664 O. LEXA ET AL.onset <strong>of</strong> dynamic recrystallization in weaklydeformed metagabbros show that the lower-temperaturemylonites exhibit a smaller initial recrystallizationgrain size than the new recrystallized grains<strong>of</strong> the high-temperature mylonites (Baratoux et al.,2005). In addition, inspection <strong>of</strong> the N 0 –Gt plotshows that highly deformed samples (GLT2,GHT2a,b, T2) exhibit higher N 0 <strong>and</strong> lower Gt valuesrelative to weakly deformed samples (GLT1, GHT1).Based on these two observations, we suggest that thedifferences in CSD parameters are not the result <strong>of</strong>textural coarsening but are merely controlled bytemperature- <strong>and</strong> strain rate-dependent mechanisms<strong>of</strong> dynamic recrystallization. Azpiroz & Ferna´ndez(2003) reported an increase in N 0 but a constant Gt(slope) with decreasing temperature <strong>and</strong> increasing Gtvalues for constant N 0 with increasing finite strain inthe Iberian Massif metabasites. However, it is proposedthat in our study the N 0 <strong>and</strong> Gt changesimultaneously due to temperature <strong>and</strong> strainintensity variations <strong>and</strong> that the temperature changeplays a key role in the resulting CSD shape.Samples from the b<strong>and</strong>ed amphibolite complex aremarked by lower N 0 <strong>and</strong> higher Gt values in comparisonwith the mylonitic metagabbros. The CSD isdeveloped in both amphibolites <strong>and</strong> tonalitic gneiss,which indicates that it is independent on a relativeproportion <strong>of</strong> amphibole <strong>and</strong> plagioclase in both rocktypes. These data in the N 0 –Gt diagram show a continuoustrend together with the above-described samplesfrom the mylonitic metagabbros. In addition,results <strong>of</strong> Hb–Pl thermometry reveal an increase inestimated temperatures from the eastern mylonitemetagabbros, through the western mylonite metagabbrosto the b<strong>and</strong>ed amphibolite complex. Such anevolutionary trend is likely to be interpreted as theresult <strong>of</strong> a textural coarsening comparable with theresults <strong>of</strong> Cashman & Ferry (1988) reinterpreted byHiggins (1998).Interpretation <strong>of</strong> spatial distribution minerals <strong>and</strong> grainboundariesSeng (1936) <strong>and</strong> later DeVore (1959) proposed that thespatial distribution <strong>of</strong> crystals in high-grade gneisses isdominantly determined by interfacial energy. Thisconcept was adopted by Flinn (1969) who explained aprevailing number <strong>of</strong> unlike boundaries in granulitesthrough the insertion <strong>of</strong> grains <strong>of</strong> one phase betweengrains <strong>of</strong> other phases. Flinn (1969) suggested that thisfeature is a consequence <strong>of</strong> a smaller interfacial energy<strong>of</strong> unlike boundaries in comparison with like–likeboundaries. However, Ramberg (1952) suggested thatdifferences in interfacial energies are too small to drivediffusional mass transfer in high-grade rocks.Modern material science experimental studies showthat during the wetting process the low-energy (lowmisorientationangle) boundaries in one phase arepreserved while another phase preferentially precipitateson high-energy (high-misorientation angle)boundaries (e.g. Kim & Rohrer, 2004). In other words,the highest energy boundaries are progressively eliminatedfrom an inherited population by ÔinfiltrationÕ <strong>of</strong>the other phase. This is in agreement with the knownfact that in granular-polygonal aggregates the minorphase precipitates on triple points to achieve lowertotal interfacial energy (Spry, 1969; Vernon, 1974).Such a tendency was documented by Dallain et al.(1999) who showed that the predominance <strong>of</strong> unlikecontacts in polycrystalline aggregates originatedthrough wetting <strong>of</strong> grain boundaries by fluids or melts,<strong>and</strong> subsequent precipitation <strong>of</strong> other phases on like–like contacts.In contrast, the solid-state differentiation resultingfrom dynamic recrystallization leads to the development<strong>of</strong> monomineralic aggregates or b<strong>and</strong>s due tocoalescence <strong>of</strong> like phases at high strains (Schulmannet al., 1996; Kruse & Stu¨ nitz, 1999). Therefore, thelike–like contacts prevail <strong>and</strong> the so-called aggregatetypedistribution develops, which is a typical feature <strong>of</strong>high-temperature deformation <strong>of</strong> polyphase rocks suchas gabbros <strong>and</strong> granites (Dallain et al., 1999; Baratouxet al., 2005).The high-temperature mylonitic metagabbros fromthe study area exhibit high-grain SPO <strong>and</strong> GPBOassociated with the development <strong>of</strong> a strong aggregatedistribution. The lower-temperature mylonitic metagabbrosare characterized by extreme values <strong>of</strong> SPO inconjunction with an almost r<strong>and</strong>om grain distribution.We suggest that in the case <strong>of</strong> high-temperaturemylonitic metagabbros the process controlling thedevelopment <strong>of</strong> a strong aggregate distribution is solidstatedifferentiation due to a different efficiency <strong>of</strong>dislocation creep in hornblende <strong>and</strong> plagioclase. Thisprocess is likely to be accompanied by some diffusionalmass transfer responsible for preferential heterogeneousnucleation (Kruse & Stu¨ nitz, 1999) <strong>of</strong> interstitialplagioclase in coarse-grained amphibole aggregates(Baratoux et al., 2005). On the contrary, in the lowertemperaturemetagabbro mylonites, the r<strong>and</strong>om mineraldistribution <strong>and</strong> the lack <strong>of</strong> crystallographicpreferred orientation <strong>of</strong> plagioclase were interpreted tobe the result <strong>of</strong> mechanical mixing due to grainboundarysliding during granular flow.Samples from the b<strong>and</strong>ed amphibolite <strong>and</strong> tonaliticgneiss show a low SPO, a very weak elongation <strong>of</strong> bothplagioclase <strong>and</strong> amphibole, a weak GBPO connectedwith a weak dominance <strong>of</strong> unlike contacts indicating aregular to anticlustered grain distribution. Such a graindistribution <strong>and</strong> the large grain size <strong>of</strong> both phasesexclude mechanical mixing as a process explaining thistexture. We are <strong>of</strong> the opinion that the spatial distribution<strong>of</strong> plagioclase <strong>and</strong> amphibole (e.g. sampleLAC1) can result from heterogeneous nucleation <strong>of</strong>plagioclase in an amphibole aggregates. However, anoriginal grain-size distribution characteristic <strong>of</strong> nucleation<strong>and</strong> growth processes is completely obliteratedby elimination <strong>of</strong> the small grains. Very low-grainÓ 2005 Blackwell Publishing Ltd246
CONTRASTING TEXTURAL RECORD OF TWO METAMORPHIC EVENTS 665elongation, SPO <strong>and</strong> GBPO, similar CSD <strong>of</strong> bothphases <strong>and</strong> regular grain distribution indicate that theaggregates tend to achieve a state with a minimuminterfacial energy. As mentioned above, the processes<strong>of</strong> heterogeneous nucleation <strong>of</strong> minor phase lead tooccupation <strong>of</strong> the high-energy grain boundaries atearly stages <strong>of</strong> the texture development. However, inthe rocks studied it is impossible to distinguish a minorphase from the host aggregate, which indicates that theprocess <strong>of</strong> interfacial energy reduction is more advanceddue to significant diffusional mass transfer. Asthe driving differences in bulk interfacial energies aretoo small (Ramberg, 1952), the only plausible explanationis the long time-scale <strong>of</strong> the process.Different time-scales <strong>of</strong> Cambro-Ordovician <strong>and</strong> Variscanmetamorphic eventsSˇtípska´ et al. (2001) proposed a tectonic model inwhich the Cambro-Ordovician metamorphism is relatedto large-scale rifting while the Variscan metamorphicevent was connected with a thermal effect inducedby the syntectonic granodiorite sill intrusion, <strong>and</strong> wasspatially restricted to the host rocks <strong>of</strong> the intrusion.The thermal time constant s is given by the relationship:s / l 2 j ;ð3Þwhere l is the characteristic length <strong>of</strong> thermal event <strong>and</strong>j is the thermal diffusivity (Carlslaw & Jaeger, 1959).This equation indicates that duration <strong>of</strong> thermalequilibration increases with the square <strong>of</strong> the size <strong>of</strong> thethermal anomaly. Based on the proposed tectonicmodel, we assume that a relaxation <strong>of</strong> the perturbedtemperature field generated by the continental riftdiffers in time-scale by at least one order <strong>of</strong> magnitudefrom that generated by an intrusion <strong>of</strong> several km insize. In other words, the metamorphic P–T conditionsattained at a similar depth level may yield similartemperatures but the time required for metamorphicequilibration <strong>and</strong> development <strong>of</strong> specific metamorphictextures may differ substantially.ACKNOWLEDGEMENTSThis research is a part <strong>of</strong> an ongoing collaborationbetween Charles University, Prague, Mainz University,Germany, <strong>and</strong> ETH Zu¨ rich, Switzerl<strong>and</strong>. Financialsupport