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chemical thermodynamics of neptunium and plutonium - U.S. ...

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24 2. St<strong>and</strong>ards, Conventions, <strong>and</strong> Contents <strong>of</strong> the TablesFigure 2.1: St<strong>and</strong>ard order <strong>of</strong> arrangement <strong>of</strong> the elements <strong>and</strong> compounds based onthe periodic classification <strong>of</strong> the elements (from Ref. [82WAG/EVA]).LiNaBeMgK Ca ScRb Sr YCs Ba LaFr Ra Ac H HeB C N O FNeAl Si P S Cl ArTi V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br KrZr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I XeHf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lrfor molality, m. It is <strong>of</strong>ten necessary to convert concentration data from molarity tomolality <strong>and</strong> vice versa. This conversion is used for the correction <strong>and</strong> extrapolation<strong>of</strong> equilibrium data to zero ionic strength by the specific ion interaction theory whichworks in molality units (cf. Appendix B). This conversion is made in the following way.Molality is defined as m B moles <strong>of</strong> substance B dissolved in 1000 grams <strong>of</strong> pure water.Molarity is defined as c B moles <strong>of</strong> substance B dissolved in (1000ρ − c B M) grams <strong>of</strong>pure water, where ρ is the density <strong>of</strong> the solution <strong>and</strong> M the molar weight <strong>of</strong> the solute.From this it follows thatm B =1000c B1000ρ − c B MTable 2.4: Unit conversion factorsTo convert from to multiply by(non-SI unit symbol)(SI unit symbol)ångström (Å) metre (m) 1 × 10 −10 (exactly)st<strong>and</strong>ard atmosphere (atm) pascal (Pa) 1.01325 × 10 5 (exactly)bar (bar) pascal (Pa) 1 × 10 5 (exactly)thermo<strong>chemical</strong> calorie (cal) joule (J) 4.184 (exactly)entropy unit (e.u. ∧ = cal · K −1 · mol −1 ) J · K −1 · mol −1 4.184 (exactly)

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