chemical thermodynamics of neptunium and plutonium - U.S. ...

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2.1 Symbols, terminology and nomenclature 11Table 2.1: (continued),B )Symbols and terminologyactivity coefficient, molality basis: a B /m Bγ Bactivity coefficient, concentration basis: a B /c By Bmean ionic activity (e) , a (ν ++ν − )± = a B = a ν ++ a ν −− a ±mean ionic activity coefficient (e) , γ (ν ++ν − )± = γ ν ++ γ ν −− γ ±osmotic coefficient, molality basisφionic strength: I m = 1 ∑2 i m i zi 2 or I c = 1 ∑2 i c i zi2 ISIT ion interaction coefficient between substance B 1 and ε (B1substance B 22stoichiometric coefficient of substance B (negative for ν Breactants, positive for products)general equation for a chemical reaction0 = ∑ B ν BBequilibrium constant (f)Krate constantkFaraday constantFcharge number of an ion B (positive for cations, negative for z Banions)charge number of a cell reactionnelectromotive forceEpH =−log 10 [a H +/(mol · kg −1 )]electrolytic conductivityκsuperscript for standard state (g)◦(a) The ratio of the average mass per formula unit of a substance to12 1 of the mass of an atomof nuclide 12 C.(b) cf. Sections 1.2 and 3.6 of the IUPAC manual [79WHI].(c) This quantity is called “amount-of-substance concentration” in the IUPAC manual [79WHI].A solution with a concentration equal to 0.1mol· dm −3 is called a 0.1 molar solution or a0.1 M solution.(d) A solution having a molality equal to 0.1mol· kg −1 is called a 0.1 molal solution or a 0.1 msolution.(e) For an electrolyte N ν+ X ν− which dissociates into ν ± (= ν + + ν − ) ions, in an aqueoussolution with concentration m, the individual cationic molality and activity coefficient arem + (= ν + m) and γ + (= a + /m + ). A similar definition is used for the anionic symbols.Electrical neutrality requires that ν + z + = ν − z − .(f) Special notations for equilibrium constants are outlined in Section 2.1.6. In some cases, K cis used to indicate a concentration constant in molar units, and K m a constant in molal units.(g) See Section 2.3.1.
12 2. Standards, Conventions, and Contents of the TablesTable 2.2: Abbreviations for experimental methodsaix anion exchangecal calorimetrychr chromatographycix cation exchangecol colorimetrycon conductivitycor correctedcou coulometrycry cryoscopydis distribution between two phasesem electromigrationemf electromotive force, not specifiedgl glass electrodeise-X ion selective electrode with ion X statedix ion exchangekin rate of reactionmvd mole volume determinationnmr nuclear magnetic resonancepol polarographypot potentiometryprx proton relaxationqh quinhydrone electrodered emf with redox electroderev reviewsp spectrophotometrysol solubilitytc transient conductivitytls thermal lensing spectrophotometryvlt voltammetry? method unknown to the reviewers
Page 1 and 2: 4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
Page 3 and 4: CHEMICAL THERMODYNAMICSVol. 1. Chem
Page 5 and 6: Published under the imprint NORTH-H
Page 7 and 8: viPREFACEviewed several of the othe
Page 9 and 10: viiiACKNOWLEDGEMENTSand Whiteshell
Page 11 and 12: xFOREWORDsending comments on the TD
Page 13 and 14: xiiCONTENTSIII Discussion of neptun
Page 15: xivCONTENTS11.1.4.2 Solid neptunium
Page 18 and 19: CONTENTSxvii20.5.1 PuSb(cr) . . . .
Page 20 and 21: List of Tables2.1 Symbols and termi
Page 22 and 23: LIST OF TABLESxxi20.2 Experimental
Page 24 and 25: List of Figures2.1 Standard order o
Page 26: Part IIntroductory material1
Page 29 and 30: 4 1. IntroductionInorganic Complexe
Page 31 and 32: 6 1. Introductionlected, but form a
Page 34 and 35: Chapter 2Standards, Conventions, an
Page 38 and 39: 2.1 Symbols, terminology and nomenc
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Page 50 and 51: 2.2 Units and conversion factors 25
Page 52 and 53: 2.3 Standard and reference conditio
Page 54 and 55: 2.3 Standard and reference conditio
Page 56 and 57: 2.5 Uncertainty estimates 31Table 2
Page 58 and 59: 2.7 Presentation of the selected da
Page 60: 2.7 Presentation of the selected da
Page 64 and 65: Chapter 3Selected neptunium dataThi
Page 66 and 67: 41Table 3.1: Selected thermodynamic
Page 68 and 69: 43Table 3.1: (continued)Compound f
Page 74 and 75: 49Table 3.2: (continued)SpeciesReac
Page 76 and 77: 51Table 3.2: (continued)SpeciesReac
Page 78 and 79: Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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63Table 4.2: (continued)SpeciesReac
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Chapter 5Selected auxiliary dataThi
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67Table 5.1: (continued)Compound f
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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sol 3 M NaClO 25 −(2.14±0.18)
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(f) Values selected in this review
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(V vs. SHE) (V vs. SHE) (V · K −
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(h) 1MK 2 CO 3 is written in Table
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2 3 r H m (5.0±2.0)log 10 β 2 MO
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
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464 BIBLIOGRAPHY[61SCH][61STO/FRY][
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466 BIBLIOGRAPHY[63ROB/WAL] Roberts
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468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
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474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
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476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
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478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
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480 BIBLIOGRAPHY[71MOS][71MOS2][71M
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482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
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484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
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488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
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490 BIBLIOGRAPHY298.15 K”, J. Che
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492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
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494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
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496 BIBLIOGRAPHYof plutonium(IV)”
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498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
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500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
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502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
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504 BIBLIOGRAPHY[83ALL][83BES/LIN][
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506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
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508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
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510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
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512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
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514 BIBLIOGRAPHY[86FAH][86FRE/KEL]F
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516 BIBLIOGRAPHY[87BEN][87BEN/HOF][
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518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
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520 BIBLIOGRAPHYGeochim. Cosmochim.
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522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
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524 BIBLIOGRAPHY254, 258, 258, 264,
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526 BIBLIOGRAPHY[91MEI][91NIT][91OK
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528 BIBLIOGRAPHYment”, Waste Mana
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530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
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532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
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534 BIBLIOGRAPHYpages 222, 223, 226
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536 BIBLIOGRAPHYK, gas-phase infrar
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538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
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540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
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542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
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544 LIST OF CITED AUTHORSTable 23.1
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Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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