chemical thermodynamics of neptunium and plutonium - U.S. ...

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7.6 Summary 103Figure 7.2:SHE.Formal potentials (1 M HClO 4 , 25 ◦ C) for <strong>neptunium</strong>, in units <strong>of</strong> V vs.-(0.558 ± 0.010)-(0.897 ± 0.012)(0.678 ± 0.001)(0.449 ± 0.001)(0.940 ± 0.001) -(1.307 ± 0.014)(1.137 ± 0.001) (0.743 ± 0.001) (0.155 ± 0.001) -(1.795 ± 0.020)NpO 2+ 2 NpO +Np 4+ Np 3+2 Np
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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45Table 3.1: (continued)Compound f
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47Table 3.2: Selected thermodynamic
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49Table 3.2: (continued)SpeciesReac
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51Table 3.2: (continued)SpeciesReac
Page 78 and 79: Chapter 4Selected plutonium dataThi
Page 80 and 81: 55Table 4.1: Selected thermodynamic
Page 82 and 83: 57Table 4.1: (continued)Compound f
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Page 90 and 91: Chapter 5Selected auxiliary dataThi
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9.1 Neptunium halide compounds 1539
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9.1 Neptunium halide compounds 1559
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9.2 Aqueous neptunium group 17 (hal
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Chapter 10Neptunium group 16compoun
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10.1 Neptunium sulphur compounds an
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188 11. Neptunium group 15 compound
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sol 3 M NaClO 4 22 (15.72±0.51) [9
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ed 0.51 M K 2 CO 3 ? (0.451±0.010)
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was unique. The interpretation (pro
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Method Ionic medium t log 10 K (I c
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sol 3 M NaClO 25 (4.76±0.04) (e) (
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sp 5 M NaCl 23 (2.91±0.20) [96RUN/
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sol 1 M NaClO 30 −(10.7±0.1) −
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KNpO 2 CO 3·xH 2 O(s) + 2CO 3Å K
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K 3 NpO 2 (CO 3 ) 2·xH 2 O(s) + CO
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Reference log 10 Ks,0 ◦ log 10 K1
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3complex (Cl − addition to NpO 2
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Np(CO 3 ) 4−4 + CO 2−3Å Np(CO
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Np 4+ + 3CO 2−3Å Np(CO 3 ) 2−3
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10 21 3 2 3 3 2 3 2 3log 10 K s,0 N
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Chapter 13Neptunium group 2(alkalin
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Chapter 14Neptunium group 1 (alkali
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14.4 Neptunium rubidium compounds 2
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Chapter 15Elemental plutonium15.1 P
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15.2 Plutonium ideal monatomic gas
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Chapter 16Plutonium aqua ionsPluton
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16.2 PuO 2+2303After incorporating
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16.3 PuO + 2305Table 16.2: Experime
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16.3 PuO + 2307Blanc and Madic [84B
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16.4 Pu 4+ 309Table 16.3: Experimen
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16.4 Pu 4+ 311Figure 16.2: Formal p
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16.5 Pu 3+ 31316.5 Pu 3+The values
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16.6 Summary 315Figure 16.3: Standa
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Chapter 17Plutonium oxygen and hydr
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17.1 Aqueous plutonium hydroxide co
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2:2 LPAS 25 0.1 M ClO − −7.3
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17.2 Solid plutonium oxides and hyd
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346 18. Plutonium group 17 (halogen
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PuO 2+2+ F − Å PuO 2 F + (b)cix
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Chapter 19Plutonium group 16 compou
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19.1 Plutonium sulphur compounds an
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402 20. Plutonium group 15 compound
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dis, TTA 2 M HClO 4 10 (0.57 ± 0.0
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ut does not exist as cited (there i
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Chapter 21Plutonium group 14 compou
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21.1 Plutonium carbon compounds and
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Chapter 22Plutonium group 2(alkalin
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22.2 Plutonium barium compounds 447
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Bibliography[22BRØ][22BRØ2][35GUG
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BIBLIOGRAPHY 453[49HIN/AME][49HIN/M
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BIBLIOGRAPHY 455[50BUS/COW][50EYR/W
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BIBLIOGRAPHY 457[53JON][53RAB][53WE
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BIBLIOGRAPHY 459[56RAB]Rabideau, S.
