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Part VAppendices569
Part VAppendices569
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.1 Symbols, terminology and nomenc
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2.1 Symbols, terminology and nomenc
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2.1 Symbols, terminology and nomenc
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2.1 Symbols, terminology and nomenc
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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45Table 3.1: (continued)Compound f
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47Table 3.2: Selected thermodynamic
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49Table 3.2: (continued)SpeciesReac
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51Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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55Table 4.1: Selected thermodynamic
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57Table 4.1: (continued)Compound f
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59Table 4.1: (continued)Compound f
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61SpeciesPu(OH) 3 (cr)ReactionTable
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63Table 4.2: (continued)SpeciesReac
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Chapter 5Selected auxiliary dataThi
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67Table 5.1: (continued)Compound f
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69Table 5.1: (continued)Compound f
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71Table 5.1: (continued)Compound f
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73Table 5.1: (continued)Compound f
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75Table 5.1: (continued)Compound f
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.1 Aqueous neptunium hydroxide com
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8.1 Aqueous neptunium hydroxide com
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8.1 Aqueous neptunium hydroxide com
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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8.2 Crystalline and amorphous neptu
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8.2 Crystalline and amorphous neptu
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8.2 Crystalline and amorphous neptu
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8.2 Crystalline and amorphous neptu
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8.2 Crystalline and amorphous neptu
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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134 9. Neptunium group 17 (halogen)
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136 9. Neptunium group 17 (halogen)
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138 9. Neptunium group 17 (halogen)
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140 9. Neptunium group 17 (halogen)
- Page 167 and 168:
142 9. Neptunium group 17 (halogen)
- Page 169 and 170:
144 9. Neptunium group 17 (halogen)
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146 9. Neptunium group 17 (halogen)
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148 9. Neptunium group 17 (halogen)
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150 9. Neptunium group 17 (halogen)
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152 9. Neptunium group 17 (halogen)
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154 9. Neptunium group 17 (halogen)
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156 9. Neptunium group 17 (halogen)
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158 9. Neptunium group 17 (halogen)
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160 9. Neptunium group 17 (halogen)
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162 9. Neptunium group 17 (halogen)
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164 9. Neptunium group 17 (halogen)
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166 9. Neptunium group 17 (halogen)
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168 9. Neptunium group 17 (halogen)
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170 9. Neptunium group 17 (halogen)
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172 9. Neptunium group 17 (halogen)
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174 9. Neptunium group 17 (halogen)
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176 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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180 10. Neptunium group 16 compound
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182 10. Neptunium group 16 compound
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184 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.1 Neptunium nitrogen compounds a
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11.1 Neptunium nitrogen compounds a
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
- Page 240 and 241:
12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
- Page 244 and 245:
12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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sol 3 M NaClO 25 −(2.14±0.18)
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(f) Values selected in this review
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12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
- Page 276 and 277:
12.1 Neptunium carbon compounds and
- Page 278 and 279:
12.1 Neptunium carbon compounds and
- Page 280 and 281:
12.1 Neptunium carbon compounds and
- Page 282 and 283:
(V vs. SHE) (V vs. SHE) (V · K −
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(h) 1MK 2 CO 3 is written in Table
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12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
- Page 292 and 293:
2 3 r H m (5.0±2.0)log 10 β 2 MO
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12.1 Neptunium carbon compounds and
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12.1 Neptunium carbon compounds and
- Page 298 and 299:
12.1 Neptunium carbon compounds and
- Page 300 and 301:
12.1 Neptunium carbon compounds and
- Page 302 and 303:
12.1 Neptunium carbon compounds and
- Page 304 and 305:
12.1 Neptunium carbon compounds and
- Page 306 and 307:
12.1 Neptunium carbon compounds and
- Page 308 and 309:
12.1 Neptunium carbon compounds and
- Page 310 and 311:
12.1 Neptunium carbon compounds and
- Page 312:
12.1 Neptunium carbon compounds and
- Page 315 and 316:
290 13. Neptunium group 2 (alkaline
- Page 317 and 318:
292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
- Page 337 and 338:
312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
- Page 341 and 342:
316 16. Plutonium aqua ionsFigure 1
- Page 343 and 344:
318 17. Plutonium oxygen and hydrog
- Page 345 and 346:
320 17. Plutonium oxygen and hydrog
- Page 347 and 348:
322 17. Plutonium oxygen and hydrog
- Page 349 and 350:
324 17. Plutonium oxygen and hydrog
- Page 351 and 352:
1:1 pot RT 1 M NaClO 4 −5.71 [49K
- Page 353 and 354:
328 17. Plutonium oxygen and hydrog
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330 17. Plutonium oxygen and hydrog
- Page 357 and 358:
332 17. Plutonium oxygen and hydrog
- Page 359 and 360:
334 17. Plutonium oxygen and hydrog
- Page 361 and 362:
336 17. Plutonium oxygen and hydrog
- Page 363 and 364:
338 17. Plutonium oxygen and hydrog
- Page 365 and 366:
340 17. Plutonium oxygen and hydrog
- Page 367 and 368:
342 17. Plutonium oxygen and hydrog
- Page 370 and 371:
Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.1 Plutonium halide compounds 349
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18.1 Plutonium halide compounds 351
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18.1 Plutonium halide compounds 353
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18.1 Plutonium halide compounds 355
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18.1 Plutonium halide compounds 357
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18.1 Plutonium halide compounds 359
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18.1 Plutonium halide compounds 361
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18.1 Plutonium halide compounds 363
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18.1 Plutonium halide compounds 365
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18.1 Plutonium halide compounds 367
- Page 394 and 395:
18.1 Plutonium halide compounds 369
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18.2 Aqueous plutonium group 17 (ha
- Page 398 and 399:
18.2 Aqueous plutonium group 17 (ha
- Page 400 and 401:
18.2 Aqueous plutonium group 17 (ha
- Page 402 and 403:
PuO 2+2+ 3F − Å PuO 2 F − (b)3
- Page 404 and 405:
18.2 Aqueous plutonium group 17 (ha
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18.2 Aqueous plutonium group 17 (ha
- Page 408 and 409:
18.2 Aqueous plutonium group 17 (ha
- Page 410 and 411:
18.2 Aqueous plutonium group 17 (ha
- Page 412:
18.2 Aqueous plutonium group 17 (ha
- Page 415 and 416:
390 19. Plutonium group 16 compound
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392 19. Plutonium group 16 compound
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394 19. Plutonium group 16 compound
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396 19. Plutonium group 16 compound
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398 19. Plutonium group 16 compound
- Page 426 and 427:
Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
- Page 434 and 435:
3 3 3dis, TTA 6 M (? HCl or HClO 4
- Page 436 and 437:
20.1 Plutonium nitrogen compounds a
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20.1 Plutonium nitrogen compounds a
- Page 440 and 441:
20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
- Page 448 and 449:
20.6 The plutonium-bismuth system 4
- Page 450:
20.6 The plutonium-bismuth system 4
- Page 453 and 454:
428 21. Plutonium group 14 compound
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430 21. Plutonium group 14 compound
- Page 457 and 458:
432 21. Plutonium group 14 compound
- Page 459 and 460:
434 21. Plutonium group 14 compound
- Page 461 and 462:
436 21. Plutonium group 14 compound
- Page 463 and 464:
438 21. Plutonium group 14 compound
- Page 465 and 466:
440 21. Plutonium group 14 compound
- Page 467 and 468:
442 21. Plutonium group 14 compound
- Page 469 and 470:
444 21. Plutonium group 14 compound
- Page 471 and 472:
446 22. Plutonium group 2 (alkaline
- Page 474:
Chapter 23Plutonium group 1 (alkali
- Page 477 and 478:
452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
- Page 479 and 480:
454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
- Page 481 and 482:
456 BIBLIOGRAPHY[51WES/EYR][51WES/W
- Page 483 and 484:
458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
- Page 485 and 486:
460 BIBLIOGRAPHYmetals in connectio
- Page 487 and 488:
462 BIBLIOGRAPHY[59SHE/TIM][59STU][
- Page 489 and 490:
464 BIBLIOGRAPHY[61SCH][61STO/FRY][
- Page 491 and 492:
466 BIBLIOGRAPHY[63ROB/WAL] Roberts
- Page 493 and 494:
468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
- Page 495 and 496:
470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
- Page 497 and 498:
472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
- Page 499 and 500:
474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
- Page 501 and 502:
476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
- Page 503 and 504:
478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
- Page 505 and 506:
480 BIBLIOGRAPHY[71MOS][71MOS2][71M
- Page 507 and 508:
482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
- Page 509 and 510:
484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
- Page 511 and 512:
486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
- Page 513 and 514:
488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
- Page 515 and 516:
490 BIBLIOGRAPHY298.15 K”, J. Che
- Page 517 and 518:
492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
- Page 519 and 520:
494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
- Page 521 and 522:
496 BIBLIOGRAPHYof plutonium(IV)”
- Page 523 and 524:
498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
- Page 525 and 526:
500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
- Page 527 and 528:
502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
- Page 529 and 530:
504 BIBLIOGRAPHY[83ALL][83BES/LIN][
- Page 531 and 532:
506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
- Page 533 and 534:
508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
- Page 535 and 536:
510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
- Page 537 and 538:
512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
- Page 539 and 540:
514 BIBLIOGRAPHY[86FAH][86FRE/KEL]F
- Page 541 and 542:
516 BIBLIOGRAPHY[87BEN][87BEN/HOF][
- Page 543 and 544: 518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
- Page 545 and 546: 520 BIBLIOGRAPHYGeochim. Cosmochim.
