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sol 3 M NaClO 25 −(2.14±0.18) −(2.12±1.10) (c) [95NEC/RUN]sol45 M NaClO 4 25 −(2.51±0.17) −(2.55±1.7) (c)sol 5 M NaCl 25 −(1.64±1.53)K 3 NpO 2 (CO 3 ) 2·xH 2 O(s) + (y − x)H 2 O(l) Å KNpO 2 CO 3·yH 2 O(s) + CO 2−3+ 2K +sol 0.2 to 0.8 (p) MK 2 CO 3 −(0.6±0.9) [74SIM/VOL] (a)(b)sol 1 M KCl 75 −(2.7±0.6) [93LEM/BOY] (c)(b)(NH 4 ) 3 NpO 2 (CO 3 ) 2·xH 2 O(s) + (y − x)H 2 O(l) Å NH 4 NpO 2 CO 3·yH 2 O(s) + CO 2−3+ 2NH + 4sol 1.5 to 2.2 (p) M(NH 4 ) 2 CO 3 ? −(0.34±0.58) [71MOS2] (m)(b)(p) In M 2 CO 3 aqueous solution, the two M-Np(V)-CO 3 solid phases are at equilibrium for a unique [M 2 CO 3 ]value,[M 2 CO 3 ] s ; but, since thermodynamic cycles wereused, the value of the equilibrium constant can be estimated in aqueous solution with M 2 CO 3 concentration different from the [M 2 CO 3 ] s value. This is important onlyfor ionic strength corrections.12.1 Neptunium carbon compounds and complexes 237
Reference log 10 Ks,0 ◦ log 10 K1 ◦ log 10 K2 ◦ log 10 K3 ◦ ε 0 ε 1 ε 2 ε 3[98VIT/CAP] (b,e) −10.96 4.97 1.49 −1.20 −0.20 −0.40 −0.70[90RIG] (c) (4.80±0.11) (1.50±0.01) −(0.88±0.01) −(0.16±0.10) −(0.27±0.11) −(0.61±0.11)[90RIG] (b) −(1.04±0.05) −(0.16±0.05)[98VIT/CAP] (g) −(11.00±0.22) (4.70±0.10) (1.38±0.32) −(0.86±0.13) (0.25±0.05) −(0.07±0.03) −(0.28±0.03) −(0.40±0.11)[91KIM/KLE] (m) −(10.96±0.05) (5.04±0.06) (1.55±0.11) −(0.86±0.19) (0.34±0.08) (j) (0.09±0.10) (p) −(0.06±0.09) (j) −(0.23±0.21) (j)(0.25±0.08) (k) (0.03±0.18) (k) −(0.05±0.20) (k)[94NEC/RUN] (m) −(11.0±0.07) (4.81±0.15) (1.74±0.27) −(1.01±0.25) (0.31±0.08) (j) −(0.05±0.11) (p) −(0.16±0.10) (j) −(0.33±0.20) (j)(0.22±0.08) (k) −(0.07±0.19) (k) −(0.15±0.19) (k)−(0.16±0.11) (s)[94NEC/RUN] (c,m) −(10.96±0.14) (d) (4.98±0.16) (d) (1.61±0.07) (d) −0.92 (d) (0.34±0.10) (j) (0.08±0.13) (p) −(0.06±0.13) (j) −(0.24±0.25) (j)(0.24±0.12) (k) (0.03±0.21) (k) −(0.06±0.26) (k)[94NEC/KIM] (m)(0.18±0.03) (c,l)[95FAN/NEC] (h,m) −(11.09±0.11) (n) (5.03±0.06) (1.44±0.15) −(1.10±0.39) (0.20±0.05) (a) (0.06±0.01) (a) (0.12±0.30) (a) (0.63±0.78) (a)[95FAN/NEC] (a,h,q)(0.09±0.01) (r)[94NEC/KIM] (q)(0.09±0.08) (c,l,r)[96RUN/NEU] (q) −(11.05±0.05) (5.18±0.17) (1.01±0.48) −(0.35±0.48) (0.05±0.08) (r) −(0.02±0.13) −(0.36±0.12) −(0.26±0.13)[95NOV/ROB] −11.3 5.39 0.41 −0.62 (0.21±0.07) (a) (0.08±0.07) (a) (0.01±0.45) (a) (0.63±0.81) (a)[96RUN/NEU] (h) −10.89 5.06 1.43 −1.07 (0.17±0.01) (a) (0.05±0.07) (a) (0.08±0.10) (a) (0.51±0.69) (a)[90NIT/STA] (h) (4.69±0.13)This review (b,i) (4.92±0.03) (1.58±0.09) −(1.04±0.12) (0.25±0.05) −(0.22±0.06) −(0.35±0.11) −(0.59±0.13)This review (b,f) −(11.66±0.50) (o) (4.96±0.06) (1.57±0.08) −(1.06±0.11) (0.25±0.05) −(0.18±0.15) −(0.33±0.16) −(0.53±0.19)12. Neptunium group 14 compounds and complexes(a) Calculated in this review from the ion pair Pitzer parameters, neglecting higher order terms even when given in the original publication. Similarε values were derived from the Pitzer parameters from different publications [95FAN/NEC, 95NEC/FAN, 95NOV/ROB, 96RUN/NEU], probablybecause the authors fitted parameters from similar sets of published equilibrium constants.(continued on next page)
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4VOLUMECHEMICALTHERMODYNAMICSCHEMIC
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CHEMICAL THERMODYNAMICSVol. 1. Chem
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Published under the imprint NORTH-H
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viPREFACEviewed several of the othe
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viiiACKNOWLEDGEMENTSand Whiteshell
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xFOREWORDsending comments on the TD
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xiiCONTENTSIII Discussion of neptun
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xivCONTENTS11.1.4.2 Solid neptunium
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CONTENTSxvii20.5.1 PuSb(cr) . . . .