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BIBLIOGRAPHY 461[59AXE/IHL][59BJO/R
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BIBLIOGRAPHY 463[60RAB/KLI][61BEN/D
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BIBLIOGRAPHY 465[62SCH/NEB] Schwabe
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BIBLIOGRAPHY 467[64GEL/ZAI][64KAY/L
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BIBLIOGRAPHY 469[65MUL/ELL][65PAR][
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BIBLIOGRAPHY 471[66RAN][66RYK/YAK][
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BIBLIOGRAPHY 473[67SOL/TSV][68AHR/B
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BIBLIOGRAPHY 475[68TRE/GER][68ZAI/A
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BIBLIOGRAPHY 477[69SUL/ZIE][70AL-/W
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BIBLIOGRAPHY 479hexammine cobalt(II
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BIBLIOGRAPHY 481[72BLO/BUK][72BLO/B
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BIBLIOGRAPHY 483radioactif., CEN, F
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BIBLIOGRAPHY 485169, 169, 169, 170,
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BIBLIOGRAPHY 487[75ACK/RAU][75ALE/O
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BIBLIOGRAPHY 489other Actinides, he
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BIBLIOGRAPHY 491[76OET/RAN][76PAR][
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BIBLIOGRAPHY 493[77MUS/MAR] Musikas
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BIBLIOGRAPHY 495[78RAO/BAG][78RAO/B
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BIBLIOGRAPHY 497[79MUE/LAN][79PIT][
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BIBLIOGRAPHY 499and plutonium sesqu
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BIBLIOGRAPHY 501[81RAI/SWA][81ROL/G
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BIBLIOGRAPHY 503[82MOR/FUG][82NAI/C
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BIBLIOGRAPHY 505[83KIM/LIE][83MAR/H
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BIBLIOGRAPHY 507[84BUS/PLU][84CHO/R
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BIBLIOGRAPHY 509[84REE/DAN][84VAR/B
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BIBLIOGRAPHY 511The gaseous actinid
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BIBLIOGRAPHY 513[86BLA/FRE][86BRO/F
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BIBLIOGRAPHY 515and Radiation Chemi
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BIBLIOGRAPHY 517[87RAI/SWA][87RIC/S
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BIBLIOGRAPHY 519Can. J. Chem., 66 (
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BIBLIOGRAPHY 521[89RÖS/DIT][89SAW/
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BIBLIOGRAPHY 523[90KRI/HAG][90LEI][
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BIBLIOGRAPHY 525[91AND/CAS][91BYR/L
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BIBLIOGRAPHY 527[91WAN][91YAM/PRA][
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BIBLIOGRAPHY 529diochim. Acta, 58/5
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BIBLIOGRAPHY 531[93OKA/MAE][93OKA/R
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BIBLIOGRAPHY 533[94GIF/VIT][94GRI/C
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BIBLIOGRAPHY 535[94VEI/SMI][94YAM/S
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BIBLIOGRAPHY 537RC-1407 and COG-I-9
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BIBLIOGRAPHY 539lecular structure o
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BIBLIOGRAPHY 541in the Plutonium(IV
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List of cited authorsThis chapter c
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LIST OF CITED AUTHORS 545Table 23.1
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Part VAppendices569
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572 A. Discussion of selected refer
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y this review (from these experimen
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800 B. Ionic strength correctionsin
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802 B. Ionic strength correctionsEq
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804 B. Ionic strength correctionsTh
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806 B. Ionic strength correctionsof
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808 B. Ionic strength correctionsFi
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810 B. Ionic strength correctionsNE
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812 B. Ionic strength correctionsIt
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814 B. Ionic strength correctionsTa
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The uncertainties represent the 95%
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824 C. Assigned uncertaintiesX ± 1
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826 C. Assigned uncertaintiesii. If
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828 C. Assigned uncertaintiestwo gr
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830 C. Assigned uncertaintiesNote t
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832 C. Assigned uncertaintiesI m el
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834 C. Assigned uncertaintiesBeving
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836 C. Assigned uncertaintiesIn the
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838 IndexIndex - generalabbreviatio
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840 IndexIndex - neptuniumactinide
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842 Indexlithium compoundsLi 2 NpO
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844 IndexPuOCl(cr), 360chlorine com
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