chemical thermodynamics of neptunium and plutonium - U.S. ...

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BIBLIOGRAPHY 471[66RAN][66RYK/YAK][66SHI/NAZ][66STE][66WAI][67DAV][67DEN/SHE][67DEN/SHE2][67DES][67ENG]Rand, M. H., “Thermochemical properties, in: Plutonium: Physicochemicalproperties of its compounds and alloys”, At. Energy Rev.,4 (1966) 7–51, Special Issue No. 1. Cited pages 312, 312, 350,351, 561Rykov, A. G., Yakovlev, G. N., “Investigations of the oxidationreductionreactions of the actinide elements. II. Kinetics of the reactionbetween neptunium(IV) and neptunium(VI) in nitrate solutions”,Sov. Radiochem., 8 (1966) 26–30. Cited pages xxiv, 191,192, 195, 195, 562, 568, 610, 611Shilin, I. V., Nazarov, V. K., “Complex formation of neptunium(IV)with nitrate and chloride ions”, Sov. Radiochem., 8 (1966) 474–478.Cited pages 166, 167, 167, 167, 168, 168, 191, 192, 192, 558, 564,612Stephens, D. R., “Phase diagram and compressibility of neptunium”,J. Phys. Chem. Solids, 27 (1966) 1201–1204. Cited pages85, 85, 87, 565Wain, A. G., “The potential of the Pu(III)-Pu(IV) couple in nitricacid solution and equilibrium constants for the nitrato complexesof Pu(IV)”, Report AERE-R5320, U. K. Atomic Energy ResearchEstablishment, 1966. Cited pages 407, 567, 613Davydov, Y. P., “Solubility product of metal hydroxides”, Sov. Radiochem.,9 (1967) 50–54. Cited pages 341, 341, 341, 341, 341,547, 613Denotkina, R. G., Shevchenko, V. B., “Complex formation by plutonium(VI)with phosphate ions”, Russ. J. Inorg. Chem., 12 (1967)1237–1239. Cited pages 418, 418, 419, 419, 419, 548, 563, 614,614Denotkina, R. G., Shevchenko, V. B., “Phosphato-compounds ofplutonium(VI)”, Russ. J. Inorg. Chem., 12 (1967) 42–45. Citedpages 548, 563, 614, 614DeSando, R. J., “X-ray diffraction studies”, Tech. Rep. MLM–1399(TID–4500), Mound Laboratory, Mound Laboratory, Miamisburg,OH, USA, 1967, In Mound Laboratory Progress Report for Chemistry,October to December 1966, pages 48. Cited pages 415, 547Engel, T. K., “Reactor fuels and materials development plutoniumresearch: April-September, 1966”, Tech. Rep. MLM-1347 TID-4500 UC-25 Metals, Ceramics and Materials, United States AtomicEnergy Commission, USA, 1967, 32 p. Cited pages 297, 297, 548
472 BIBLIOGRAPHY[67ERM/STA][67FRL/CLA][67GEL/MOS]Ermakov, V. A., Stary, A. E., “Complex formation of Am, Cm, andFm with lactic acid”, Sov. Radiochem., 9 (1967) 195. Cited pages548, 564, 615Frlec, B., Claassen, H. H., “Long-wavelength, infrared-active fundamentalfor uranium, neptunium and plutonium hexafluorides”, J.Chem. Phys., 46 (1967) 4603–4604. Cited pages 140, 546, 549Gel’man, A. D., Moskvin, A. I., Zaitsev, L. M., Mefod’eva, M. P.,Complex compounds of transuranides, New York: Davey, 1967,152 p. Cited pages 431, 432, 442, 550, 557, 558, 568, 615[67GIN] Gingerich, K. A., “Dissociation energy of gaseous uraniummononitride”, J. Chem. Phys., 47 (1967) 2192–2193. Cited pages404, 550[67GRU/DEK][67IAE][67KRU/MOS][67LAP/BUN][67LYO/BAI][67MOS/ESS][67NAI/RAO]Gruen, D. M., DeKock, C. W., “Electronic absorption spectra ofgaseous PuCl 3 ,PuBr 3 and PuCl 4 ; the thermodynamics of PuCl 4 ”,J. Inorg. Nucl. Chem., 29 (1967) 2569–2575. Cited pages 359, 547,551“The plutonium-oxygen and uranium-plutonium-oxygen systems:A thermochemical assessment”, Technical Report Series 79,I.A.E.A., Vienna, 1967, 86 p. Cited pages 333, 334, 335, 335,337Kruger, O. L., Moser, J. B., “Lattice constants and melting points ofactinide-group IVA-VIA compounds with NaCl-type structures”, J.Phys. Chem. Solids, 28 (1967) 2321–2325. Cited pages 419, 421,421, 422, 423, 555, 558Lapage, R., Bunce, J. L., “Heat of combustion of plutonium nitride”,Trans. Faraday Soc., 63 (1967) 1889–1894. Cited pages402, 402, 545, 555Lyon, W. L., Baily, W. E., “The solid-liquid phase diagram for theUO 2 -PuO 2 system”, J. Nucl. Mater., 22 (1967) 332–339. Citedpages 334, 544, 556Moskvin, A. I., Essen, L. N., Bukhtiyarova, T. N., “The formationof thorium(IV) and uranium(IV) complexes in phosphate solutions”,Russ. J. Inorg. Chem., 12 (1967) 1794–1795. Cited pages198, 198, 467, 545, 548, 558, 615Nair, G. M., Rao, C. L., Welch, G. A., “Study of plutonium(III)-sulphate complexes”, Radiochim. Acta, 7 (1967) 77–80. Citedpages 396, 397, 397, 397, 397, 397, 398, 398, 398, 398, 398, 558,561, 567, 616, 673
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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49Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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Chapter 5Selected auxiliary dataThi
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Chapter 11Neptunium group 15compoun
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11.1 Neptunium nitrogen compounds a
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11.2 Neptunium phosphorus compounds