- Page 547 and 548: 522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
- Page 549 and 550: 524 BIBLIOGRAPHY254, 258, 258, 264,
- Page 551 and 552: 526 BIBLIOGRAPHY[91MEI][91NIT][91OK
- Page 553 and 554: 528 BIBLIOGRAPHYment”, Waste Mana
- Page 555 and 556: 530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
- Page 557 and 558: 532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
- Page 559 and 560: 534 BIBLIOGRAPHYpages 222, 223, 226
- Page 561 and 562: 536 BIBLIOGRAPHYK, gas-phase infrar
- Page 563 and 564: 538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
- Page 565 and 566: 540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
- Page 567 and 568: 542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
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748 A. Discussion of selected refer
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750 A. Discussion of selected refer
- Page 777 and 778:
y this review (from these experimen
- Page 779 and 780:
754 A. Discussion of selected refer
- Page 781 and 782:
756 A. Discussion of selected refer
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758 A. Discussion of selected refer
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760 A. Discussion of selected refer
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762 A. Discussion of selected refer
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764 A. Discussion of selected refer
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766 A. Discussion of selected refer
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768 A. Discussion of selected refer
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770 A. Discussion of selected refer
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772 A. Discussion of selected refer
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774 A. Discussion of selected refer
- Page 801 and 802:
776 A. Discussion of selected refer
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778 A. Discussion of selected refer
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780 A. Discussion of selected refer
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782 A. Discussion of selected refer
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784 A. Discussion of selected refer
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786 A. Discussion of selected refer
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788 A. Discussion of selected refer
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790 A. Discussion of selected refer
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792 A. Discussion of selected refer
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794 A. Discussion of selected refer
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796 A. Discussion of selected refer
- Page 823 and 824:
798 A. Discussion of selected refer
- Page 825 and 826:
800 B. Ionic strength correctionsin
- Page 827 and 828:
802 B. Ionic strength correctionsEq
- Page 829 and 830:
804 B. Ionic strength correctionsTh
- Page 831 and 832:
806 B. Ionic strength correctionsof
- Page 833 and 834:
808 B. Ionic strength correctionsFi
- Page 835 and 836:
810 B. Ionic strength correctionsNE
- Page 837 and 838:
812 B. Ionic strength correctionsIt
- Page 839 and 840:
814 B. Ionic strength correctionsTa
- Page 841 and 842:
816 B. Ionic strength correctionsTa
- Page 843 and 844:
818 B. Ionic strength correctionsTa
- Page 845 and 846:
820 B. Ionic strength correctionsTa
- Page 847 and 848:
The uncertainties represent the 95%
- Page 849 and 850:
824 C. Assigned uncertaintiesX ± 1
- Page 851 and 852:
826 C. Assigned uncertaintiesii. If
- Page 853 and 854:
828 C. Assigned uncertaintiestwo gr
- Page 855 and 856:
830 C. Assigned uncertaintiesNote t
- Page 857 and 858:
832 C. Assigned uncertaintiesI m el
- Page 859 and 860:
834 C. Assigned uncertaintiesBeving
- Page 861 and 862:
836 C. Assigned uncertaintiesIn the
- Page 863 and 864:
838 IndexIndex - generalabbreviatio
- Page 865 and 866:
840 IndexIndex - neptuniumactinide
- Page 867 and 868:
842 Indexlithium compoundsLi 2 NpO
- Page 869 and 870:
844 IndexPuOCl(cr), 360chlorine com
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