chemical thermodynamics of neptunium and plutonium - U.S. ...

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LIST OF CITED AUTHORS 549Table 23.1: (continued)AuthorEyring, L.Fahey, J. A.Faircloth, R. L.Fang, D.Fanghänel, T.Farah, K.Fardy, J. J.Faucherre, J.Feber, R. C.Fedorov, I. A.Fedoseev, A. M.Felmy, A. R.Fernelius, W. C. (chairman)Ferri, D.Fidelis, I.Fink, J. K.Firestone, R. B.Fischer, J.Fitzgibbon, G. C.Florin,A.E.Flotow, H. E.Flowers, G. C.Foltyn, E. M.Fomin, V. V.Forchioni, A.Fox, A. C.Fradin, F. Y.Francis, K. E.de Franco, M.Fred, M.Freeman, R. D.Fried, S.Fried, S. M.Friedman, A. M.Frlec, B.Frolova, L. M.Frolova, U. K.Fronæus, S.Frost, B. R. T.Frurip, D. J.Fry, A. J.References[49WES/EYR], [50EYR/WES], [51WES/EYR][76FAH/TUR], [86FAH][66ACK/FAI][69KEL/FAN][95FAN/NEC], [95NEC/FAN], [96FAN/NEC], [97NEC/FAN],[97PAS/CZE], [99NEC/FAN][76SOU/SHA][74FAR/PEA], [76FAR/BUC][73DER/FAU], [73DER/FAU2], [73DER/FAU3][65FEB/HER][64POZ/FED][79FED/PER], [89BUD/FED][89FEL/RAI], [90RAI/FEL], [92RAI/FEL], [95RAI/FEL],[97FEL/RAI], [98RAI/FEL], [99RAI/HES], [99RAI/HES2][77FER][81CIA/FER], [83FER/GRE], [85FER/GRE][78BED/FID][82FIN][86BRO/FIR][61JOH/FIS][71FIT/PAV][56FLO/TAN][74OSB/FLO], [75OSB/FLO], [76FLO/OSB], [81FLO/TET][81HEL/KIR][90FOL][60LIP/POZ][83MUS/CUI][62RAN/FOX][69LAM/FRA][56MAN/RAE][77CHE/DEA][75FRE], [83FRE/BLA], [86BLA/FRE][84FRE][69COH/FRI], [69FRI/SCH], [70COH/FRI], [52FRI/DAV][74OSB/FLO], [75OSB/FLO], [76FLO/OSB], [76GRU/MCB][85SCH/FRI][67FRL/CLA][76FRO/CHI], [76FRO/CHI2][66FRO/KUM][51FRO][56FRO][85CHA/DAV][61STO/FRY](Continued on next page)
550 LIST OF CITED AUTHORSTable 23.1: (continued)AuthorFuger, J.Fuks, L.Fulton, R. W.Gainar, I.Gal’chenko, G. L.Gallegos, C. F.Gallo, L. S.G<strong>and</strong>he, S. P.Gardner, E. R.Garisto, F.Garvin, D.Gatti, R.Gaumann, T.Gel’man, A. D.Gens, R.Gerdanian, P.Gerding, T. J.Gibney, R. B.Giffaut, E.Gingerich, K. A.Ginnings, D. C.Girichev, G. V.Giricheva, N. I.Gleiser, M.Glushko, V. P.Golodets, G. I.Golub, A. M.Goodman, G. L.Gorbenko-Germanov, D. S.Gordon, J. E.Gordon, S.Gore,S.J.M.Gorum, A. E.Goudiakas, J.Grass, F.Graves, D. T.Green,D.W.References[63FUG/CUN], [69FUG/BRO], [71FUG/BRO], [73FUG/BRO],[76FUG/OET], [77BRO/HUR], [77MAG/FUG], [79FUG],[82MOR/FUG], [83FUG], [83FUG/PAR], [83MOR/WIL], [85FUG],[85GEN/FUG], [85MAR/FUG], [89SCH/GEN], [91GOU/JEM],[92FUG/KHO], [92GRE/FUG], [94MER/FUG], [2000RAN/FUG][87FUK/SIE][85KRU/RAI], [92RAI/FEL][64GAI/SYK][59POP/GAL][81ROL/GAL][61PAU/GAL][79KUS/GAN][64MAR/BON], [65GAR/MAR][89LEM/GAR][87GAR/PAR][94SIL/NIT][61BER/GAU][58GEL/ZAI], [58GEL/ZAI2], [58MOS/GEL], [59GEL/ZAI],[62GEL/MOS], [64GEL/ZAI], [67GEL/MOS], [68KRO/MEF],[68ZAI/ALE], [68ZAI/ALE2], [70KRO/GEL], [72BLO/BUK],[72BLO/BUK2], [72MEF/KRO], [72MEF/KRO2], [72PER/KRO],[74MEF/KRO][83MOR/WIL], [85GEN/FUG], [89SCH/GEN][77CHE/DEA][68TRE/GER][73SAN/GIB][92CAP/VIT], [93GIF/VIT], [93GIF/VIT2], [94GIF], [94GIF/VIT],[96CAP/VIT][67GIN][47GIN/COR][96KON/BOO][96KON/BOO][73HUL/DES][82GLU/GUR][61GOL/GOL][61GOL/GOL][65WEI/GOO][65IAK/GOR], [66GOR/KLI], [66GOR/ZEN][76GOR/HAL][80SCH/GOR], [83SCH/GOR], [84MUL/GOR][85EWA/GOR][57GOR][91GOU/JEM][71SHE/GRA][77MYE/GRA][78GRE/REE](Continued on next page)
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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49Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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Chapter 5Selected auxiliary dataThi
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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sol 3 M NaClO 25 −(2.14±0.18)