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11.2 Neptunium phosphorus compounds
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Chapter 12Neptunium group 14compoun
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12.1 Neptunium carbon compounds and
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cal 0.3-1.6 M Na 2 SO 4 25 r H m =
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vlt 0 25 (0.340±0.002) (k) [95OFF/
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sol K + ,CO 2−3 , 20 −(2.31±0.
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sp 0.1 M NaCl 23 (4.68±0.03) [96RU
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dis 0.2 M NaClO 25 2.93 (3.42±1.0)
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sol 1 M NaCl 23 (2.06±0.13) [96RUN
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sol 0.15 M Na 2 CO 3 −(2.58±0.64
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sol 1 M NaClO 30 −(4.0±0.2) [93L
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sol 3 M NaClO 25 −(2.14±0.18)
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(f) Values selected in this review
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(V vs. SHE) (V vs. SHE) (V · K −
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(h) 1MK 2 CO 3 is written in Table
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2 3 r H m (5.0±2.0)log 10 β 2 MO
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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Page 474: Chapter 23Plutonium group 1 (alkali
Page 477 and 478: 452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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Page 481 and 482: 456 BIBLIOGRAPHY[51WES/EYR][51WES/W
Page 483 and 484: 458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
Page 485 and 486: 460 BIBLIOGRAPHYmetals in connectio
Page 487 and 488: 462 BIBLIOGRAPHY[59SHE/TIM][59STU][
Page 489 and 490: 464 BIBLIOGRAPHY[61SCH][61STO/FRY][
Page 491 and 492: 466 BIBLIOGRAPHY[63ROB/WAL] Roberts
Page 493 and 494: 468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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Page 503 and 504: 478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
Page 505 and 506: 480 BIBLIOGRAPHY[71MOS][71MOS2][71M
Page 507 and 508: 482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
Page 509 and 510: 484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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Page 513 and 514: 488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
Page 515 and 516: 490 BIBLIOGRAPHY298.15 K”, J. Che
Page 517 and 518: 492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
Page 519 and 520: 494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
Page 521 and 522: 496 BIBLIOGRAPHYof plutonium(IV)”
Page 523 and 524: 498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
Page 525 and 526: 500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
Page 527 and 528: 502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
Page 529 and 530: 504 BIBLIOGRAPHY[83ALL][83BES/LIN][
Page 531 and 532: 506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
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Page 535 and 536: 510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
Page 537 and 538: 512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
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Page 543 and 544: 518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
Page 545 and 546: 520 BIBLIOGRAPHYGeochim. Cosmochim.
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522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
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524 BIBLIOGRAPHY254, 258, 258, 264,
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526 BIBLIOGRAPHY[91MEI][91NIT][91OK
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528 BIBLIOGRAPHYment”, Waste Mana
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530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
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532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
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534 BIBLIOGRAPHYpages 222, 223, 226
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536 BIBLIOGRAPHYK, gas-phase infrar
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538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
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540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
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542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
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544 LIST OF CITED AUTHORSTable 23.1
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Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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