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List of Tables2.1 Symbols and termi
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LIST OF TABLESxxi20.2 Experimental
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List of Figures2.1 Standard order o
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Part IIntroductory material1
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4 1. IntroductionInorganic Complexe
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6 1. Introductionlected, but form a
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Chapter 2Standards, Conventions, an
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2.1 Symbols, terminology and nomenc
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2.2 Units and conversion factors 23
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2.2 Units and conversion factors 25
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2.3 Standard and reference conditio
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2.3 Standard and reference conditio
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2.5 Uncertainty estimates 31Table 2
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2.7 Presentation of the selected da
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2.7 Presentation of the selected da
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Chapter 3Selected neptunium dataThi
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41Table 3.1: Selected thermodynamic
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43Table 3.1: (continued)Compound f
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49Table 3.2: (continued)SpeciesReac
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Chapter 4Selected plutonium dataThi
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61SpeciesPu(OH) 3 (cr)ReactionTable
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Chapter 5Selected auxiliary dataThi
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(footnotes continued)(p) Data from
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79Table 5.2: (continued)Species Rea
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81Table 5.2: (continued)Species Rea
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Chapter 6Elemental neptunium6.1 Nep
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6.1 Neptunium crystal and liquid 87
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6.2 Neptunium ideal monatomic gas 8
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92 7. Neptunium aqua ionsE ◦′ (
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94 7. Neptunium aqua ionsto the sta
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96 7. Neptunium aqua ions(∂ E ◦
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98 7. Neptunium aqua ionsnon-system
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100 7. Neptunium aqua ionsto the re
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102 7. Neptunium aqua ionsTable 7.4
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Chapter 8Neptunium oxygen andhydrog
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8.1 Aqueous neptunium hydroxide com
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8.2 Crystalline and amorphous neptu
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132 9. Neptunium group 17 (halogen)
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178 10. Neptunium group 16 compound
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Page 212 and 213: Chapter 11Neptunium group 15compoun
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Page 222 and 223: 11.2 Neptunium phosphorus compounds
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Page 226 and 227: Chapter 12Neptunium group 14compoun
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Page 230 and 231: cal 0.3-1.6 M Na 2 SO 4 25 r H m =
Page 232 and 233: vlt 0 25 (0.340±0.002) (k) [95OFF/
Page 234 and 235: sol K + ,CO 2−3 , 20 −(2.31±0.
Page 252 and 253: sp 0.1 M NaCl 23 (4.68±0.03) [96RU
Page 254 and 255: dis 0.2 M NaClO 25 2.93 (3.42±1.0)
Page 256 and 257: sol 1 M NaCl 23 (2.06±0.13) [96RUN
Page 258 and 259: sol 0.15 M Na 2 CO 3 −(2.58±0.64
Page 260 and 261: sol 1 M NaClO 30 −(4.0±0.2) [93L
Page 264 and 265: (f) Values selected in this review
Page 282 and 283: (V vs. SHE) (V vs. SHE) (V · K −
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Page 292 and 293: 2 3 r H m (5.0±2.0)log 10 β 2 MO
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12.1 Neptunium carbon compounds and
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290 13. Neptunium group 2 (alkaline
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292 14. Neptunium group 1 (alkali)
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Part IVDiscussion of plutonium data
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298 15. Elemental plutoniumTable 15
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300 15. Elemental plutoniumfrom 298
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302 16. Plutonium aqua ionsthe prop
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304 16. Plutonium aqua ions298.15 K
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306 16. Plutonium aqua ionsE ◦ =
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308 16. Plutonium aqua ionsSm ◦ (
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310 16. Plutonium aqua ionsstandard
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312 16. Plutonium aqua ions r H ◦
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314 16. Plutonium aqua ionsE ◦′
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316 16. Plutonium aqua ionsFigure 1
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318 17. Plutonium oxygen and hydrog
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1:1 pot RT 1 M NaClO 4 −5.71 [49K
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Chapter 18Plutonium group 17 (halog
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18.1 Plutonium halide compounds 347
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18.2 Aqueous plutonium group 17 (ha
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PuO 2+2+ 3F − Å PuO 2 F − (b)3
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390 19. Plutonium group 16 compound
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Chapter 20Plutonium group 15 compou
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20.1 Plutonium nitrogen compounds a
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Pu + NO 3Å PuNO 3sp 2 M HClO 4 20
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3 3 3dis, TTA 6 M (? HCl or HClO 4
