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NUI Galway – UL Alliance First Annual ENGINEERING AND - ARAN ...

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Assessment of the Suitability of Co-Mixed and Composted Separated Solids of<br />

Pig Manure for Use as a Solid Fuel<br />

Shane Troy ab , Tereza Nolan a , James J. Leahy c , Witold Kwapinski c , Peadar G. Lawlor a and<br />

Mark G. Healy b .<br />

a Teagasc, Pig Development Department, Moorepark, Fermoy, Co. Cork, Ireland<br />

b Civil Engineering, National University of Ireland, <strong>Galway</strong>, Co. <strong>Galway</strong>, Ireland<br />

c Chemical and Environmental Science, University of Limerick, Limerick, Ireland<br />

E-mail: shane.troy@teagasc.ie<br />

Abstract<br />

The aim of this project is to investigate the use of the<br />

solid portion of separated pig manure mixed with<br />

various bulking agents as a both a compost and a solid<br />

fuel. Composting experiments showed sawdust to be the<br />

best of the bulking agents studied. An initial carbon<br />

(C): nitrogen (N) ratio of 16:1 was used to produce<br />

stable compost using separated pig manure and<br />

sawdust. The three products of pyrolysis; biochar, biooil<br />

and gas are being investigated. The bio-oil and<br />

gases will be characterised as a fuel to provide the<br />

energy needs of the pyrolysis process. The biochar is<br />

being characterised as a fertiliser and soil addendum.<br />

The effects of composting of the swine manure solids<br />

before pyrolysis and the addition of C-rich bulking<br />

agents is also being investigated.<br />

1. Introduction<br />

Management of pig manure is becoming an<br />

expensive problem for pig farmers as new legislation to<br />

prevent environmental pollution reduces the spreadlands<br />

available. Practical and economically viable on-farm<br />

solutions for swine wastewater treatment are needed to<br />

tackle this growing problem. The aim of this research is<br />

to investigate (a) composting, (b) pyrolysis and (c) both<br />

composting and pyrolysis as methods of treating pig<br />

manure in an economically viable manner, while also<br />

providing environmental benefits. Composting stabilises<br />

organic matter, destroys pathogens, and decreases water<br />

content and odours. Pyrolysis of swine manure may<br />

reduce waste disposal costs and provide cost effective<br />

energy to be used on the farm. Pyrolysis is a process<br />

whereby a biomass feedstock is thermally degraded at<br />

high temperatures in an oxygen-free atmosphere. The<br />

products of this process are biochar, bio-oil and gases.<br />

The bio-oil and gases can be used as fuels or to provide<br />

the energy needs of the pyrolysis process. Biochar may<br />

also be used as a fuel, or as a fertiliser and soil<br />

addendum, for C sequestration and for gas scrubbing.<br />

2. Composting Experiments<br />

Four composting trials were undertaken using<br />

separated pig manure solids and a variety of C-rich<br />

bulking agents. Trials 1 and 2 investigated the effect of<br />

the addition of different bulking agents on the quality of<br />

compost produced. Greenwaste, sawdust, woodchip and<br />

straw were the bulking agents studied. Results showed<br />

110<br />

that sawdust was the bulking agent which produced the<br />

best quality compost. Trials 3 and 4 investigated the<br />

effect of different quantities of sawdust addition. The<br />

aim was to show if a C:N ratio lower than the<br />

recommended 25-30 could be used to produce stable<br />

compost. It was found that an initial C:N ratio of 16<br />

resulted in stable compost, thus reducing the cost of the<br />

process for farmers.<br />

2. Characterisation of biochar<br />

Proximate and ultimate analyses have been<br />

undertaken on feedstock and biochar from 24 different<br />

biomass mixtures. Six samples (anaerobically digested<br />

pig manure with added sawdust, both before and after<br />

composting) have been further analysed to investigate<br />

surface area, pyrolysis energy requirements and pore<br />

structure. Analysis has shown that pre-composting of<br />

biomass before pyrolysis results in decreased heating<br />

values, fixed carbon content and surface area. Product<br />

yield is also changed for pre-composted samples;<br />

biochar and bio-oil yield increases, while gas yield<br />

decreases. The addition of bulking agents to pig manure<br />

before pyrolysis results in increased heating values,<br />

fixed carbon contents and surface areas.<br />

3. Ongoing experiments<br />

Further studies investigating the fuel characteristics<br />

of the bio-oil and gases produced by the six feedstocks<br />

described above are ongoing. An energy balance will be<br />

conducted using experimental data from the separation,<br />

composting and pyrolysis studies. The aim is to identify<br />

the viability of an on-farm pyrolysis plant producing<br />

biochar from pig manure with the energy requirements<br />

provided by the bio-oil and gases. The impact of precomposting<br />

will also be assessed in this energy balance.<br />

The effect of sawdust addition on the energy balance<br />

will show whether it is worthwhile for pig farmers to<br />

import sawdust onto their farm to use as a co-feedstock.<br />

4. Future Experiments<br />

Landspreading analyses are planned using pig<br />

manure, pig manure compost and artificial fertiliser with<br />

and without the addition of pig manure biochar under<br />

medium rainfall conditions. These analyses will quantify<br />

the nutrient leaching from the three fertilisers and also<br />

the nutrient retention capacity gained when biochar is<br />

added to soil.

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