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(f) Values selected in this review
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(V vs. SHE) (V vs. SHE) (V · K −
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(h) 1MK 2 CO 3 is written in Table
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2 3 r H m (5.0±2.0)log 10 β 2 MO
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
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464 BIBLIOGRAPHY[61SCH][61STO/FRY][
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466 BIBLIOGRAPHY[63ROB/WAL] Roberts
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468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
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474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
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476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
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478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
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480 BIBLIOGRAPHY[71MOS][71MOS2][71M
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482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
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484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
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488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
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490 BIBLIOGRAPHY298.15 K”, J. Che
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492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
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494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
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496 BIBLIOGRAPHYof plutonium(IV)”
Page 523 and 524: 498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
Page 525 and 526: 500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
Page 527 and 528: 502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
Page 529 and 530: 504 BIBLIOGRAPHY[83ALL][83BES/LIN][
Page 531 and 532: 506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
Page 533 and 534: 508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
Page 535 and 536: 510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
Page 537 and 538: 512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
Page 539 and 540: 514 BIBLIOGRAPHY[86FAH][86FRE/KEL]F
Page 541 and 542: 516 BIBLIOGRAPHY[87BEN][87BEN/HOF][
Page 543 and 544: 518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
Page 545 and 546: 520 BIBLIOGRAPHYGeochim. Cosmochim.
Page 547 and 548: 522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
Page 549 and 550: 524 BIBLIOGRAPHY254, 258, 258, 264,
Page 551 and 552: 526 BIBLIOGRAPHY[91MEI][91NIT][91OK
Page 553 and 554: 528 BIBLIOGRAPHYment”, Waste Mana
Page 555 and 556: 530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
Page 557 and 558: 532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
Page 559 and 560: 534 BIBLIOGRAPHYpages 222, 223, 226
Page 561 and 562: 536 BIBLIOGRAPHYK, gas-phase infrar
Page 563 and 564: 538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
Page 565 and 566: 540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
Page 567 and 568: 542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
Page 569 and 570: 544 LIST OF CITED AUTHORSTable 23.1
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Page 596 and 597: Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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