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20.2 Plutonium phosphorus compounds
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20.2 Plutonium phosphorus compounds
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20.3 Solid plutonium phosphorus com
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20.4 Plutonium arsenic compounds 42
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20.6 The plutonium-bismuth system 4
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20.6 The plutonium-bismuth system 4
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446 22. Plutonium group 2 (alkaline
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Chapter 23Plutonium group 1 (alkali
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452 BIBLIOGRAPHY[47GIN/COR][48KRA/N
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454 BIBLIOGRAPHY[49MAG/LAC][49ROB][
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456 BIBLIOGRAPHY[51WES/EYR][51WES/W
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458 BIBLIOGRAPHY[55COH/SUL]Cohen, D
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460 BIBLIOGRAPHYmetals in connectio
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462 BIBLIOGRAPHY[59SHE/TIM][59STU][
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464 BIBLIOGRAPHY[61SCH][61STO/FRY][
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466 BIBLIOGRAPHY[63ROB/WAL] Roberts
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468 BIBLIOGRAPHY[64SIL/MAR][65CHO/K
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470 BIBLIOGRAPHY[66DAN/ORL][66FRO/K
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472 BIBLIOGRAPHY[67ERM/STA][67FRL/C
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474 BIBLIOGRAPHY[68KRU/SAV][68KRY/K
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476 BIBLIOGRAPHY[69KEN/LEA][69KRY/K
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478 BIBLIOGRAPHY[70HIN/COB][70KRO/G
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480 BIBLIOGRAPHY[71MOS][71MOS2][71M
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482 BIBLIOGRAPHY[72MET/GUI][72NIK/S
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484 BIBLIOGRAPHY[73PAT/RAM2][73PIT]
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486 BIBLIOGRAPHY[74SAV][74SIM/VOL][
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488 BIBLIOGRAPHY[75OSB/FLO][75PAT/R
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490 BIBLIOGRAPHY298.15 K”, J. Che
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492 BIBLIOGRAPHY[76VOL/VIS][77BAG/R
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494 BIBLIOGRAPHY[78HAL/LEE][78HUR][
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496 BIBLIOGRAPHYof plutonium(IV)”
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498 BIBLIOGRAPHYNa 0.6 NpO 2 (CO 3
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500 BIBLIOGRAPHY[81CHI/AKH][81CIA/F
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502 BIBLIOGRAPHY[81WOO][82ALC/ROB][
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504 BIBLIOGRAPHY[83ALL][83BES/LIN][
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506 BIBLIOGRAPHY[83SCH/GOR]Schmidt,
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508 BIBLIOGRAPHY[84LEM][84LIE/KIM][
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510 BIBLIOGRAPHY[85CÔM][85EIS/KIM]
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512 BIBLIOGRAPHY[85NEW/SUL][85RAI/R
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514 BIBLIOGRAPHY[86FAH][86FRE/KEL]F
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516 BIBLIOGRAPHY[87BEN][87BEN/HOF][
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518 BIBLIOGRAPHY[88HIR/LIE][88ITU][
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520 BIBLIOGRAPHYGeochim. Cosmochim.
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522 BIBLIOGRAPHY[90BEN][90CAP/VIT][
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524 BIBLIOGRAPHY254, 258, 258, 264,
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526 BIBLIOGRAPHY[91MEI][91NIT][91OK
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528 BIBLIOGRAPHYment”, Waste Mana
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530 BIBLIOGRAPHY[93ERI/NDA][93GIF/V
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532 BIBLIOGRAPHY[93TAY/LEM][93WEG/O
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534 BIBLIOGRAPHYpages 222, 223, 226
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536 BIBLIOGRAPHYK, gas-phase infrar
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538 BIBLIOGRAPHY[96ALL/VEI][96CAP/V
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540 BIBLIOGRAPHY[97CAP/VIT][97FEL/R
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542 BIBLIOGRAPHY[99RAI/HES2][99RAR/
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544 LIST OF CITED AUTHORSTable 23.1
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Appendix ADiscussion of selected re
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A. Discussion of selected reference
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5 −10.63±0.11 (g) −12.48±0.23
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dataarein1MNa + media, except as no
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Appendix BIonic strength correction
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B.1 The specific ion interaction eq
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B.2 Ion interaction coefficients ve
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B.3 Tables of ion interaction coeff
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Appendix CAssigned uncertainties
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C.2 Two or more independent source
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C.2 Two or more independent source
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C.3 Several data at different ionic
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C.3 Several data at different ionic
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C.4 Procedures for data handling 83
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C.4 Procedures for data handling 83
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Index837
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INDEX - GENERAL 839standard state p
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INDEX - NEPTUNIUM 841elemental nept
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INDEX - PLUTONIUM 843Index - pluton
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INDEX - PLUTONIUM 845monobismuthide
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