to P. Sˇtı´pska´ by the Charles University GrantAgency (grant no. 223/2002/B-GEO/PrF) <strong>and</strong> theCzech National Grant Agency (GA205/00/D043 <strong>and</strong>GA205/99/1195) is gratefully acknowledged. Themicroprobe work at ETH Zu¨ rich was financed by theSwiss National Foundation (ÔContinuous OrogenesisÕgrant to A.B. Thompson). Two visits <strong>of</strong> P. Sˇtı´pska´ toMainz University <strong>and</strong> a part <strong>of</strong> the microprobe workwere funded by the German Science Foundation(DFG, grant Kr 68-1, Kr 590/35). The grant no.24313005 <strong>of</strong> the Ministry <strong>of</strong> Education <strong>of</strong> the CzechRepublic provided funds for O. Lexa, P. Sˇtı´pska´ <strong>and</strong>K. Schulmann.REFERENCESAzpiroz, M. D. & Fernández, C., 2003. Characterization <strong>of</strong>tectono-metamorphic events using crystal size distribution(CSD) diagrams. A case study from the Acebuches metabasites(SW Spain). Journal <strong>of</strong> Structural Geology, 25, 935–947.Baratoux, L., Schulmann, K., Ulrich, S. & Lexa, O., 2005.Contrasting microstructures <strong>and</strong> deformation mechanisms inmetagabbro mylonites contemporaneously deformed underdifferent temperatures (c. 650 <strong>and</strong> c. 750 °C). In: DeformationMechanisms, Rheology <strong>and</strong> Tectonics: from Minerals to theLithosphere (eds Gapais, D., Brun, J. P. & Cobbold, P. R.),Geological Society Special Publications, pp. 97–125. GeologicalSociety <strong>of</strong> London, London, UK.Bohlen, S. R., Wall, V. J. & Boettcher, A. L., 1983. Experimentalinvestigations <strong>and</strong> geological applications <strong>of</strong> equilibria in thesystem FeO–TiO 2 –Al 2 O 3 –SiO 2 –H 2 O. American Mineralogist,68, 1049–1058.Brodie, K. H. & Rutter, E. H., 1987. The role <strong>of</strong> transiently finegrainedreaction-products in syntectonic metamorphism –natural <strong>and</strong> experimental examples. Canadian Journal <strong>of</strong> EarthSciences, 24, 556–564.Burg, J.-P., 1999. Ductile structures <strong>and</strong> instabilities: theirimplication for Variscan tectonics in the Ardennes. Tectonophysics,309, 1–25.Cahn, J. V., 1957. Nucleation on dislocations. Acta Metallurgica,5, 169–172.Carlslaw, H. S. & Jaeger, J. C., 1959. Conduction <strong>of</strong> Heat inSolids. Oxford University Press, Oxford.Cashman, K. V. & Ferry, J. M., 1988. Crystal size distribution(CSD) in rocks <strong>and</strong> the kinetics <strong>and</strong> dynamics <strong>of</strong> crystallization;3, Metamorphic crystallization. Contributions toMineralogy <strong>and</strong> Petrology, 99, 401–415.Dallain, C., Schulmann, K. & Ledru, P., 1999. Textural evolutionin the transition from subsolidus annealing to meltingprocess, Velay Dome, French Massif Central. Journal <strong>of</strong>Metamorphic Geology, 17, 61–74.DeH<strong>of</strong>f, R. T., 1991. A geometrically general-theory <strong>of</strong> diffusioncontrolled coarsening. Acta Metallurgica Et Materialia, 39,2349–2360.DeVore, G. W., 1959. Role <strong>of</strong> minimum interfacial free energy indetermining the macroscopic features <strong>of</strong> minerals assemblages.Journal <strong>of</strong> Geology, 67, 211–227.Eberl, D. D., Drits, V. A. & Srodon J., 1998. Deducing growthmechanisms for minerals from the shapes <strong>of</strong> crystal size distributions.American Journal <strong>of</strong> Science, 298, 499–533.Ferry, J. M. & Spear, F. S., 1978. Experimental calibration <strong>of</strong> thepartitioning <strong>of</strong> Fe <strong>and</strong> Mg between biotite <strong>and</strong> garnet.Contributions to Mineralogy <strong>and</strong> Petrology, 66, 113–117.Flinn, D., 1969. Grain contacts in crystalline rocks. Lithos, 2,361–370.Gasparik, T. & Newton, R. C., 1984. The reversed aluminacontents <strong>of</strong> orthopyroxene in equilibrium with spinel <strong>and</strong>forsterite in the system MgO–Al 2 O 3 –SiO 2 . Contributions toMineralogy <strong>and</strong> Petrology, 85, 186–196.Hickey, K. A. & Bell, T. H., 1996. Syn-deformational graingrowth: matrix coarsening during foliation development <strong>and</strong>regional metamorphism rather than by static annealing.European Journal <strong>of</strong> Mineralogy, 8, 1351–1373.Higgins, M. D., 1998. Origin <strong>of</strong> anorthosite by textural coarsening:quantitative measurements <strong>of</strong> a natural sequence <strong>of</strong>textural development. Journal <strong>of</strong> Petrology, 39, 1307–1323.Holl<strong>and</strong>, T. J. B. & Blundy, J. D., 1994. Non-ideal interactionsin calcic amphiboles <strong>and</strong> their bearing on amphibole–plagio-Ó 2005 Blackwell Publishing Ltd247
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