layers<br />

(Paper II).<br />

22 Risø-PhD-11

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